Thermal behaviour and interactions of cassava starch filled with glycerol plasticized polyvinyl alcohol blends

Carbohydrate Polymers

Volumn 81, Issue 4, 2010, Pages 805-810

  Rahman, W A W A ^a   Sin, Lee Tin ^a   Rahmat, A R ^a   Samad, A A ^a  

^a UNIVERSITI TEKNOLOGI MALAYSIA   (Malaysia)

Author keywords

Cassava starch; DSC; Glycerol; Polyvinyl alcohol; Thermogravimetry

Indexed keywords

BIODEGRADABLE COMPOUNDS; BLENDED FILMS; CARBONACEOUS RESIDUES; CASSAVA STARCH; DEGRADATION ACTIVATION ENERGY; DIFFERENTIAL SCANNING CALORIMETRY METHODS; DSC; END POINTS; MELTING TEMPERATURES; PHASE 1; THERMAL ATTACK; THERMAL BEHAVIOURS; THERMOGRAVIMETRY; THREE PHASIS;

ACTIVATION ENERGY; BLENDING; DEGRADATION; DIFFERENTIAL SCANNING CALORIMETRY; ENTHALPY; MELTING; STARCH; THERMOGRAVIMETRIC ANALYSIS;

GLYCEROL;

MANIHOT ESCULENTA;

EID: 77953140321     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbpol.2010.03.052     Document Type: Article

References (37)

