Enhanced ion anisotropy by nonconventional coordination geometry: Single-chain magnet behavior for a [{FeIIL}2{Nb IV(CN)8}] helical chain compound designed with heptacoordinate FeII

Journal of the American Chemical Society

Volumn 132, Issue 17, 2010, Pages 6047-6056

  Venkatakrishnan, Thengarai S ^a,b   Sahoo, Shaon ^c,d   Bréfuel, Nicolas ^a,b   Duhayon, Carine ^a,b   Paulsen, Carley ^e   Barra, Anne Laure ^c   Ramasesha, S ^c   Sutter, Jean Pascal ^a,b  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^b UNIVERSITÉ DE TOULOUSE   (France)

^c INDIAN INSTITUTE OF SCIENCE   (India)

^d CNRS   (France)

^e GRENOBLE HIGH MAGNETIC FIELD LABORATORY   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIFERROMAGNETICS; COERCIVE FIELD; COORDINATION GEOMETRY; CYANO-BRIDGED; FERRIMAGNETIC CHAINS; HELICAL CHAINS; HETEROMETALLICS; HETERONUCLEAR; HIGH FIELD EPR; ION ANISOTROPY; LOW TEMPERATURES; MACROCYCLES; MAGNETIC AVALANCHES; MAGNETIC BEHAVIOR; MAGNETIC EXCHANGE COUPLING; MAGNETIC FEATURES; NONCOLLINEAR; PARENT COMPOUNDS; POLYMERIC STRUCTURES; SINGLE-CHAIN MAGNET; SINGLE-CRYSTAL AND POWDER; SLOW RELAXATIONS; SPIN ARRANGEMENT; ZERO-FIELD SPLITTING PARAMETERS;

ANISOTROPY; ANTIFERROMAGNETISM; CRYSTAL STRUCTURE; EXCHANGE INTERACTIONS; HYSTERESIS; ISING MODEL; MAGNETIC SUSCEPTIBILITY; MAGNETIZATION; MAGNETS; METALLIC COMPOUNDS; MOLYBDENUM; X RAY DIFFRACTION;

MAGNETIC MATERIALS;

FERROUS ION; MACROCYCLIC COMPOUND;

ANISOTROPY; ARTICLE; CRYSTAL STRUCTURE; HYSTERESIS; LOW TEMPERATURE; MAGNETISM; POLYMERIZATION; X RAY DIFFRACTION;

EID: 77951688141     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja9089389     Document Type: Article

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