Os(VIII) as an efficient homogeneous catalyst for the oxidative decolorization of methylene blue dye with alkaline chloramine-T: Kinetic, mechanistic, and platinum metal ions reactivity studies

Industrial and Engineering Chemistry Research

Volumn 49, Issue 7, 2010, Pages 3137-3145

  Vinod, K N ^a   Puttaswamy, ^a   Ninge Gowda, K N ^a  

^a BANGALORE UNIVERSITY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION PARAMETER; ALKALINE MEDIUM; BIOLOGICAL APPLICATIONS; CATALYZED REACTIONS; CHLORAMINE-T; DIELECTRIC CONSTANTS; EFFICIENT PROCESS; ELECTRONIC CONFIGURATION; FIRST-ORDER DEPENDENCE; HARMFUL EFFECTS; HOMOGENEOUS CATALYST; INDUSTRIAL WASTEWATERS; KINETICS OF OXIDATION; LOW COSTS; MANUFACTURING INDUSTRIES; METHYLENE BLUE; METHYLENE BLUE DYE; OXIDATIVE DECOLORIZATION; PHYSICOCHEMICAL PROCESS; RATE LAWS; REDOX SYSTEMS; RELATIVE REACTIVITIES; SOLVENT ISOTOPE EFFECTS; THIAZINE DYES; UNCATALYZED REACTIONS;

CATALYSTS; CHEMICAL OXYGEN DEMAND; DYES; IRIDIUM; ISOTOPES; METAL IONS; METHANOL; ORGANIC SOLVENTS; OSMIUM; PALLADIUM; PALLADIUM COMPOUNDS; PLATINUM; REACTION RATES; RHODIUM; TEXTILE INDUSTRY; WASTEWATER;

TEXTILE PROCESSING;

EID: 77950384091     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie900628r     Document Type: Article

References (47)