1. Acros Organics. Reference handbook of fine chemicals (2006), Acros Organics, Geel
2. Belmares M., Blanco M., Goddard W.A., Ross R.B., Caldwell G., Chou S.H., et al. Hildebrand and Hansen solubility parameters from molecular dynamics with application to electronic nose polymer sensors. Journal of Computational Chemistry 2 (2004) 1814-1826
3. British Standard Institution. (2005). Plastics-Thermogravimetry (TG) of polymers-Part 2: Determination of Activation Energy. BS ISO 11358-2.
4. Chen L., Imam S.H., Gordon S.H., and Grèene R.V. Starch-polyvinyl alcohol crosslinked film-performance and biodgradation. Journal of Environmental Polymer Degradation 5 (1997) 111-117
5. Chiellini E., Corti A., D'Antone S., and Solaro R. Biodegradation of poly(vinyl alcohol) based materials. Progress in Polymer Science 28 (2003) 963-1014
6. Chiellini E., Cinelli P., Ilieva V.I., Imam S.H., and Lawton J.W. Environmentally compatible foamed articles based on potato starch, corn fiber, and poly(vinyl alcohol). Journal of Cellular Plastics 45 (2009) 17-32
7. Cinelli P., Chiellini E., Lawton J.W., and Imam S.H. Foamed articles based on potato starch, corn fibers and poly(vinyl alcohol). Polymer Degradation and Stability 91 (2006) 1147-1155
8. Constantin M., Fundueanu G., Bortolotti F., Cortesi R., Ascenzi P., and Menegatti E. Preparation and characterization of poly(vinyl alcohol) cyclodextrin microspheres as matrix for inclusion and separation of drugs. International Journal of Pharmaceutics 285 (2004) 87-96
9. Dou B., Dupont V., Williams P.T., Chen H., and Ding Y. Thermogravimetric kinetics of crude glycerol. Bioresource Technology 100 (2009) 2613-2620
10. Fishman M.L., Coffin D.R., Onwulata C.I., and Willet J.L. Two stage extrusion of plasticized pectin/poly(vinyl alcohol) blends. Carbohydrate Polymers 65 (2006) 421-429
11. Flynn J.H., and Wall L.A. A quick, direct method for the determination of activation energy from thermogravimetric data. Polymer Letters 4 (1966) 323-328
12. Forssell P.M., Hulleman S.H.D., Myllärinen P.J., Moates G.K., and Parker R. Ageing of rubbery thermoplastic barley and oat starches. Carbohydrate Polymers 39 (1999) 43-51
13. Garg S., and Jana A.K. Studies on the properties and characteristics of starch-LDPE blend films using cross-linked, glycerol modified, cross-linked and glycerol modified starch. European Polymer Journal 43 (2007) 3976-3987
14. Gomes M.E., Godinho J.S., Tchalamov D., Cunha A.M., and Reis R.L. Alternative tissue engineering scaffolds based on starch: processing methodologies, morphology, degradation and mechanical properties. Materials Science and Engineering C 20 (2002) 19-26
15. Holland B.J., and Hay J.N. The thermal degradation of poly(vinyl alcohol). Polymer 42 (2001) 6775-6783
16. Imam S.H., Gordon S.H., and Greene R.V. Starch biodegradation (in starch-plastic blends). In: Salamone J.C. (Ed). Polymeric materials encyclopedia 10 (1996), CRC Press, Boca Raton, FL 7893-7894
17. Kholodovych V., and Welsh W.J. Thermo-oxidative stability and degradation of polymers. In: Mark J.E. (Ed). Physical properties of polymers handbook. 2nd ed. (2007), Springer Science+Business Media, New York 927-937
18. Kuraray Specialities. Specialized in specialties. Mowiol polyvinyl alcohol-uses of Mowiol (2003), Kuraray Specialities Europe KSE GmBH, Frakfurt/Main
19. Lee T.S., Rahman W.A.W.A., Rahmat A.R., and Khan M.I. Detection of synergistic interactions of polyvinyl alcohol-cassava starch blends through DSC. Carbohydrate Polymers 79 (2010) 224-226
20. Lee T.S., Rahman W.A.W.A., Rahmat A.R., and Samad A.A. Computational modeling and experimental infrared spectroscopy of hydrogen bonding interactions in polyvinyl alcohol-starch blends. Polymer 51 (2010) 1206-1211
21. Lin C., and Ku T. Shear and elongational flow properties of thermoplastic polyvinyl alcohol melts with different plasticizer contents and degrees of polymerization. Journal of Materials Processing Technology 200 (2008) 331-338
22. Liu Z., Feng Y., and Yi X. Thermoplastic starch/PVAL compounds: preparation, processing and properties. Journal of Applied Polymer Science 74 (1999) 2667-2673
23. Mao L., Imam S., Gordon S., Cinelli P., and Chiellini E. Extruded cornstarch-glycerol-polyvinyl alcohol blends: mechanical properties, morphology, and biodegradability. Journal of Polymers and the Environment 8 (2000) 205-211
24. Moolman F.S., Meunier M., Labuschagne P.W., and Truter P.A. Compatibility of polyvinyl alcohol and poly(methyl vinyl ether-co-maleic acid) blends estimated by molecular dynamics. Polymer 46 (2005) 6192-6200
25. Ozawa T. A new method of analyzing thermogravimetric data. Bulletin of the Chemical Society of Japan 38 (1965) 1881-1886
26. Price D.M., Hourston D.J., and Dumont F. Thermogravimetry of polymers. In: Meyers R.A. (Ed). Encyclopedia of analytical chemistry (2000), John Wiley, Chichester 8094-8105
27. Ramaraj B. Crosslinked poly(vinyl alcohol) and starch composite films. II. Physicomechanical, thermal properties and swelling studies. Journal of Applied Polymer Science 103 (2007) 909, 916
28. Siddaramaiah, Raj B., and Somashekar R. Structure-property relation in polyvinyl alcohol/starch composites. Journal of Applied Polymer Science 9 (2004) 630-635
29. Sinha A., Das G., Sharma B.K., Roy R.P., Pramanick A.K., and Nayar S. Poly(vinyl alcohol)-hydroxyapatite biomimetic scaffold for tissue regeneration. Materials Science and Engineering C 27 (2007) 70-74
30. Stojanović Z., Katsikas L., Popović I., Javanović S., and Jeremić K. Thermal stability of starch benzoate. Polymer Degradation Stability 87 (2005) 177-182
31. 2 on the performance of starch/polyvinyl alcohol blend films. Carbohydrate Polymers 72 (2008) 521-526
32. Tubbs R.K., and Ting K.W. Thermal properties of polyvinyl alcohol. In: Finch C.A. (Ed). Polyvinyl alcohol-properties and applications (1973), John Wiley, Great Britain 167-182
33. Wade L.G. Organic chemistry. 4th ed. (1999), Prentice-Hall, New Jersey
34. Wang, J. H., Schertiz, D. M. & Pomplun, W. S. (2001). Unmodified polyvinyl alcohol fibers. US Patent Office, Pat. No. 6 203 903 B1.
35. Wunderlich B. The application of MTDSC to polymer melting. In: Reading M., and Hourston D.J. (Eds). Modulated temperature differential scanning calorimetry: theoretical and practical applications in polymer characterization (2006), Springers, Dordrecht, Netherlands 217-320
36. Xiao C., and Yang M. Controlled preparation of physical cross-linked starch-g-PVA hydrogel. Carbohydrate Polymers 64 (2006) 37-40
37. Zhai M.L., Yoshii F., Kume T., and Hashim K. Syntheses of PVA/starch grafted hydrogels by irradiation. Carbohydrate Polymers 50 (2002) 295-303