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For a thermal [4+2]/Nazarov sequence, see: (p) Wada, E.; Fujiwara, I.; Kanemasa, S.; Tsuge, O. Bull. Chem. Soc. Jpn. 1987, 60, 325.
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For a thermal [4+2]/Nazarov sequence, see: (p) Wada, E.; Fujiwara, I.; Kanemasa, S.; Tsuge, O. Bull. Chem. Soc. Jpn. 1987, 60, 325.
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Observed dr values appear to be the result of thermodynamic equilibration of cis/trans Nazarov products under the reaction/workup conditions see Supporting Information, For early examples of catalytic stereoselective reprotonation of the Nazarov intermediate, see: Liang, G, Trauner, D. J. Am. Chem. Soc. 2004, 126, 9544
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Observed dr values appear to be the result of thermodynamic equilibration of cis/trans Nazarov products under the reaction/workup conditions (see Supporting Information). For early examples of catalytic stereoselective reprotonation of the Nazarov intermediate, see: Liang, G.; Trauner, D. J. Am. Chem. Soc. 2004, 126, 9544.
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