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Crystallographic data: 1a: [Au18Se8(dppthph) 6]Cl2·9CH2Cl2: C 177H150Au18Cl20P12S 6Se8; triclinic, space group P1, Z, 2; a, 1819.2(4, b, 2402.5(5, c, 2499.9(5) pm, a, 95.37(3, β, 91.07(3, γ, 103.53(3)°; V, 10567(4) × 106 pm3; T, 180(2) K; ρ calcd, 2.429 g cm-3, 57341 data measured of which 34770 were unique (Rint, 0.0784, 2026 parameters; GoF, 1.017, wR2, 0.206 (all data, R1, 0.078 [I > 2σ(I, largest diff. peak/hole: 4.63/-5.96 eA -3 [the relatively high remaining electron density is located close to Au2 (95.3 pm, 1b: [Au18Se8-(dppthph) 6]Cl2
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Selected bond lengths of the optimized structure: Au⋯Au (within the heterocubane unit) 303.0 pm, Au-Se (within the heterocubane unit) 246.6 pm, Au-Se (from the heterocubane unit to Se outside of it) 251.3 pm; for experimental values see Figure 1.
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Selected bond lengths of the optimized structure: Au⋯Au (within the heterocubane unit) 303.0 pm, Au-Se (within the heterocubane unit) 246.6 pm, Au-Se (from the heterocubane unit to Se outside of it) 251.3 pm; for experimental values see Figure 1.
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