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Volumn 12, Issue 10, 2010, Pages 2410-2413

Synthesis of alkyl alkynyl ketones by Pd/light-induced three-component coupling reactions of iodoalkanes, CO, and 1-alkynes

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNE; CARBON MONOXIDE; IODINATED HYDROCARBON; KETONE; PALLADIUM;

EID: 77952378090     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/ol1007668     Document Type: Article
Times cited : (111)

References (67)
  • 31
    • 77952382113 scopus 로고    scopus 로고
    • For recyclable reaction media and catalyst, see
    • For recyclable reaction media and catalyst, see
  • 38
    • 77952358759 scopus 로고    scopus 로고
    • For previous efforts on metal-catalyzed carbonylation under photoirradiation conditions, see
    • For previous efforts on metal-catalyzed carbonylation under photoirradiation conditions, see
  • 41
    • 77952358259 scopus 로고    scopus 로고
    • For atom transfer carbonylation reactions, see
    • For atom transfer carbonylation reactions, see
  • 45
    • 77952380633 scopus 로고    scopus 로고
    • Also see a review
    • Also see a review
  • 47
    • 77952391964 scopus 로고    scopus 로고
    • For radical/metal hybrid reactions, see
    • For radical/metal hybrid reactions, see
  • 51
    • 77952352893 scopus 로고    scopus 로고
    • Also see a review
    • Also see a review
  • 53
    • 77952385863 scopus 로고    scopus 로고
    • note
    • Acceleration by water may be concerned with the fact that in the absence of water the reaction mixture became a suspension due to the gradually formed amine-HI salt, which is supposed to prevent effective photoirradiation. In the presence of water, we observed that a clear solution was maintained during the photoirradiation reaction.
  • 56
    • 77952372039 scopus 로고    scopus 로고
    • For precedents of electron transfer from low-valent palladium and platinum complexes, see
    • For precedents of electron transfer from low-valent palladium and platinum complexes, see
  • 59
    • 77952411478 scopus 로고    scopus 로고
    • note
    • Miyaura and co-workers also proposed an electron transfer from Pd(0) to alkyl iodides to afford a radical pair (Pd(I)I + alkylradical); see ref 8b.
  • 60
    • 77952402846 scopus 로고    scopus 로고
    • For photogeneration of Pd radical from Pd dimer complex, see
    • For photogeneration of Pd radical from Pd dimer complex, see
  • 62
    • 77952379629 scopus 로고    scopus 로고
    • note
    • ̇C(O)Pd(II)I might exist as a persistent radical. For the persistent radical effect, see the following reviews


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.