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Volumn 46, Issue 22, 2010, Pages 3991-3993

Spin trapping of radical intermediates in gas phase catalysis: Cyclohexane oxidation over metal oxides

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOHEXANE; METAL OXIDE; OXYGEN; RADICAL;

EID: 77952788745     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/c0cc00157k     Document Type: Article
Times cited : (19)

References (33)
  • 15
    • 49549170009 scopus 로고
    • H = 16.08 G are quite unusual for a 'pure' carbon type radical and it could also be consistent with an acyl or an allyl radical (see ref. 11). It should be noted that while formation of allyl radicals is ascertained for n-alkyl hydrocarbons oxidation, such as propane, formation of allyl radical in the cyclohexane oxidation has only been postulated in the gas phase oxidation below 400 °C (see:
    • E. G. Janzen C. A. Evans J.-P. Liu J. Magn. Reson. 1973 9 513
    • (1973) J. Magn. Reson. , vol.9 , pp. 513
    • Janzen, E.G.1    Evans, C.A.2    Liu, J.-P.3
  • 18
    • 2942676526 scopus 로고    scopus 로고
    • Cleavage of C-H bond with direct coordination of H to the metal centre is considered operating in the liquid phase oxidation of cyclohexane in the presence of cobalt based organometallic complexes as catalysts. See ref. 5
    • A. Bhattacharya A. Mungikar Can. J. Chem. Eng. 2003 81 220
    • (2003) Can. J. Chem. Eng. , vol.81 , pp. 220
    • Bhattacharya, A.1    Mungikar, A.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.