High-yield synthesis of gold microplates using amphiphilic block copolymers: Are lyotropic liquid crystals required?

Macromolecular Symposia

Volumn 289, Issue 1, 2010, Pages 18-24

  Sakai, Toshio ^a   Alexandridis, Paschalis ^a  

^a State University of New York ^*  (United States)

Author keywords

Block copolymers; Gold microplates; Lyotropic liquid crystals; Nanoparticles; Poly(ethylene oxide); Poly(propylene oxide); Template

Indexed keywords

AMBIENT CONDITIONS; AMPHIPHILIC BLOCK COPOLYMERS; AQUEOUS SOLUTIONS; AUTOREDUCTION; HIGH YIELD SYNTHESIS; LAMELLAR PHASIS; LYOTROPIC LIQUID CRYSTAL; MICROPLATES; PLURONIC L64; REDUCTANTS; TEMPLATE; TEMPLATING;

BLOCK COPOLYMERS; COPOLYMERIZATION; CRYSTALS; ETHYLENE; GOLD; HYDRATES; LIQUID CRYSTALS; NANOPARTICLES; PLASTIC PRODUCTS; POLYETHYLENE GLYCOLS; POLYETHYLENE OXIDES; SURFACE ACTIVE AGENTS; SYNTHESIS (CHEMICAL);

PROPYLENE;

EID: 77950303913     PISSN: 10221360     EISSN: 15213900     Source Type: Journal    
DOI: 10.1002/masy.200900003     Document Type: Article

References (43)

