A stable silagermene (tBu3Si)2Si=Ge(Mes) 2 (Mes = 2,4,6-Trimethylphenyl): Synthesis, X-ray crystal structure, and thermal isomerization

Heteroatom Chemistry

Volumn 19, Issue 7, 2008, Pages 649-653

  Igarashi, Masayasu ^a   Lchinohe, Masaaki ^a   Sekiguchi, Akira ^a  

^a UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

SPECTROSCOPIC DATA; THERMAL ISOMERIZATIONS; X RAY CRYSTAL STRUCTURES;

CRYSTAL STRUCTURE; ELECTRON TRANSITIONS; GERMANIUM; ISOMERIZATION; ISOMERS; SILICON; SYNTHESIS (CHEMICAL);

X RAY CRYSTALLOGRAPHY;

EID: 77950336299     PISSN: 10427163     EISSN: 10981071     Source Type: Journal    
DOI: 10.1002/hc.20503     Document Type: Article

References (27)

1. Brook, A. G.; Abdesaken, F.; Gutekunst, B.; Gutekunst, G.; Kallury, R. K. J Chem Soc Chem Commun 1981, 191.
2. West, R.; Fink, M. J.; Michl, J. Science 1981, 214, 1343.
3. Lee, V. Ya.; Sekiguchi, A. Organometallics 2004, 23, 2822.
4. (a)Baines, K. M.; Cooke, J. A. Organometallics 1991, 10, 3419;
5. (b)Baines, K. M.; Cooke, J. A. Organometallics 1992, 11, 3487.
6. (a)Lee, V. Ya.; Ichinohe, M.; Sekiguchi, A.; Takagi, N.; Nagase, S. J Am Chem Soc 2000, 122, 9034;
7. (b)Lee, V. Ya.; Ichinohe, M.; Sekiguchi, A. J Organomet Chem 2003, 685, 168.
8. Ichinohe, M.; Arai, Y.; Sekiguchi, A.; Takagi, N.; Nagase, S. Organometallics 2001, 20, 4141.
9. (a)Lee, V. Ya.; Ichinohe,M.; Sekiguchi, A. J AmChem Soc 2000, 122, 12604;
10. (b)Lee, V. Ya.; Ichinohe, M.; Sekiguchi, A. J Organomet Chem 2001, 636, 41.
11. Igarashi, M.; Ichinohe, M.; Sekiguchi, A. J Am Chem Soc 2007, 129, 12660.
12. Iwamoto, T.; Masuda, H.; Kabuto, C.; Kira, M. Organometallics 2005, 24, 197.
13. (a)Fukawa, T.; Lee, V. Ya.; Nakamoto, M.; Sekiguchi, A. J Am Chem Soc 2004, 126, 11758;
14. (b)Lee, V. Ya.; Fukawa, T.; Nakamoto, M.; Sekiguchi, A.; Tumanskii, B. L.; Karni, M.; Apeloig, Y. J Am Chem Soc 2006, 128, 11643.
15. Sekiguchi, A.; Tanaka, T.; Ichinohe, M.; Akiyama, K.; Tero-Kubota, S. J Am Chem Soc 2003, 125, 4962.
16. (a) Trinquier,G.; Malrieu, J. P.; Riviére, P. J AmChem Soc 1982, 104, 4529
17. (b)Trinquier, G.; Malrieu, J. P. J Am Chem Soc 1989, 111, 5916;
18. (b)Goldberg, D. E.; Hitchcock, P. B.; Lappert, M. F.; Thomas, K. M.; Thorne, A. J.; Fjeldberg, T.; Haaland, A.; Schilling, B. E. R. J Chem Soc, Dalton Trans 1986, 2387
19. (c)Trinquier, G.; Malrieu, J. P. J Am Chem Soc 1987, 109, 5303;
20. (d)Liang, C.; Allen, C. C. J Am Chem Soc 1990, 112, 1039
21. (e)Karni,M.; Apeloig, Y. J Am Chem Soc 1990, 112, 8589;
22. (f)Chen, W.-C.; Su, M.-D.; Chu, S.-Y. Organometallics 2001, 20, 564
23. (g)Driess, M.; Grützmacher,H. Angew Chem, Int Ed 2007, 46, 6596.
24. Yokelson, B. H.; Maxka, J.; Siegel, A. D.; West, R. J Am Chem Soc 1986, 108, 4239.
25. Sekiguchi, A.; Izumi, R.; Lee, V. Ya.; Ichinohe, M. Organometallics 2003, 22, 1483.
26. Altomare, A.; Burla, M. C.; Camalli, M.; Cascarano, G.; Giacovazzo, C.; Guagliardi, A.;Moliterni, A. G. G.; Polidori, G.; Spagna, R. J Appl Crystallogr 1999, 32, 115.
27. Sheldrick, G. M. SHELX-97, Program for the Refinement of Crystal Structures; University of Göttingen: Göttingen, Germany, 1997