Analytical strategy for the molecular weight determination of random copolymers of poly(methyl methacrylate) and poly(methacrylic acid)

Journal of the American Society for Mass Spectrometry

Volumn 21, Issue 6, 2010, Pages 1075-1085

  Giordanengo, Rémi ^a   Viel, Stéphane ^a   Hidalgo, Manuel ^b   Allard Breton, Béatrice ^b   Thévand, André ^a   Charles, Laurence ^a  

^a AIX MARSEILLE UNIVERSITY   (France)

^b ARKEMA   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLATION; ESTERS; IONIZATION; MASS SPECTROMETRY; METHYLATION; MOLECULAR WEIGHT; MOLECULES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYACRYLATES;

AMPHIPHILIC CO-POLYMERS; IONIZATION TECHNIQUES; MOLECULAR WEIGHT DETERMINATION; POLY (METHACRYLIC ACID); PULSED GRADIENT SPIN ECHOS; TANDEM MASS SPECTROMETRY; TRIMETHYLSILYLDIAZOMETHANE; WEIGHT-AVERAGE MOLECULAR WEIGHT;

ACRYLIC MONOMERS;

ALKENE; DIAZONIUM COMPOUND; POLY(METHYL METHACRYLATE); POLYMETHACRYLIC ACID; TRIMETHYLSILYLDIAZOMETHANE; UNCLASSIFIED DRUG;

ANALYTIC METHOD; ARTICLE; CHEMICAL ANALYSIS; CONTROLLED STUDY; ELECTRON SPIN RESONANCE; IONIZATION; MATRIX ASSISTED LASER DESORPTION IONIZATION TIME OF FLIGHT MASS SPECTROMETRY; METHYLATION; MOLECULAR WEIGHT; PROTON NUCLEAR MAGNETIC RESONANCE; TANDEM MASS SPECTROMETRY;

EID: 77952882471     PISSN: 10440305     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jasms.2010.02.007     Document Type: Article

References (42)