1. S. Eustis, M. A. El-Sayed, "Why Gold Nanoparticles Are More Precious Than Pretty Gold: Noble Metal Surface Plasmon Resonance and its Enhancement of the Radiative and Nonradiative Properties of Nanocrystals of Different Shapes" Chem. Soc. Rev. 2006, 35, 209-217.
2. J. Sharma, T. Imae, "Recent Advances in Fabrication of Anisotropic Metallic Nanostructures" J. Nanosci. Nanotech. 2009, 9, 19-40.
3. C. J. Johnson, E. Dujardin, S. A. Davis, C. J. Murphy, S. Mann, "Growth and Form of Gold Nanorods Prepared by Seed-Mediated, Surfactant-Directed Synthesis". J. Mater. Chem. 2002, 12, 1765-1770.
4. T. K. Sau, C. J. Murphy, "Room Temperature, High-Yield Synthesis of Multiple Shapes of Gold Nanoparticles in Aqueous Solution". J. Am. Chem. Soc. 2004, 126, 8648-8649.
5. Y. Shao, Y. Jin, S. Dong, "Synthesis of Gold Nanoplates by Aspartate Reduction of Gold Chloride". Chem. Commun. 2004, 1104-1105.
6. D. Ibano, Y. Yokota, T. Tominaga, "Preparation of Gold Nanoplates Protected by an Anionic Phospholipid". Chem. Lett. 2003, 32, 574-575.
7. M. Tsuji, M. Hashimoto, Y. Nishizawa, T. Tsuji, "Preparation of Gold Nanoplates by a Microwave-Polyol Method". Chem. Lett. 2003, 32, 1114-1115.
8. S. Porel, S. Singh, T. P. Radhakrishnan, "Polygonal Gold Nanoplates in a Polymer Matrix". Chem. Commun. 2005, 2387-2389.
9. X. Sun, S. Dong, E. Wang, "High-Yield Synthesis of Large Single-Crystalline Gold Nanoplates through a Polyamine Process". Langmuir 2005, 21, 4710-4712.
10. J.-U. Kim, S.-H. Cha, K. Shin, J. Y. Jho, J.-C. Lee, "Preparation of Gold Nanowires and Nanosheets in Bulk Block Copolymer Phases under Mild Conditions". Adv. Mater. 2004, 16, 459-464.
11. L. Wang, X. Chen, J. Zhan, Z. Sui, J. Zhao, Z. Sun, "Controllable Morphology Formation of Gold Nanoand Micro-Plates in Amphiphilic Block Copolymer-Based Liquid Crystalline Phase". Chem. Lett. 2004, 33, 720-721.
12. L. Wang, X. Chen, J. Zhan, Y. Chai, C. Yang, L. Xu, W. Zhuang, B. Jing, "Synthesis of Gold Nano-and Microplates in Hexagonal Liquid Crystals". J. Phys. Chem. B 2005, 109, 3189-3194.
13. C. Ni, P. A. Hassan, E. W. Kaler, "Structural Characteristics and Growth of Pentagonal Silver Nanorods Prepared by a Surfactant Method". Langmuir 2005, 21, 3334-3337.
14. M. R. Bockstaller, R. A. Mickiewicz, E. L. Thomas, "Block Copolymer Nnanocomposites: Perspectives for Tailored Functional Materials". Adv. Mater. 2005, 17, 1331-1349.
15. R. B. Grubbs, "Hybrid Metal-Polymer Composites from Functional Block Copolymers". J. Polym. Sci. Part A-Polym. Chem. 2005, 43, 4323-4336.
16. R. A. Vaia, J. F. Maguire, "Polymer Nanocomposites with Prescribed Morphology: Going beyond Nanoparticle-Filled Polymers". Chem. Mater. 2007, 19, 2736-2751.
17. J. Shan, H. Tenhu, "Recent Advances in Polymer Protected Gold Nanoparticles: Synthesis Properties and Applications". Chem. Commun. 2007, 4580-4598.
18. B. A. Rozenberg, R. Tenne, "Polymer-Assisted Fabrication of Nanoparticles and Nanocomposites". Progr. Polym. Sci. 2008, 33, 40-112.
19. "Amphiphilic Block Copolymers: Self-Assembly and Applications", P., Alexandridis, B. Lindman, Eds., Elsevier Science B. V, Amsterdam 2000.
20. G. J. d, A. A. Soler-Illia, E. L. Crepaldi, D. Grosso, C. Sanchez, "Block Copolymer-Templated Mesoporous Oxides". Curr. Opin. Colloid Interface Sci. 2003, 8, 109-126.
21. D. Zhao, J. Feng, Q. Huo, N. Melosh, G. H. Fredrickson, B. F. Chmelka, G. D. Stucky, "Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores". Science 1998, 279, 548-552.
22. P. Alexandridis, D. L. Zhou, A. Khan, "Lyotropic Liquid Crystallinity in Amphiphilic Block Copolymers: Temperature Effects on Phase Behavior and Structure for Poly (ethylene oxide)-b-Poly (propylene oxide)-b-Poly (ethylene oxide) Copolymers of Different Composition". Langmuir 1996, 12, 2690-2700.
23. P. Holmqvist, P. Alexandridis, B. Lindman, "Phase Behavior and Structure of Ternary Amphiphilic Block Copolymer-Alkanol-Water Systems: Comparison of Poly (ethylene oxide) Poly (propylene oxide) to Poly (-ethylene oxide) Poly (tetrahydrofuran) Copolymers". Langmuir 1997, 13, 2471-2479.
24. P. Alexandridis, U. Olsson, B. Lindman, "A Record Nine Different Phases (Four Cubic, Two Hexagonal, and One Lamellar Lyotropic Liquid Crystalline and Two Micellar Solutions) in a Ternary Isothermal System of an Amphiphilic Block Copolymer and Selective Solvents (Water and Oil) ". Langmuir 1998, 14, 2627-2638.
