Tetra(alkynyl)silanes, a 3,6-disila-triyne, a 3,6,9-trisila-tetrayne, a 1,3,4,6-tetrasiladiyne, and bis(trimethylstannyl)ethyne. molecular structures and solid-state NMR studies

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

Volumn 65, Issue 2, 2010, Pages 119-127

  Wrackmeyer, Bernd ^a   Khan, Ezzat ^a,b   Badshah, Amin ^a,c   Molla, Elias ^a,d   Thoma, Peter ^a   Tok, Oleg L ^a   Milius, Wolfgang ^a   Kempe, Rhett ^a   Senker, Jürgen ^a  

^a UNIVERSITY OF BAYREUTH   (Germany)

^b UNIVERSITY OF MALAKAND   (Pakistan)

^c QUAID I AZAM UNIVERSITY   (Pakistan)

^d JAHANGIRNAGAR UNIVERSITY   (Bangladesh)

Author keywords

Alkynes; NMR; Organotin compounds; Silanes; X Ray

Indexed keywords

ACETYLENE; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; X RAYS;

ALKYNES; ALKYNYLS; MAS-NMR SPECTROSCOPY; ORGANOTIN COMPOUND; SOLID STATE NMR; SOLUTION STATE NMR; TETRAKIS; TETRAMETHYL;

SILANES;

EID: 77949864260     PISSN: 09320776     EISSN: None     Source Type: Journal    
DOI: 10.1515/znb-2010-0204     Document Type: Article

References (61)

