Chemistry and effects of polyphosphoric acid on the microstructure, molecular mass, glass transition temperatures and performance grades of asphalts

Asphalt Paving Technology: Association of Asphalt Paving Technologists-Proceedings of the Technical Sessions

Volumn 78, Issue , 2009, Pages 455-484

  Masson, J F ^a   Collins, P ^a   Woods, J R ^a   Bundalo Perc, S ^a   Margeson, J ^a  

^a NATIONAL RESEARCH COUNCIL CANADA   (Canada)

Author keywords

Asphalt; Bitumen; Chemistry; Polyphosphoric acid; Reactions; Rheology

Indexed keywords

BINDER PROPERTIES; GLASS TRANSITION TEMPERATURE; HIGH TEMPERATURE PERFORMANCE; HYDROGEN BOND NETWORKS; MALTENES; MODEL COMPOUND; PERFORMANCE GRADE; PHYSICO-CHEMICALS; POLYPHOSPHORIC ACID; POLYPHOSPHORIC ACIDS; SERVICE TEMPERATURE; STERIC HARDENING;

ACIDS; ASPHALT; ASPHALTENES; BINDERS; ELASTICITY; GLASS; GRAFTING (CHEMICAL); HYDROGEN BONDS; PAVEMENTS; PLASTICITY; RHEOLOGY; SUPERCONDUCTING TRANSITION TEMPERATURE; SYNTHESIS (CHEMICAL); VISCOSITY;

GLASS TRANSITION;

EID: 77951128357     PISSN: 02702932     EISSN: None     Source Type: Conference Proceeding    
DOI: None     Document Type: Conference Paper

References (42)

