Is Mo involved in hydride binding by the four-electron reduced (E 4) intermediate of the nitrogenase MoFe protein?

Journal of the American Chemical Society

Volumn 132, Issue 8, 2010, Pages 2526-2527

  Lukoyanov, Dmitriy ^a   Yang, Zhi Yong ^c   Dean, Dennis R ^b   Seefeldt, Lance C ^c   Hoffman, Brian M ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

^b VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY   (United States)

^c UTAH STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC TURNOVER; COFACTORS; CONFORMATIONAL CHANGE; COUPLING COEFFICIENT; EPR SIGNALS; FE-IONS; FOUR ELECTRONS; HYPERFINE COUPLING; INTERMEDIATE STATE; LOWER BOUNDS; RESTING STATE; SUBSTRATE INTERACTION;

ELECTRONIC PROPERTIES; IRON COMPOUNDS; PROTEINS;

MOLYBDENUM;

AMIDE; CITRIC ACID; ISOLEUCINE; METAL COMPLEX; MOLYBDENUM; NITROGENASE; PROTON; MOLYBDENUM IRON PROTEIN;

ARTICLE; BINDING KINETICS; CATALYSIS; ELECTRON; MOLECULAR INTERACTION; PROTEIN CONFORMATION; REDUCTION; AZOTOBACTER VINELANDII; CHEMICAL STRUCTURE; CHEMISTRY; ELECTRON SPIN RESONANCE; ENZYME SPECIFICITY; ENZYMOLOGY; METABOLISM; OXIDATION REDUCTION REACTION; PROTEIN BINDING;

AZOTOBACTER VINELANDII; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONS; MODELS, MOLECULAR; MOLYBDENUM; MOLYBDOFERREDOXIN; OXIDATION-REDUCTION; PROTEIN BINDING; SUBSTRATE SPECIFICITY;

EID: 77950397409     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja910613m     Document Type: Article

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