1. (a) T. Hiyama, A. Mori, Science of Synthesis 2002, 4, 647;
2. (b) B. Wrackmeyer, Coord. Chem. Rev. 1995, 145, 125;
3. (c) B. Wrackmeyer, Heteroatom Chem. 2006, 17, 188;
4. (d) H. Sakurai, Y. Nakadaira, A. Hosomi, Y. Eriyama, C. Kabuto. J. Am. Chem. Soc. 1983, 105, 3359;
5. (e) K. Tamao, S. Yamaguchi, M. Shiro, J. Am. Chem. Soc. 1994, 116, 11715;
6. (f) E. Khan, B. Wrackmeyer, R. Kempe, Eur. J. Inorg. Chem. 2008, 5367;
7. (g) E. Khan, R. Kempe, B. Wrackmeyer, Appl. Organomet. Chem. 2009, 23, 124;
8. (h) E. Khan, S. Bayer, R. Kempe, B. Wrackmeyer, Eur. J. Inorg. Chem. 2009. 4416.
9. (a) K. Uchida, K. Utimoto, H. Nozaki, Tetrahedron 1977, 33, 2987;
10. (b) J.A. Soderquist, B. Santiago, Tetrahedron Lett. 1990, 31, 5113;
11. (c) G.A. Molander, J. Org. Chem. 1983, 48, 5409;
12. (d) H. Lang, M. Weinmann, L. Zsolnai, J. Organomet. Chem. 1996, 522, 277;
13. (e) T. Beweries, V.V. Burlakov, S. Peitz, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2008, 27, 3954;
14. (f) P.-M. Pellny, N. Peulecke, V.V. Burlakov, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2000, 19, 1198;
15. (g) N. Peulecke, A. Ohff, P. Kosse, A. Tillack, A. Spannenberg, R. Kempe, W. Baumann, V.V. Burlakov, U. Rosenthal, Chem. Eur. J. 1998, 4, 1852;
16. (h) H. Werner, M. Baum, D. Schneider, B. Windmüller, Organometallics 1994, 13, 1089.
17. (a) T. Takahashi, Z. Xi, Y. Obora, N. Suzuki, J. Am. Chem. Soc. 1995, 117, 2665;
18. (b) H. Ito, K. Arimoto, H. Sensui, A. Hosomi, Tetrahedron Lett. 1997, 38, 3977;
19. (c) T. Yu, X. Sun, C. Wang, L. Deng, Z. Xi, Chem. Eur. J. 2005, 11, 1895;
20. (d) Z. Xi, R. Fischer, R. Hara, W.-H. Sun, Y. Obora, N. Suzuki, K. Nakajima, J. Am. Chem. Soc. 1997, 119, 12842;
21. (e) J. Liu, S. Zhang, W.-X. Zhang, Z. Xi, Organometallics 2009, 28, 413;
22. (f) M. Zirngast, C. Marschner, J. Baumgartner, Organometallics 2006, 25, 4897.
23. (a) G. Dierker, J. Ugolotti, G. Kehr, R. Fröhlich, G. Erker, Adv. Synth. Catal. 2009, 351, 1080;
24. (b) C. Rüdinger, H. Beruda, H. Schmidbaur, Z. Naturforsch. 1994, 49b, 1348;
25. (c) H. Schmidbaur, J. Ebenhöch, G. Müller, Z. Naturforsch. 1988, 43b, 49;
26. (d) W.-Y. Wong, A.W.-M. Lee, C.-K. Wong, G.-L. Lu, H. Zhang, T. Mo, K.-T. Lam, New. J. Chem. 2002, 26, 354.
27. (a) C. Ackerhans, H.W. Roesky, D. Vidovic, J. Magull, Eur. J. Inorg. Chem. 2003, 66;
28. (b) C. Mechtler, M. Zirngast, J. Baumgartner, C. Marschner, Eur. J. In org. Chem. 2004, 3254;
29. (c) J. Liu,W.-X. Zhang, X. Guo, Z. Hou, Z. Xi, Organometallics 2007, 26, 6812.
30. (a) W.-Y. Wong, C.-K. Wong, G.-L. Lu, J. Organomet. Chem. 2003, 671, 27;
31. (b) W.-Y. Wong, C.-K. Wong, G.-L. Lu, K.-W. Cheah, J.-X. Shi, Z. Lin, Dalton Trans. 2002, 4587;
32. (c) W.-Y. Wong, K.-H. Choi, G.-L. Lu, Z. Lin, Organmetallics 2002, 21, 4475;
33. (d) T. Kuhnen, M. Stradiotto, R. Ruffolo, D. Ulbrich, M. J. McGlinchey, M.A. Brook, Organometallics 1997, 16, 5048;
34. (e) W.A. Chalifoux, M. J. Ferguson, R.R. Tykwinski, Eur. J. Org. Chem. 2007, 1001.
35. (a) B. Wrackmeyer, H. E. Maisel, J. Süß, W. Milius, Z. Naturforsch. 1996, 51b, 1320;
36. (b) B. Wrackmeyer, W. Milius, O. L. Tok, Chem. Eur. J. 2003, 9, 4732.
37. B.Wrackmeyer,W.Milius, A. Badshah, J. Organomet. Chem. 2002, 656, 97.
38. E. Klaus, A. Sebald, Magn. Reson. Chem. 1994, 32, 679.
39. J. Kümmerlen, A. Sebald, E. Sendermann, Organometallics 1994, 13, 802.
40. B. Wrackmeyer, O. L. Tok, A. Badshah, Z. Naturforsch. 2003, 58b, 809.
41. B. Wrackmeyer, B. H. Kenner-Hofmann, W. Milius, P. Thoma, O. L. Tok, M. Herberhold, Eur. J. Inorg. Chem. 2006 101.
42. B. Wrackmeyer, G. Kehr, D. Wettinger, W. Milius, Main Group Met. Chem. 1993, 16, 445.
43. B. Wrackmeyer, P. Thoma, R. Kempe, Eur. J. Inorg. Chem. 2009, 1469.
44. (a) W. E. Davidsohn, M.C. Henry, Chem. Rev. 1967, 67, 73;
45. (b) L. Brandsma, Preparative Acetylenic Chemistry (2nd ed.), Elsevier, Amsterdam, 1988;
46. (c) L. Brandsma, Synthesis of Acetylenes, Allenes, and Cumulenes - Methods and Techniques, Elsevier, Amsterdam, 2004.
47. B. Wrackmeyer, G. Kehr, J. Süß, E. Molla, J. Organomet. Chem. 1998, 562, 207.
48. B. Wrackmeyer, G. Kehr, J. Süß, E. Molla, J. Organomet. Chem. 1999, 577, 82.
49. B. Wrackmeyer in Organometallic Syntheses (Eds. R.B. King, J. J. Eisch), Vol.4, Elsevier, New York 1988, p. 559.
50. B.Wrackmeyer, O. L. Tok, P. Thoma, Arkivoc 2008, 6.
51. M. J. Frisch, G.W. Trucks, H. B. Schlegel, G. E. Scuseria, M.A. Robb, J.R. Cheeseman, J.A. Montgomery, Jr., T. Vreven, K.N. Kudin, J.C. Burant, J.M. Millam, S. S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G.A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J. E. Knox, H. P. Hratchian, J.B. Cross, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J.W. Ochterski, P.Y. Ayala, K. Morokuma, G.A. Voth, P. Salvador, J. J. Dannenberg, V.G. Zakrzewski, S. Dapprich, A.D. Daniels, M. C. Strain, O. Farkas, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J.V. Ortiz, Q. Cui, A.G. Baboul, S. Clifford, J. Cioslowski, B.B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M.A. Al-Laham, C.Y. Peng, A. Nanayakkara, M. Challacombe, P. M.W. Gill, B. Johnson, W. Chen, M.W. Wong, C. Gonzalez, J.A. Pople, GAUSSIAN 03 (revision B.02), Gaussian, Inc., Pittsburgh PA, 2003.
52. (a) O. B. Peersen, X. Wu, S.O. Smith, J. Magn. Reson. A 1994, 106, 127;
53. (b) G. Metz, X. Wu, S.O. Smith, J. Magn. Reson. A 1994, 110, 219;
54. (c) S.C. Shekar, A. Ramamoorthy, Chem. Phys. Lett. 2001, 342, 127.
55. B. M. Fung, A.K. Khitrin, K. Ermolaev, J. Magn. Reson. 2000, 142, 97.
56. T. Kottke, D. Stalke, J. Appl. Cryst. 1993, 26, 615.
57. A. Altomare, M. C. Burla, M. Camalli, G. L. Cascarano, C. Giacovazzo, A. Guagliardi, A. G. C. Moliterni, G. Polidori, R. Spagna, SIR97, A Program for the Automatic Solution of Crystal Structures by Direct Methods; see: J. Appl. Crystallogr. 1999, 32, 115.
58. M. Sheldrick, SHELXL-97 (release 97-2), Program for the Refinement of Crystal Structures, University of Göttingen, Göttingen (Germany) 1998.
59. See also: G.M. Sheldrick, Acta Crystallogr. 2008, A64, 112.
60. L. J. Farrugia, WINGX, A MS-Windows System of Programs for Solving, Refining and Analysing Single Crystal X-ray Diffraction Data for Small Molecules, University of Glasgow, Glasgow, Scotland (U.K.) 2005.
61. See also: L. J. Farrugia, J. Appl. Crystallogr. 1999, 32, 837.