1. Forster S., Abetz V., Muller A.H.E. Polyelectrolyte Block Copolymer Micelles. Polyelectrolytes with Defined Molecular Architecture II 2004, 173-210. Lavoisier, Paris, France, Vol. CLXVI.
2. Mun G.A., Nurkeeva Z.S., Irmukhametova G.S., Guven O. Synthesis, Characterization, and Adsorption Study of the Uranyl Ions by Hydrogels Based on Polyethylene Glycol and Methacrylic Acid Copolymers. Nucl. Instrum. Methods Phys. Res. Sect. B 2007, 265:379-384.
3. Colombani O., Ruppel M., Burkhardt M., Drechsler M., Schumacher M., Gradzielski M., Schweins R., Muller A.H.E. Structure of Micelles of Poly(n-Butyl Acrylate)-Block-Poly (Acrylic Acid) Diblock Copolymers in Aqueous Solution. Macromolecules 2007, 40:4351-4362.
4. Colombani O., Ruppel M., Schubert F., Zettl H., Pergushov D.V., Muller A.H.E. Synthesis of Poly(n-Butyl Acrylate)-Block-Poly(Acrylic Acid) Diblock Copolymers by ATRP and Their Micellization in Water. Macromolecules 2007, 40:4338-4350.
5. Burkhardt M., Martinez-Castro N., Tea S., Drechsler M., Babin I., Grishagin I., Schweins R., Pergushov D.V., Gradzielski M., Zezin A.B., Muller A.H.E. Polyisobutylene-Block-Poly(Methacrylic Acid) Diblock Copolymers: Self-Assembly in Aqueous Media. Langmuir 2007, 23:12864-12874.
6. Pergushov D.V., Remizova E.V., Feldthusen J., Zezin A.B., Muller A.H.E., Kabanov V.A. Novel Water-Soluble Micellar Interpolyelectrolyte Complexes. J. Phys. Chem. B 2003, 107:8093-8096.
7. Ravi P., Wang C., Tam K.C., Gan L.H. Association Behavior of Poly(Methacrylic Acid)-Block-Poly(Methyl Methacrylate) in Aqueous Medium: Potentiometric and Laser Light Scattering Studies. Macromolecules 2003, 36:173-179.
8. Yao H., Ravi P., Tam K.C., Gan L.H. Association Behavior of Poly(Methyl Methacrylate-b-Methacrylic Acid-b-Methyl Methacrylate) in Aqueous Medium. Polymer 2004, 45:2781-2791.
9. Yao J., Ravi P., Tam K.C., Gan L.H. Association Behavior of Poly(Methyl Methacrylate-Block-Methacrylic Acid) in Aqueous Medium. Langmuir 2004, 20:2157-2163.
10. Adhikari R., Michler G.H. Influence of Molecular Architecture on Morphology and Micromechanical Behavior of Styrene/Butadiene Bblock Copolymer Systems. Prog. Polym. Sci. 2004, 29:949-986.
11. Gotzamanis G., Tsitsilianis C. Stimuli-Responsive A-b-(B-co-C) Diblock Terpolymers Bearing Polyampholyte Sequences. Macromol. Rapid Commun. 2006, 27:1757-1763.
12. Gotzamanis G., Tsitsilianis C. Design of Responsive Double-Hydrophilic A-b-(B-co-C) Diblock Terpolymers with Tunable Thermosensitivity. Polymer 2007, 48:6226-6233.
13. Zielinski J.M., Spontak R.J. Thermodynamic Considerations of Triblock Copolymers with a Random Middle Block. Macromolecules. 1992, 25:5957-5964.
14. Laurer J.H., Smith S.D., Samseth J., Mortensen K., Spontak R.J. Interfacial Modification as a Route to Novel Bilayered Morphologies in Binary Block Copolymer/Homopolymer Blends. Macromolecules 1998, 31:4975-4985.
15. Grubisic Z., Rempp P., Benoit H. A Universal Calibration for Gel Permeation Chromatography. J. Polym. Sci. B Polym. Phys. 1996, 34:1707-1713.
16. Mori S., Barth H.G. Size Exclusion Chromatography 1999, 185-198. Springer-Verlag, Berlin, Germany.
17. Medrano R., Laguna M.T.R., Saiz E., Tarazona M.P. Analysis of Copolymers of Styrene and Methyl Methacrylate Using Size Exclusion Chromatography with Multiple Detection. Phys. Chem., Chem. Phys. 2003, 5:151-157.
18. Stejskal E.O., Tanner J.E. Spin Diffusion Measurements: Spin Echoes in the Presence of a Time-Dependent Field Gradient. J. Chem. Phys. 1965, 42:288-291.
19. Stilbs P. Fourier Transform Pulsed-Gradient Spin-Echo Studies of Molecular Diffusion. Prog. Nucl. Magn. Reson. Spectrosc. 1987, 19:1-45.
20. Price W.S. Pulsed-Field Gradient Nuclear Magnetic Resonance as a Tool for Studying Translational Diffusion: Part 1. Basic Theory. Concepts Magn. Reson. 1997, 9:299-336.
21. Chen A., Wu D., Johnson C.S. Determination of Molecular Weight Distributions for Polymers by Diffusion Ordered NMR. J. Am. Chem. Soc. 1995, 117:7965-7970.
22. Håkansson B., Nydén M., Söderman O. The Influence of Polymer Molecular Weight Distributions on Pulsed Field Gradient Nuclear Magnetic Resonance Self-Diffusion Experiments. Colloid. Polym. Sci. 1999, 278:399-405.