25. P. Alexandridis, "Structural Polymorphism of Poly (ethylene oxide)-Poly (propylene oxide) Block Copolymers in Nonaqueous Polar Solvents". Macromolecules 1998, 31, 6935-6942.
26. J. Zipfel, J. Berghausen, G. Schmidt, P. Lindner, P. Alexandridis, M. Tsianou, W. Richtering, "Shear Induced Structures in Lamellar Phases of Amphiphilic Block Copolymers". Phys. Chem. Chem. Phys. 1999, 1, 3905-3910.
27. R. Ivanova, B. Lindman, P. Alexandridis, "Evolution in Structural Polymorphism of Ppluronic F127 Poly (ethylene oxide)-Poly (propylene oxide) Bblock Ccopolymer in Ternary Systems with Water and Pharmaceutically Acceptable Organic Solvents: From "Glycols" to "Oils"". Langmuir 2000, 16, 9058-9069.
28. R. Ivanova, B. Lindman, P. Alexandridis, "Effect of Pharmaceutically Acceptable Glycols on the Stability of the Liquid Crystalline Gels Formed by Poloxamer 407 in Water". J. Colloid Interface Sci. 2002, 252, 226-235.
29. P. Alexandridis, "Structural Polymorphism of Poly (ethylene oxide)-Poly (propylene oxide) Block Copolymers in Nonaqueous Polar Solvents". Macromolecules 1998, 31, 6935-6942.
30. S.-H. Chen, C. Liao, E. Fratini, P. Baglioni, F. Mallamace, "Interaction, Critical, Percolation and Kinetic Glass Transitions in Pluronic L-64 Micellar Solutions". Colloids Surf. A 2001, 183, 95-111.
31. G. N. Karanikolos, N. L. Law, R. Mallory, A. Petrou, P. Alexandridis, T. J. Mountziaris, "Water-Based Synthesis of ZnSe Nanostructures Using Amphiphilic Block Copolymer Stabilized Lyotropic Liquid Crystals as Templates". Nanotechnology 2006, 17, 3121-3128.
32. G. N. Karanikolos, P. Alexandridis, T. J. Mountziaris, "Growth of ZnSe and CdSe Nanostructures in Self-Assembled Block Copolymer-Stabilized Templates". Materials Science and Engineering B-Advanced Functional Solid-State Materials 2008, 152, 66-71.
33. T. Sakai, P. Alexandridis, "Single-Step Synthesis and Stabilization of Metal Nanoparticles in Aqueous Pluronic Block Copolymer Solutions at Ambient Temperature". Langmuir 2004, 20, 8426-8430.
34. T. Sakai, P. Alexandridis, "Mechanism of Gold Metal Ion Reduction, Nanoparticle Growth and Size Control in Aqueous Amphiphilic Block Copolymer Solutions at Ambient Conditions". J. Phys. Chem. B 2005, 109, 7766-7777.
35. T. Sakai, P. Alexandridis, "Spontaneous Formation of Gold Nanoparticles in Poly (ethylene oxide) - Poly (propylene oxide) Solutions: Solvent Quality and Polymer Structure Effects". Langmuir 2005, 21, 8019-8025.
36. T. Sakai, P. Alexandridis, "Size-and Shape-Controlled Synthesis of Colloidal Gold through Autoreduction of Auric Cation by Poly (ethylene oxide)-Poly (propylene oxide) Block Copolymers in Aqueous Solutions at Ambient Conditions". Nanotechnology 2005, 16, S344-S353.
37. M. S. Bakshi, A. Kaura, P. Bhandari, G. Kaur, K. Torigoe, K. Esumi, "Synthesis of Colloidal Gold Nanoparticles of Different Morphologies in the Presence of Triblock Polymer Micelles". J. Nanosci. Nanotech. 2006, 6, 1405-1410.
38. S. Chen, C. Guo, G. H. Hu, J. Wang, J. H. Ma, X. F. Liang, L. Zheng, H. Z. Liu, "Effect of Hydrophobicity inside PEO-PPO-PEO Block Copolymer Micelles on the Stabilization of Gold Nanoparticles: Experiments". Langmuir 2006, 22, 9704-9711.
39. S. Chen, C. Guo, G. H. Hu, H. Z. Liu, X. F. Liang, J. Wang, J. H. Ma, L. Zheng, "Dissipative Particle Dynamics Simulation of Gold Nanoparticles Stabilization by PEO-PPO-PEO Block Copolymer Micelles". Colloid Poly. Sci. 2007, 285, 1543-1552.
40. K. Rahme, F. Gauffre, J. D. Marty, B. Payre, C. Mingotaud, "A Systematic Study of the Stabilization in Water of Gold Nanoparticles by Poly (ethylene oxide) - Poly (propylene oxide)-Poly (ethylene oxide) Ttriblock Copolymers". J. Phys. Chem. C 2007, 111, 7273-7279.
41. S. Goy-Lopez, E. Castro, P. Taboada, V. Mosquera, "Block Copolymer-Mediated Synthesis of Siza-Tunable Gold Nanospheres and Nanoplates". Langmuir 2008, 24, 13186-13196.
42. T. Sakai, P. Alexandridis, "Facile Preparation of Ag-Au Bimetallic Nanonetworks". Mater. Lett. 2006, 60, 1983-1986.
43. T. Sakai, P. Alexandridis, "Ag and Au Monometallic and Bimetallic Colloids: Morphogenesis in Amphiphilic Block Copolymer Solutions". Chem. Mater. 2006, 18, 2577-2583.