Atomic-scale insight into the origin of pyridine inhibition of MoS2-based hydrotreating catalysts

Journal of Catalysis

Volumn 271, Issue 2, 2010, Pages 280-289

  Temel, Burcin ^a   Tuxen, Anders K ^b   Kibsgaard, Jakob ^b   Topsøe, Nan Yu ^a   Hinnemann, Berit ^a   Knudsen, Kim G ^a   Topsøe, Henrik ^a   Lauritsen, Jeppe V ^b   Besenbacher, Flemming ^b  

^a HALDOR TOPSØE A S   (Denmark)

^b AARHUS UNIVERSITY   (Denmark)

Author keywords

Density functional theory; Hydrodesulfurization; Hydrotreating catalysis; Infra red Spectroscopy; Inhibition; MoS2; Pyridine; Pyridinium; Scanning tunneling microscopy (STM)

Indexed keywords

ADSORBED SPECIES; ADSORPTION MODES; ADSORPTION SITE; ALUMINA-SUPPORTED; ATOMIC SCALE; BASIC NITROGEN; BRIM SITES; DENSITY FUNCTIONAL THEORY CALCULATIONS; DFT STUDY; DIRECT OBSERVATION; HYDRO DESULFURIZATIONS; HYDROGENATION REACTIONS; HYDROTREATING CATALYSIS; HYDROTREATING CATALYSTS; INHIBITION EFFECT; IR-SPECTROSCOPY; N-COMPOUNDS; PROTON AFFINITY; PYRIDINE ADSORPTION; PYRIDINE MOLECULES; PYRIDINIUM; SCANNING TUNNELING MICROSCOPY (STM); STM IMAGES; VIBRATIONAL MODES;

ADSORPTION; ATOMS; CATALYSIS; CATALYSTS; DENSITY FUNCTIONAL THEORY; EXPERIMENTS; HYDRODESULFURIZATION; HYDROGENATION; MOLYBDENUM COMPOUNDS; PYRIDINE; SCANNING; WIND TUNNELS;

SCANNING TUNNELING MICROSCOPY;

EID: 77951133873     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2010.02.007     Document Type: Article

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