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See the Supporting Information for details on NOE studies.
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The structures of 7d and 7e were confirmed after O-O bond cleavage. See the Supporting Information, for complete details.
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The structures of 7d and 7e were confirmed after O-O bond cleavage. See the Supporting Information, for complete details.
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Cycloadduct 10e was more stable in solution, possibly due to the bulky o-Br substituent forcing the aromatic ring to rotate out of the plane of the N-O bond, slowing the cycloreversion.
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