23. Viel S., Capitani D., Mannina L., Segre A. Diffusion-Ordered NMR Spectroscopy: A Versatile Tool for the Molecular Weight Determination of Uncharged Polysaccharides. Biomacromolecules 2003, 4:1843-1847.
24. Mazarin M., Viel S., Allard-Breton B., Thevand A., Charles L. Use of Pulsed Gradient Spin-Echo NMR as a Tool in MALDI Method Development for Polymer Molecular Weight Determination. Anal. Chem. 2006, 78:2758-2764.
25. Barrere C., Mazarin M., Giordanengo R., Phan T.N.T., Thevand A., Viel S., Charles L. Molecular Weight Determination of Block Copolymers by Pulsed Gradient Spin Echo NMR. Anal. Chem. 2009, 81:8054-8060.
26. Montaudo G., Lattimer R.P. Mass Spectrometry of Polymers 2002, 523-552. CRC Press, Boca Raton.
27. Pasch H., Schrepp W. MALDI-TOF Mass Spectrometry of Synthetic Polymers 2002, 85-106. Springer-Verlag, Berlin, Germany.
28. Leenheer J.A., Rostad C.E., Gates P.M., Furlong E.T., Ferrer I. Molecular Resolution and Fragmentation of Fulvic Acid by Electrospray Ionization/Multistage Tandem Mass Spectrometry. Anal. Chem. 2001, 73:1461-1471.
29. Giordanengo R., Viel S., Allard-Breton B., Thevand A., Charles L. Tandem Mass Spectrometry of Poly(Methacrylic Acid) Oligomers Produced by Negative Mode Electrospray Ionization. J. Am. Soc. Mass Spectrom. 2009, 20:25-33.
30. Giordanengo R., Viel S., Allard-Breton B., Thevand A., Charles L. Positive Mode Electrospray Tandem Mass Spectrometry of Poly(Methacrylic Acid) Oligomers. Rapid Commun. Mass Spectrom. 2009, 23:1557-1562.
31. Giordanengo R., Viel S., Hidalgo M., Allard-Breton B., Thevand A., Charles L. Structural Characterization of a Poly(Methacrylic Acid)-Poly(Methyl Methacrylate) Copolymer by Nuclear Magnetic Resonance and Mass Spectrometry. Anal. Chim. Acta 2009, 654:49-58.
32. Wyatt M.F., Schaeffer N., Tan B., Cooper A.I. Strategies for the Analysis of Poly(Methacrylic Acid) by Matrix-Assisted Laser Desorption/Ionization Time-of-Flight Mass Spectrometry. J. Am. Soc. Mass Spectrom. 2007, 18:1507-1510.
33. Girod M., Mazarin M., Phan T.N.T., Gigmes D., Charles L. Determination of Block Size in Poly(Ethylene Oxide)-b-Polystyrene Block Copolymers by Matrix-Assisted Laser Desorption/Ionization Time-of-Flight Mass Spectrometry. J. Polym. Sci. A Polym. Chem. 2009, 47:3380-3390.
34. Couvreur L., Lefay C., Belleney J., Charleux B., Guerret O., Magnet S. First Nitroxide-Mediated Controlled Free-Radical Polymerization of Acrylic Acid. Macromolecules 2003, 36:8260-8267.
35. Arakawa R., Egami S., Okuno S. An effective Derivatization Method for Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry of Poly(Acrylic Acid). J. Mass Spectrom. 2006, 41:549-550.
36. Charles L. Influence of Internal Standard Charge State on the Accuracy of Mass Measurements in Orthogonal Acceleration Time-of-Flight Mass Spectrometers. Rapid Commun. Mass Spectrom. 2008, 22:151-155.
37. Edwards S.F., Doi M. The Theory of Polymer Dynamics 1986, 391. Oxford University Press, New York.
38. Danis P.O., Karr D.E. Analysis of Poly(Styrenesulfonic Acid) by Matrix-Assisted Laser-Desorption Ionization Time-of-Flight Mass-Spectrometry. Macromolecules 1995, 28:8548-8551.
39. Mori S., Sakai I., Aoyama T., Shioiri T. New Methods and Reagents in Organic-Synthesis. 28. A Convenient and Efficient Preparation of Trimethylsilyldiazomethane (Tmschn2) Using Diphenyl Phosphorazidate (DPPA). Chem. Pharm. Bull. 1982, 30:3380-3382.
40. Jackson A.T., Yates H.T., Scrivens J.H., Critchley G., Brown J., Green M.R., Bateman R.H. The Application of Matrix-Assisted Laser Desorption/Ionization Combined with Collision-Induced Dissociation to the Analysis of Synthetic Polymers. Rapid Commun. Mass Spectrom. 1996, 10:1668-1674.
41. Jackson A.T., Yates H.T., Scrivens J.H., Green M.R., Bateman R.H. Utilizing Matrix-Assisted Laser Desorption/Ionization-Collision Induced Dissociation for the Generation of Structural Information from Poly(Alkyl Methacrylate)s. J. Am. Soc. Mass Spectrom. 1997, 8:1206-1213.
42. Jackson A.T., Slade S.E., Scrivens J.H. Characterization of Poly(Alkyl Methacrylate)s by Means of Electrospray Ionization-Tandem Mass Spectrometry (ESI-MS/MS). Int. J. Mass Spectrom. 2004, 238:265-277.