Gas-phase synthesis of dimethyl carbonate from methanol and carbon dioxide over Co1.5PW12O40 keggin-type heteropolyanion

International Journal of Molecular Sciences

Volumn 11, Issue 4, 2010, Pages 1343-1351

  Aouissi, Ahmed ^a   Al Othman, Zeid Abdullah ^a   Al Amro, Amro ^a  

^a KING SAUD UNIVERSITY   (Saudi Arabia)

Author keywords

Carbon dioxide; Dimethyl carbonate; Direct synthesis; Heteropolyanion; Keggin structure; Methanol

Indexed keywords

CARBON DIOXIDE; CARBONIC ACID DERIVATIVE; CARBONIC ACID DIMETHYL ESTER; METHANOL; POLYANION; UNCLASSIFIED DRUG;

ARTICLE; ATMOSPHERIC PRESSURE; CHEMICAL REACTION; CONTROLLED STUDY; DIFFERENTIAL SCANNING CALORIMETRY; GAS; INFRARED SPECTROSCOPY; SYNTHESIS; TEMPERATURE; THERMOGRAVIMETRY; TIME; VELOCITY; X RAY DIFFRACTION;

CARBON DIOXIDE; DIMETHYL CARBONATE; DIRECT SYNTHESIS; HETEROPOLYANION; KEGGIN STRUCTURE; METHANOL;

ATMOSPHERIC PRESSURE; CARBON DIOXIDE; CATALYSIS; COBALT; FORMATES; GASES; METHANOL; OXIDES; PHOSPHORUS COMPOUNDS; TEMPERATURE; TUNGSTEN;

EID: 77951901448     PISSN: None     EISSN: 14220067     Source Type: Journal    
DOI: 10.3390/ijms11041343     Document Type: Article

References (26)

