Synthesis and X-ray crystal structure of (OsO3F 2)2·2XeOF4 and the raman spectra of (OsO3F2)∞, (OsO3F 2)2, and (OsO3F2) 2·2XeOF4

Inorganic Chemistry

Volumn 48, Issue 10, 2009, Pages 4478-4490

  Hughes, Michael J ^a   Mercier, Hélène P A ^a   Schrobilgen, Gary J ^a  

^a MCMASTER UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 66149122895     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic900242m     Document Type: Article

References (44)

1. Hepworth, M. A.; Robinson, P. L. J. Inorg. Nucl. Chem. 1957, 4, 24-29.
2. Nghi, N.; Bartlett, N. C. R. Acad. Sci. 1969, 269, 756-759.
3. Bougon, R.; Buu, B.; Seppelt, K. Chem. Ber. 1993, 126, 1331-1336.
4. Hope, E. G.; Levason, W.; Ogden, J. S. J. Chem. Soc, Dalton Trans. 1988, 61-65.
5. Beattie, I. R.; Blayden, H. E.; Crocombe, R. A.; Jones, P. J.; Ogden, J. S. J. Raman Spectrosc. 1976, 4, 313-322.
6. Falconer, W. E.; Disalvo, F. J.; Griffiths, J. E.; Stevie, F. A.; Sunder, W. A.; Vasile, M. J. J. Fluorine Chem. 1975, 6, 499-520.
7. Beattie, I. R.; Livingston, K. M. S.; Reynolds, D. J.; Ozin, G. A. J. Chem. Soc. A 1970, 1210-1216.
8. Bondi, A. J. Phys. Chem. 1964, 68, 441-451.
9. 4 are F(6)-'F(5A) (2.903(8) Å) to F(1)..."F(5B) (3.135(7) A); F(6)-"0(3C) (2.810(8) Å) to F(6)."0(4D) (3.155(8) Å); 0(2)-"0(4E) (2.954(9) Å) to 0(2)."0(3A)(3.168(8)Å);Xe(l)- F(4F) (3.545(6) A) toXe(l)."F(5A) (3.684(5) Å); and Xe(l)-"0(3C) (3.715(6) Å) to Xe(l)-"0(2F) (3.720(6) Å). The corresponding sums of the van der Waals radii (taken from ref 8) are F-"F (2.94 A), F"-0 (2.99 Å), 0"-0 (3.04 Å), Xe-"F (3.63 Å) and Xe-"0 (3.68 Å).
10. Gerken, M.; Dixon, D. A.; Schrobilgen, G. J. Inorg. Chem. 2000, 39, 4244-4255.
11. Gerken, M.; Dixon, D. A.; Schrobilgen, G. J. Inorg. Chem. 2002, 41, 259-277.
12. Supel, J.; Marx, R.; Seppelt, K. Z. Anorg. AlIg. Chem. 2005, 631, 2979-2986.
13. Casteel, W. J.; Dixon, D. A.; LeBlond, N.; Lock, P. E.; Mercier, H. P. A.; Schrobilgen, G. J. Inorg. Chem. 1999, 38, 2340-2358.
14. Casteel, W. J.; Dixon, D. A.; Mercier, H. P. A.; Schrobilgen, G. J. Inorg. Chem. 1996, 35, 4310-4322.
15. LeBlond, N.; Dixon, D. A.; Schrobilgen, G. J. Inorg. Chem. 2000, 39, 2473-2487.
16. LeBlond, N.; Mercier, H. P. A.; Dixon, D. A.; Schrobilgen, G. J. Inorg. Chem. 2000, 39, 4494-4509.
17. Schrobilgen, G. J.; Holloway, J. H.; Russell, D. R. J. Chem. Soc, Dalton Trans. 1984, 1411-1415.
18. Edwards, A. J.; Jones, G. R. J. Chem. Soc. A 1968, 2074-2078.
19. Edwards, A. J.; Steventon, B. R. J. Chem. Soc. A 1968, 2503-2510.
20. Casteel, W. J.; Dixon, D. A.; LeBlond, N.; Mercier, H. P. A.; Schrobilgen, G. J. Inorg. Chem. 1998, 37, 340-353.
