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0001066877
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In situ generation of selenoacylsilane and its trapping by a diene has been reported
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For recent examples, see
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77953218310
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note
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23NSeSi: C, 59.98; H, 6.43; N, 3.89. Found: C, 59.79; H, 6.48; N, 3.90.
-
-
-
-
34
-
-
77953225020
-
-
note
-
23GeNSe: C, 53.38; H, 5.72; N, 3.46. Found: C, 53.62; H, 5.87; N, 3.39.
-
-
-
-
35
-
-
77953206135
-
-
note
-
The computations were done using Gaussian 03. The hybrid density functional B3LYP along with the 6-311+G(d) basis set was used for the structure optimization and energy calculations. Further technical details are provided in the Supporting Information.
-
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36
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15044338850
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2 (6) in a procedure that is similar to that used to prepare 3 and 4. The C=S carbons of 6 - 8 resonate at δ 189.5, 224.2, and 225.1, respectively (see the Supporting Information).
-
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46
-
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77953198046
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note
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In contrast to the generation of carbamoyllithiums (18) and thiocarbamoyllithiums, (19) no studies of their selenium isologues have been reported.
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