1. Pacheco M.A.; Marshall C.L. Review on Dimethyl carbonate manufacture and its characteristics as a fuel additive. Energy Fuels 1997, 11, 2-29.
2. Guo X.C.; Qin, Z.F.; Wang, G.F.; Wang, J.G. Critical temperatures and pressures of reacting mixture in synthesis of dimethyl carbonate with methanol and carbon dioxide. Chin. Chem. Lett. 2008, 19, 249-252.
3. Ono, Y. Catalysis in the production and reactions of dimethyl carbonate, an environmentally benign building block. Appl. Catal. A 1997, 155, 133-166.
4. Tundo, P.; Selva, M. The Chemistry of Dimethyl Carbonate. Acc. Chem. Res. 2002, 35, 706-716.
5. Richter, M.; Fait, M.J.G.; Eckelt, R.; Schneider, M.; Radnik, J.; Heidemann, D.; Fricke, R. Gas-phase carbonylation of methanol to dimethyl carbonate on chloride-free Cu-precipitated zeolite Y at normal pressure. J. Catal. 2007, 245, 11-24.
6. Delledonne, D.; Rivetti, F.; Romano, U. Developments in the production and application of dimethylcarbonate. Appl. Catal. A: Gen. 2001, 221, 241-251.
7. Shaikh, A.G.; Sivaram, S. Organic Carbonates. Chem. Rev. 1996, 96, 951-976.
8. Romano, U.; Tesei, R.; Mauri, M.M.; Rebora, P. Synthesis of Dimethyl Carbonate from Methanol, Carbon Monoxide, and Oxygen Catalyzed by Copper Compounds. Ind. Eng. Chem. Prod. Dev. 1980, 19, 396-403.
9. Choi, J.C.; Sakakura, T.; Sako, T. Reaction of Dialkyltin Methoxide with Carbon Dioxide Relevant to the Mechanism of Catalytic Carbonate Synthesis. J. Am. Chem. Soc. 1999, 121, 3793-3794.
10. Wu, X.L.; Xiao, M.; Meng, Y.Z.; Lu, Y.X. Direct synthesis of dimethyl carbonate (DMC) using Cu-Ni/VSO as catalyst. J. Mol. Catal. A: Chem. 2006, 249, 93-97.
11. Wu, X.L.; Xiao, M.; Meng, Y.Z.; Lu, Y.X. Direct synthesis of dimethyl carbonate on H3PO4 modified V2O5. J. Mol. Catal. A: Chem. 2005, 238, 158-162.
12. Jessop, P.G.; Ikariya, T.; Noyori, R. Homogeneous Catalysis in Supercritical Fluids. Science 1995, 269, 1065-1069.
13. Tundo, P.; Selva, M. The Chemistry of Dimethyl Carbonate. Acc. Chem. Res. 2002, 35, 706-716.
14. Omae, I. Aspects of carbon dioxide utilization. Catal. Today 2006, 115, 33-52
15. Bian, J.; Xiao, M.; Wang, S.J.; Lu, Y.X.; Meng, Y.Z.J. Novel application of thermally expanded graphite as the support of catalysts for direct synthesis of DMC from CH3OH and CO2. J. Colloid. Interface Sci. 2009, 334, 50-57.
16. Bian, J.; Xiao, M.; Wang, S.; Wang, X.; Lu, Y.; Meng, Y. Highly effective synthesis of dimethyl carbonate from methanol and carbon dioxide using a novel copper-nickel/graphite bimetallic nanocomposite catalyst. Chem. Eng. J. 2009, 147, 287-296.
17. Wu, X.L.; Xiao, M.; Meng, Y.Z.; Lu, Y.X. Direct synthesis of dimethyl carbonate on H3PO4 modified V2O5. J. Mol. Catal. A. Chem. 2005, 238, 158-162.
18. Rocchiccioli-Deltcheff, C.; Fournier, M.; Franck, R.; Thouvenot, R. Vibrational nvestigations of polyoxometalates. Evidence for anion-anion interactions in molybdenum(VI) and tungsten(VI) compounds related to the Keggin structure. Inorg. Chem. 1983, 22, 207-216.
19. Rocchiccioli-Deltcheff, C.; Fournier, M. Catalysis by Polyoxometalates. Part 3,-Inflence of Vanadium (V) on the thermal Stability of 12-Metallophosphoric Acids from In Situ Infrared Studies. J. Chem. Soc. Faraday Trans. 1991, 87, 3913-3920.
20. Fournier, M.; Feumi-Jantou, C.; Rabia, C.; Herve, G.; Launay, S. Polyoxometalates Catalyst Materials: X-Ray Thermal Stability Study of Phosphorus-containing Heteropolyacids H3+xPM12-xVxO40.13-14H2O (M=Mo, W; x=0-1). J. Mater. Chem. 1992, 2, 971-978.
21. Gao, R.; Chen, H.; Le, Y.; Dai, W.-L.; Fan K. Highly active and selective Cs2.5H0.5PW12O40/SBA-15 composite material in the oxidation of cyclopentane-1,2-diol to glutaric acid by aqueous H2O2. Appl. Catal. 2009, 352, 61-65.
22. Fuchs, V.M.; Pizzio, L.R.; Blanco, M.N. Synthesis and characterization of aluminum or copper tungstophosphate and tungstosilicate immobilized in a polymeric blend. Eur. Polym. J. 2008, 44, 801-807.
23. Cabello, C.I.; Egusquiza, M.G.; Botto, I.L.; Minelli, G. Heteropolyoxotungstates containing a wide catalytic target: reducibility and thermal stability. Mater. Chem. Phys. 2004, 87, 264-274.
24. Fu, Y.; Zhu, H.; Shen, J. Thermal decomposition of dimethoxymethane and dimethyl carbonate catalyzed by solid acids and bases. Thermochim. Acta. 2005, 434, 88-92.
25. Zhao, T.; Han, Y.; Sun,Y. Novel reaction route for dimethyl carbonate synthesis from CO2 and methanol. Fuel Proces. Tech. 2000, 62, 187-194.
26. Wang, X.J.; Xiao, M.; Wang, S.J.; Lu, Y.X.; Meng, Y.Z. Direct synthesis of dimethyl carbonate from carbon dioxide and methanol using supported copper (Ni, V, O) catalyst with photo-assistance. J. Mol. Catal. A: Chem. 2007, 278, 92-96