1. Shah, K. M. Handbook on Synthetic Dyes and Pigments; Multitech Publisher: Mumbai, India, 1998; Vol.1, p 117.
2. Santus, R.; Kohen, C.; Kohen, E.; Reyftmann, J. P.; Morliere, P.; Dubertret, L.; Tocci, P. M. Permiation of Lysosomal Membranes in the Course of Photosensitization with Methylene Blue and Hematoporphyrin: Study by Cellular Microspectroflurometer. J. Photochem. Photobiol. 1983, 38, 71.
3. Muthakia, G. K. Uncatalyzed and V(V) Catalyzed Reaction of Methylene Blue with Potassium Bromate in Sulfuric Acid. J. Phy. Chem. 1989, 93, 4751.
4. Robison, T.; McMillan, G.; Marchant, R.; Nigam, P. Remediation of Dyes in Textile Effluent: A Critical Review on Current Treatment Technologies with a Proposed Alternative. Bioresour. Technol. 2001, 77, 247.
5. 2 and UV/Acetone Oxidation Processes. Desalination 2005, 181, 225.
6. Dutta, K.; Mukhopadhyay, S.; Bhattacharjee, S.; Chaudhuri, B. Chemical Oxidation of Methylene Blue Using a Fenton-like Reaction. J. Hazard. Mater. 2001, B84, 57.
7. Kling, S. H.; Neto, J. S. Oxidation of Methylene Blue by Crude Lignin Peroxidase from Phanerochaete chrysosporium. J. Biotechnol. 1991, 21, 295.
8. Gao, L.; Zhai, Y.; Ma, H.; Wang, B. Degradation of Cationic Dye Methylene Blue by Ozonation Assisted with Kaolin. App l. Clay Sci. 2009, 46, 226.
9. Campbell, M. M.; Johnson, G. Chloramine-T and Related NHalogeno- N-Metallo Reagents. Chem. Rev. 1978, 78, 65.
10. Benerji, K. K.; Jayaram, B.; Mahadevappa, D. S. Mechanistic Aspects of Oxidation by N-Metallo-N-haloarylsulfonamides. J. Sci. Ind. Res. 1987, 46, 65.
11. Geetanjali, A.; Chloramine, T. Chloramine-T (Sodium N-Chlorop- toluenesulfonamide). Synlett. 2005, 18, 2857.
12. Kolvari, E. A.; Choghamarani, G.; Salehi, P.; Zolfigol, M. A. Application of N-Halo Reagents in Organic Synthesis. J. Iran. Chem. Soc. 2007, 4, 126.
13. Puttaswamy; Jagadeesh, R. V. Ruthenium(III)-Catalyzed Mechanistic Investigation of Oxidation of an Azo Dye by Sodium N-Haloarenesulfonamidates in Acid Medium: A Comparative Spectrophotometric Kinetic Study. Appl. Catal. A: Gen. 2005, 292, 259.
14. Puttaswamy; Vinod, K. N.; Ningegowda, K. N. Oxidation of C.I. Acid Red 27 by Chloramine-T in Perchloric Acid Medium: Spectrophotometric, Kinetic, and Mechanistic Approaches. Dyes Pigm. 2008, 78, 131.
15. Schrauzer G. N. Transition Metals in Homogeneous Catalysis; Marcel Dekker: New York, 1971.
16. Cotton, F. A.; Wilkinson, G.; Murillo, C. A.; Bochmann, M. Advanced Inorganic Chemistry, 6th ed.; J. Wiley & Sons, Inc: New York, 1999.
17. Griffith, W. P. The Chemistry of Rare Platinum Metals; Interscience: New York, 1967.
18. Silverton, J. V.; Dansette, P. M.; Silverton, D. M. J. Oxidation of 4,5-Dihydrobenzo[a]pyrene with Osmium Tetroxide. Stereochemistry of a Substituted K-Region Diol. Tetrahedron Lett. 1976, 17, 1557.
19. Morris, J. C.; Salazar, J. R.; Wineman, M. A. Equilibrium Studies on Chloro Compounds: The Ionization Constant of N-Chloro-p-toluenesulfonamide. J. Am. Chem. Soc. 1948, 70, 2036.
20. Stall, E. Thin Layer Chromatography-A Laboratory Handbook; Springer-Verlag: New York, 1969; Vol.508, p 514.
21. Akerloff, G. Dielectric Constants of Some Organic Solvents-Water Mixture at Various Temperatures. J. Am. Chem. Soc. 1932, 54, 4125.
22. Murthy, A. R. V.; Rao, B. S. Oxidation by Chloramine-T. II. Redox Potential of Chloramine-T-Sulfonamide Systems. Proc. Indian Acad. Sci., Sect. A. 1952, 35A, 69.
23. Hardy, F. F.; Johnston, J. P. The Interactions of N-Bromo- Nsodiobenzesulfonamide (Bromamine-B) with p-Nitrophenoxide Ion. J. Chem. Soc., Perkin Trans. 1973, 2, 742.
