A 3-D lanthanum-organic framework containing double chains: La2[NC5H3(CO2)2]3·3H2O

Inorganic Chemistry Communications

Volumn 13, Issue 5, 2010, Pages 649-652

  Tran, Dat T ^a   Chu, Deryn ^a   Oliver, Allen G ^b   Oliver, Scott R J ^b  

^a U S ARMY RESEARCH LABORATORY   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

3,5 Pyridinedicarboxylate; Double chains; Hydrothermal synthesis; Lanthanum; Metal organic framework; Zig zag chains

Indexed keywords

EID: 77952105336     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2010.03.010     Document Type: Article

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29. 2O (Alfa Aesar) and 0.30 g of PDCA (Aldrich, 95%) were added. After ca. 10 min stirring, the latter solution was added dropwise to the former using a plastic pipette and allowed to stir for another 10 min. The solution was then transferred to a 45 mL capacity Teflon-lined stainless steel autoclave. The autoclave was sealed and heated at 165 °C for 3 days. The crystals were collected by vacuum filtration, rinsed with deionized water and allowed to air-dry overnight. The crystal product weighed ca. 0.288 g (yield: 58.1%). Elemental analysis agrees very well with the structural formula. Analyzed percentages of C, H, and N were 30.84%, 1.77%, and 5.09%, compared with the values of 30.49%, 1.83%, and 5.08% calculated from the molecular formula, respectively.
30. 2 = 0.1268 for all 5729 data. Frames corresponding to an arbitrary sphere of data were collected using ω-scans of 0.3° counted for a total of 1 second per frame. Data were integrated by the program SAINT [25b] to a maximum θ-value of 31.17°. The data were corrected for Lorentz and polarization effects. Data were analyzed for agreement and possible absorption using XPREP [25c]. An empirical absorption correction based on comparison of redundant and equivalent reflections was applied using SADABS [25d]. The structure was solved by direct methods [25e] and expanded using Fourier techniques [25f].
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