1. J-F. Masson, "Brief Review of the Chemistry of Polyphosphoric Acid (PPA) and Bitumen," Energy and Fuels, Vol.22, pp. 2637-2640 (2008). Corrections in Vol. 22, p. 3560 (2008).
2. G. L. Baumgardner, J-F Masson, J. R. Hardee, A. M. Menapace, and A. G. Williams, "Polyphosphoric Acid Modified Asphalt: Proposed Mechanisms," Proc. Assoc. Asphalt Paving Technol, Vol.74, pp. 283-305 (2005).
3. rd Euraphalt and Eurobitume Congress, Vienna, Paper 334, book 1, pp. 733-745. (2004)
4. Y. Edwards, Y. Tasdemir, and U. Isacsson, "Rheological Effects of Commercial Waxes and Polyphosphoric Acid in Bitumen 160/200-High and Medium Temperature Performance," Construction and Building Materials, Vol.21, pp. 1899-1908 (2007).
5. I. Kodrat, D. Sohn and S. A. M. Hesp, "Comparison of Polyphosphoric Acid-Modified Asphalt Binders with Straight and Polymer-Modified Materials," Transportation Research Record 1998, pp. 47-55 (2007).
6. Y. Edwards, Y. Tasdemir, and U. Isacsson, "Rheological Effects of Commercial Waxes and Polyphosphoric Acid in Bitumen 160/200-Low Temperature Performance," Fuels, Vol.85, pp. 898-997 (2006).
7. J-F. Masson and M. Gagné, "Ionic Pairs in Polyphosphoric Acid (PPA)-Modified Bitumen: Insights from Model Compounds," Energy and Fuels, Vol. 22, pp. 3390-3394 (2008).
8. J-F. Masson and M. Gagné, "Polyphosphoric acid (PPA)-Modified Bitumen: Disruption of the Asphaltenes Network Based on the Reaction of Non-Basic Nitrogen with Polyphosphoric Acid," Energy and Fuels, Vol.22, pp. 3402-3406 (2008).
9. J-F. Masson, M. Gagné, G. Robertson, and P. Collins, "Reactions of Polyphosphoric Acid and Bitumen Model Compounds with Oxygenated Functional Groups: Where is the Phosphorylation," Energy and Fuels, Vol.22, pp. 4151-4157 (2008)
10. J-F. Masson and P. Collins, "FTIR Study of the Reaction of Polyphosphoric acid and Model Bitumen Sulfur Compounds," Energy and Fuels Vol. 23, pp. 440-442 (2009)
11. D. Jones IV, "Materials Reference Library for Asphalt Cements: A Concise Data Compilation". Report SHRP-A-645, Strategic Highway Research Program, National Research Council: Washington DC, 1993. Available online at http://onlinepubs.trb.org/Onlinepubs/shrp/SHRP-A-645.pdf. Accessed June 14, 2008.
12. J-F. Masson, V. Leblond, and J. Margeson, "Bitumen Morphologies by Phase-Detection Atomic Force Microscopy," J. Microscopy Vol. 221, pp. 17-29 (2006).
13. J-F. Masson, G. Polomark and P. Collins, "Glass Transitions and Amorphous Phases in SBS-Bitumen Blends," Thermochimica Acta, Vol.436, pp. 96-100 (2005).
14. AASHTO T313-04, "Determining the Flexural Creep Stiffness of Asphalt Binder Using the Bending Beam Rheometer (BBR)".
15. AASHTO T315-04, "Determining the Rheological Properties of Asphalt Binder Using a Dynamic Shear Rheometer (DSR)"
16. J-F. Masson, V. Leblond, J. Margeson, and S. Bundalo-Perc, "Low-Temperature Bitumen Stiffness and Viscous Parafinnic Nano- and Micro-Domains by Cryogenic AFM and PDM," J. Microscopy Vol. 227, pp. 191-202 (2007).
17. L. Loeber, O. Sutton, J. Morel, J-M. Valleton, and G. Muller, "New Direct Observations of Asphalts and Asphalt Binders by Scanning Electron Microscopy and Atomic Force Microscopy." J. Microscopy. Vol.182, pp. 32-39 (1996).
18. A. T. Pauli, J. F. Branthaver, R. E. Robertson, and W. Grimes, "Atomic Force Microscopy Investigation of SHRP Asphalts". Symposium on Heavy Oil and Resid Compatibility and Stability, pp. 110-114. (2001) Petroleum Chemistry Division, American Chemical Society, San Diego, California.
19. J. A. S. Pribanic, M. Emmelin, G. N. King, "Use of a Multiwavelength UV-VIS Detector with HP-GPC to Give a Three-Dimensional View of Bituminous Materials," Transportation Research Record, Vol.1228, pp. 168-176 (1989).
20. J. B. Lambert, H. F. Shurvell, L. Verbit, R. G. Cooks, and G. H. Stout, "Organic Structural Analysis," Macmillan Publishing Co., Inc: New York, (1976).
21. D. L.Pavia, G. M. Lampman,v and G. S. Kriz, "Introduction to Spectroscopy," Saunders College Publishing: Philadelphia, (1979).
22. D. J. Pasto, and C. R. Johnson, "Organic Structure Determination," Prentice-Hall, Englewood Cliffs, NJ, Chapter 3 (1969).
23. J. G. Speight, "The Chemistry and Technology of Petroleum," 3rd Ed., Marcel Dekker, New York. (1999)
24. S. Peramanu, B. B. Pruden, and P. Rahimi, "Molecular Weight and Specific Gravity Distributions for Athabasca and Cold Lake Bitumens and their Saturates, Aromatic, Resin and Asphaltene Fractions." Ind. Eng. Chem. Res. Vol.38, pp. 3121-3130 (1999).
25. J. M. Krishnan and K. R. Rajagopal, "On the Mechanical Behavior of Asphalt," Mechanics of Materials, Vol.37, pp. 1085-1100 (2005).
26. J. J. Breen and J. E. Stephens, "The Interrelationship Between The Glass Transition Temperature and Molecular Characteristics of Asphalt," Proc. AAPT Vol. 36, pp. 706-712 (1969).
27. P. Claudy, J.-M. Létoffé, G. N. King, B. Brûlé, J.-P. Planche, "Characterization of Paving Grade Asphalts by Differential Scanning Calorimetry," Fuel Science and Technology International Vol9, pp.71-92 (1991).
28. P. Chambrion, R. Bertau, and P. Ehrburger, "Characterization of Bitumen by Differential Scanning Calorimetry," Fuel Vol. 2, pp. 144-148 (1996).
29. J-F. Masson, G. M. Polomark, and P. Collins, "Time-Dependent Microstructure of Bitumen and Its Fractions by Modulated Differential Scanning Calorimetry," Energy and Fuels, Vol.16, pp. 470-476 (2002).
30. J-F. Masson and G. M. Polomark, "Bitumen Microstructure by Modulated Differential Scanning Calorimetry," Thermochim. Acta, Vol.374, pp.105-114 (2001), and Erratum in Vol. 413, p. 273 (2004).
31. J-F. Masson and S. Bundalo-Perc, "Calculation of Smoothing Factors for the Comparison of DSC Results," Journal of Thermal Analysis and Calorimetry, Vol.90, pp. 639-643 (2007).
32. J. E. Mark, A. Eisenberg, W. W. Graessley, L. Mandelkern, E. T. Samulski, J. L. Koenig, G. D. Wignall, "The Glassy State and the Glass Transition," in Physical Properties of Polymers, American Chemical Society, Washington, D.C., 2nd ed., (1993)
33. T. G. Mezger, "The Rheology Handbook," Vincentz, Hannover, p. 147 (2002).
34. J-F. Masson, P. Collins, and G. Polomark, "Steric Hardening and the Ordering of Asphaltenes in Bitumen," Energy and Fuels, Vol.19, pp. 120-122 (2005).
35. L. A. Utracki, "Polymer Alloys and Blends," Hanser Publishers, New York, (1989).
36. K. R. Lange, "Surfactants, A Practical Handbook," Hanser Gardner Publications, Inc., Cincinnati, (1999).
37. J. F. Mackay, J. H. Weber and D. R. Latham, "Characterization of Nitrogen Bases in High-Boiling Petroleum Distillates," Analytical Chemistry, Vol.48, pp. 891-898 (1976).
38. F. P. Richter, P. D. Caesar, S. L. Meisel and R. D. Offenhauer, "Distribution of Nitrogen in Petroleum According to Basicity," Industrial and Engineering Chemistry, pp. 2601-2605 (1952).
39. D. K. Albert, "Determination of Nitrogen Compound Types and Distribution in Petroleum by Gas Chromatography with a Coulometric Detector," Analytical Chemistry, Vol.39, pp. 1113-1117 (1967).
40. R. Maldonado, M. Falkiewicz, G. Bazi, K. Grzybowski, "Asphalt Modification With Polyphosphoric Acid," Proceedings of the Canadian Technical Asphalt Association, Vol.51, pp. 163-178 (2006).
41. J. C. Petersen and H. Plancher, "Model Studies and Interpretive Review of the Competitive Adsorption and Water Displacement of Petroleum Asphalt Chemical Functionalities on Mineral Aggregate Surfaces", Petroleum Science and Technology, Vol.16, pp. 89-131 (1998).
42. J. Youtcheff, T. Arnold, and S. Needham, "Update on THHRC Research Into the Phosphoric Acid Modification of Asphalt," Presentation to users-producers group, October 2007.