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Volumn 49, Issue 11, 2010, Pages 4768-4780

Syntheses and multi-NMR study of fac-and mer-OsO3F 2(NCCH3) and the X-ray crystal structure (n = 2) and raman spectrum (n = 0) offac-OsO3F2(NCCH3) · nCH3CN

Author keywords

[No Author keywords available]

Indexed keywords

COORDINATION COMPOUND; ORGANOMETALLIC COMPOUND; OSMIUM;

EID: 77953044272     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic100383p     Document Type: Article
Times cited : (6)

References (61)
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    • 3) are as follows: F(2)•••O(2A) (2.988(3) ̊), F(1)•••H(5B) (2.469 ̊) to F(2)•••H(3C) (2.740 ̊), O(1)•••O(3D) (2.897(3) ̊), O(3) •••H(9D) (2.557 ̊) to O(3)•••H(1E) (2.861 ̊), O(3)•••C(2E) (3.094(4) ̊), N(3) •••H(1F) (2.601 ̊), N(3)•••C(1F) (3.206(5) ̊) to N(3)•••C(2G) (3.434(5) ̊), and C(1)•••C(5F) (3.471(5) ̊). The corresponding sums of the van der Waals radii (taken from ref 26)
    • 3) are as follows: F(2)•••O(2A) (2.988(3) ̊), F(1)•••H(5B) (2.469 ̊) to F(2)•••H(3C) (2.740 ̊), O(1)•••O(3D) (2.897(3) ̊), O(3) •••H(9D) (2.557 ̊) to O(3)•••H(1E) (2.861 ̊), O(3)•••C(2E) (3.094(4) ̊), N(3) •••H(1F) (2.601 ̊), N(3)•••C(1F) (3.206(5) ̊) to N(3)•••C(2G) (3.434(5) ̊), and C(1)•••C(5F) (3.471(5) ̊). The corresponding sums of the van der Waals radii (taken from ref 26) are as follows: [F•••F (2.94 ̊), F•••O (2.99 ̊), F•••N (3.02 ̊), F•••H (2.67 ̊), F•••C (3.17 ̊), O•••O (3.04 ̊), O•••N (3.07 ̊), O•••H (2.72 ̊), O•••C (3.22 ̊), N•••N (3.10 ̊), N•••H (2.75 ̊), N•••C (3.25 ̊), H•••H (2.40 ̊), H•••C (2.90 ̊) and C•••C (3.40 ̊)].
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    • 3) are as follows: O(1)•••O(2,3) 2.638(3), 2.655(3) ̊; O(1)•••F(1) 2.538(3) ̊; O(1)•••N(1) 2.647(4) ̊; O(2)•••O(3) 2.658(3); O(2)•••F(2) 2.534(3) ̊; O(2)•••N(1) 2.646(4) ̊; O(3)•••F(1,2) 2.633(3), 2.636(3); and N(1)•••F(1,2) 2.645(3), 2.647(3) ̊.
    • 3) are as follows: O(1)•••O(2,3) 2.638(3), 2.655(3) ̊; O(1)•••F(1) 2.538(3) ̊; O(1)•••N(1) 2.647(4) ̊; O(2)•••O(3) 2.658(3); O(2)•••F(2) 2.534(3) ̊; O(2)•••N(1) 2.646(4) ̊; O(3)•••F(1,2) 2.633(3), 2.636(3); and N(1)•••F(1,2) 2.645(3), 2.647(3) ̊.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.