Facile activation of dihydrogen by a phosphinito-bridged Pt(I)-Pt(I) complex

Journal of the American Chemical Society

Volumn 132, Issue 13, 2010, Pages 4752-4765

  Mastrorilli, Piero ^a   Latronico, Mario ^a   Gallo, Vito ^a   Polini, Flavia ^a   Re, Nazzareno ^b   Marrone, Alessandro ^b   Gobetto, Roberto ^c   Ellena, Silvano ^c  

^a POLITECNICO DI BARI   (Italy)

^b UNIVERSITY OF CHIETI   (Italy)

^c UNIVERSITY OF TURIN   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

AMBIENT CONDITIONS; COORDINATION PLANE; DFT CALCULATION; DFT STUDY; DIHYDRIDE COMPLEXES; DIHYDROGEN; DIHYDROGEN COMPLEXES; HETEROLYTIC SPLITTING; HYDRIDE LIGANDS; HYDROGEN ATOMS; HYDROGEN BRIDGES; HYDROGEN SHIFTS; INTERMOLECULAR EXCHANGE; INTRAMOLECULAR MECHANISM; PT-PT BONDS; STABLE ISOMERS;

COORDINATION REACTIONS; HYDROGEN; ISOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXYGEN; PLATINUM; SULFUR COMPOUNDS;

PLATINUM COMPOUNDS;

CITRATE SODIUM; HYDROGEN; OXYGEN; PLATINUM; PLATINUM COMPLEX; SOLVENT;

ARTICLE; CHEMICAL BOND; DEHYDROGENATION; DENSITY FUNCTIONAL THEORY; HYDROGENATION; ISOMERIZATION; NUCLEAR OVERHAUSER EFFECT; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; THERMODYNAMICS;

COMPUTER SIMULATION; HYDROGEN; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, CHEMICAL; MOLECULAR STRUCTURE; ORGANOPLATINUM COMPOUNDS; STEREOISOMERISM;

EID: 77950797999     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja909747r     Document Type: Article

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