24. Bishop, E.; Jennings, V. J. Titrimetric Analysis with Chloramine-T: The Status of Chloramine-T as a Titrimetric Reagent. Talanta 1958, 1, 197.
25. Pryde, D. R.; Soper, F. G. The Direct Interchange of Chlorine in the Interaction of p-Toluenesulphonamide and N-Chloroacetamide. J. Chem. Soc. 1931, 1510.
26. Higuchi, T.; Ikeda, K.; Hussain, A. Mechanism and Thermodynamics of Chlorine Transfer Among Organochlorinating Agents. Part II. Reversible Disproportination of Chloramine-T. J. Chem. Soc. B. 1967, 546, and references therein.
27. Ruff, F.; Kucsman, A. Mechanism of Sulfilimine Formation. III. Kinetic Study of the Reaction of Some Methyl Aryl Sulfides and Chloramine-T. Acta Chim. Acad. Sci. Hung. 1969, 62, 438.
28. Musharn, S. P.; Sanehi, R; Agarwal, M. C. Os(VIII) Catalyzed Oxidation of Acetone and Ethyl Methyl Ketone by Chloramine-T. Z. Naturforsch. 1972, 27B, 1161.
29. Puttaswamy; Jagadeesh, R. V. Mechanistic Investigation of Oxidation of Isatins by Sodium-N-chlorobenzenesulfonamide in Alkaline Medium: A Kinetic Study. Cent. Eur. J. Chem. 2005, 3, 482.
30. Singh, A. K.; Saxena, S.; Saxena, M.; Gupta, R.; Mishra, R. K. Kinetics and Mechanism of Oxidation of m-Cresol by Osmium Tetroxide in Alkaline Medium. Indian J. Chem. 1988, 27A, 438.
31. Gnana Rani, D. F.; Pushparaj, F. J. M.; Alphonse, I.; Rangappa, K. S. Kinetics and Mechanism of Oxidation of 4-Oxoacids by Hexacyanoferrate( III) Catalyzed by Os(VIII). Indian J. Chem. 2002, 41B, 2153.
32. Tripathi, R.; Upadhyay, S. K. Kinetics of Oxidation of Reducing Sugars by Catalytic Amount of Os(VIII) in Presence of Periodate. Int. J. Chem. Kinet. 2004, 36, 441.
33. Mackay, K. M.; Mackay, R. A. Introduction to Modern Inorganic Chemistry, 4th ed.; Prentice Hall: Englewood Cliffs, NJ, 1989, 259.
34. Cotton, F. A.; Wilkinson, G.; Gaus, P. L. Basic Inorganic Chemistry, 3rd ed.; Wiley & Sons: New York, 1995, 600.
35. Griffith, W. P. Osmium and Its Compounds. Q. Rev. 1965, 19, 254.
36. Puttaswamy; Vaz, N. Ru(III) and Os(VIII) Catalyzed Oxidation of 2-Thiouracil by Bromamine-B in Acid and Alkaline Medium: A Kinetic and Mechanistic Study. Trans. Metal Chem. 2003, 28, 409.
37. Ramlingaiah; Jagadeesh, R. V. Puttaswamy. Os(VIII)-Catalyzed and Uncatalyzed Oxidation of Biotin by Chloramine-T in Alkaline Medium: Comparative Mechanistic Aspects and Kinetic Modeling. J. Mol. Catal. A: Chem. 2007, 265, 70.
38. Ardon, M. Oxidation of Ethanol by Ceric Perchlorate. J. Chem. Soc. 1957, 1811.
39. Collins, C. J.; Bowman, N. S. Isotope Effects in Chemical Reactions; Van-Nostrand: New York, 1970; p 267.
40. Kohen, A.; Limbach. Isotope Effects in Chemistry and Biology; CRC Press: FL, 2006; 827.
41. House, J. E. Principles of Chemical Kinetics; Wm. C. Brown: Boston, MA, 1997.
42. Entelis, S. G.; Tiger R. P. Reaction Kinetics in Liquid Phase;Wiley: New York, 1976.
43. Amis, E. S. SolVent Effects on Reaction Rates and Mechanisms; Academic: New York, 1966.
44. Reichardt, C. SolVent and SolVent Effects in Organic Chemistry, 3rd ed.; Wiley-VCH: New York, 2003; p 219.
45. Laidler, K. J. Reaction Kinetics, 2nd ed.; Tata Mc-Graw Hill: New Delhi, India, 1995.
46. Moelwyn-Hughes, E. A. The Kinetics of Reaction in Solutions: Clarendon Press: Oxford, U.K., 1947.
47. Puttaswamy; Jagadeesh, R. V. Ru(III), Os(VIII), Pd(II), and Pt(IV) Catalyzed Oxidation of Glycyl-glycine by Sodium N-Chloro-p-toluenesulfonamide: Comparative Mechanistic Aspects and Kinetic Modeling. J. Phy. Org. Chem. 2008, 21, 844.