21. 4 are 0(1) -0(2,3) 2.634(9), 2.634(9) Å; 0(1)-F(1,1A) 2.606(8), 2.600(7) Å 0(2)-0(3) 2.674(8) Å; 0(2)-F(1A,2) 2.731(7), 2.599(9) Å; 0(3) -F(l,2) 2.740(8), 2.587(8) Å; and F(1A)-F(l,2) 2.428 (9), 2.501(7) Å.
22. Lis, T. Acta Crystallogr. 1983, C39, 961-962.
23. Christe, K. O.; Dixon, D. A.; Mack, H. G.; Oberhammer, H.; Pagelot, A.; Sanders, J. C. P.; Schrobilgen, G. J. J. Am. Chem. Soc. 1993, 115, 11279-11284.
24. Brown, T. H.; Whipple, E. B.; Verdier, P. H. J. Chem. Phys. 1963, 38, 3029-3030.
25. Brundle, C. R.; Jones, G. R. J. Electron Spectrosc. Relat. Phenom. 1973, 1, 403-407.
26. Tsao, P.; Cobb, C. C; Claassen, H. H. J. Chem. Phys. 1971, 54, 5247.
27. Martins, J.; Wilson, E. B., Jr. J. Chem. Phys. 1964, 41, 570-571.
28. Martins, J. F.; Wilson, E. B., Jr. J. Mol. Spectrosc. 1968, 26, 410417.
29. Jacob, E. J.; Thompson, H. B.; Bartell, L. S. J. Mol. Struct. 1971, 8, 383-394.
30. Pointner, B. E.; Suontamo, R. J.; Schrobilgen, G. J. Inorg. Chem. 2006, 45, 1517-1534.
31. Glendening, E. D.; Reed, A. E.; Carpenter, J. E.; Weinhold, F. NBO, Version 3.1; Gaussian Inc.: Pittsburgh, PA, 1990.
32. Reed, A. E.; Curtiss, L. A.; Weinhold, F. Chem. Rev 1998, 88, 899926.
33. Reed, A. E.; Weinstock, R. B.; Weinhold, F. J. Chem. Phys. 1985, 83, 735-746.
34. Glendening, E. D.; Badenhoop, J. K.; Reed, A. E.; Carpenter, J. E.; Bohmann, C. M.; Morales, C. M.; Weinhold, F. NBO Version 5.0; Theoretical Chemical Institute, University of Wisconsin: Madison, WI, 2001.
35. Schumacher, G. A.; Schrobilgen, G. J. Inorg. Chem. 1984, 23, 29232929.
36. APEX2, Release 2.0-2; Bruker AXS Inc.: Madison, WI, 2005.
37. Sheldrick, G. M. SADABS (Siemens Area Detector Absorption Corrections), version 2.10; Siemens Analytical X-ray Instruments Ine: Madison, WI, 2004.
38. Sheldrick, G. M., SHELXTL-Plus, release 6.14, Siemens Analytical X-ray Instruments, Ine; Madison, WI, 2000-2003.
39. Farrugia, L. J. J. Appl. Crystallogr. 1999, 32, 837-838.
40. Frisch, M. J. et al. Gaussian 03, revision B.04; Gaussian, Inc.: Pittsburgh, PA, 2003.
41. Huzinaga, S.; Andzelm, J.; Kolobukowski, M.; Radzio-Andzelm, E.; Sakai, Y.; Tatewaki, H. Gaussian Basis Sets for Molecular Calculations; Physical Science Data 16; Elsevier: Amsterdam, 1984.
42. Ehlers, A. W.; Bohme, M.; Dapprich, S.; Gobbi, A.; HoUwarth, A.; Jonas, V.; Kohler, K. F.; Stegmann, R.; Veldkamp, A.; Frenking, G. Chem. Phys. Lett. 1993, 208, 111-114.
43. Frisch, M. J. et al. Gaussian 98, Revision A.l l; Gaussian, Inc.: Pittsburgh, PA, 2003.
44. GaussView, release 3.0; Gaussian Inc.: Pittsburgh, PA, 2003.