Reactions of tetraalkynylsilanes (RC≡C)4Si (R = Ph, tBu, SiMe3) with titanocene and zirconocene complexes

Organometallics

Volumn 19, Issue 6, 2000, Pages 1198-1199

  Pellny, Paul Michael ^a   Peulecke, Normen ^a   Burlakov, Vladimir V ^a,b   Baumann, Wolfgang ^a   Spannenberg, Anke ^a   Rosenthal, Uwe ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

^b A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000453604     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om991007w     Document Type: Article

References (48)

1. Special volume devoted to Carbon-rich Organometallics. Guest Editors Bunz, U. H. F., and Adams, R. D. J. Organomet. Chem. 1999, 578, 1-264, and references therein.
2. (a) Ohshiro, N.; Takei, F.; Onitsuka, K.; Takahashi, S. J. Organomet. Chem. 1998, 569, 195.
3. (b) Leininger, S.; Stang, P. J.; Huang, S. Organometallics 1998, 17, 3981.
4. (c) Werner, H.; Bachmann, P.; Laubender, M.; Gevert, O. Eur. J. Inorg. Chem. 1998, 1217.
5. (d) Uno, M.; Dixneuf, P. H. Angew. Chem., Int. Ed. 1998, 37, 1714.
6. (e) Whittall, I. R.; Humphrey, M. G.; Houbrechts, S.; Maes, J.; Persoons, A.; Schmid, S.; Hockless, D. C. R. J. Organomet. Chem. 1997, 544, 277.
7. (f) Bunz, U. H. F.; Enkelmann, V. Organometallics 1994, 13, 3823.
8. (g) Fink, H.; Long, N. J.; Martin A. J.; Opromolla, G.; White, A. J. P.; Williams, D. J.; Zanello, P. Organometallics 1997, 12, 2646.
9. (a) Diederich, F.; Rubin, Y. Angew. Chem., Int. Ed. Engl. 1992, 31, 1101.
10. (b) Gleiter, R.; Kratz, D. Angew. Chem., Int. Ed. Engl. 1993, 32, 842.
11. (c) Bunz, U. H. F. Angew. Chem., Int. Ed. Engl. 1994, 33, 1073.
12. (a) Mao, S. S. H.; Tilley, T. D. J. Am. Chem. Soc. 1995, 117, 5365.
13. (b) Mao, S. S. H.; Tilley, T. D. J. Am. Chem. Soc. 1995, 117, 7031.
14. (c) Mao, S. S. H.; Liu, F.-Q.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 1193.
15. (d) Liu, F.-G.; Harder, G.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 3271.
16. (e) Nitschke, J.; Tilley, T. D. J. Org. Chem. 1998, 63, 3673.
17. (a) Ohff, A.; Pulst, S.; Peulecke, N.; Arndt, P.; Burlakov, V. V.; Rosenthal, U. Synlett 1996, 111, and references therein.
18. (b) Rosenthal, U.; Görls, H. J. Organomet. Chem. 1992, 439, C36-C41.
19. (c) Rosenthal, U.; Ohff, A.; Tillack, A.; Baumann, W.; Görls, H. J. Organomet. Chem. 1994, 468, C4-C8.
20. (d) Rosenthal, U.; Ohff, A.; Baumann, W.; Kempe, R.; Tillack, A.; Burlakov, V. V. Organometallics 1994, 13, 2903.
21. (e) Rosenthal, U.; Ohff, A.; Baumann, W.; Kempe, R.; Tillack, A.; Burlakov, V. V. Angew. Chem., Int. Ed. Engl. 1994, 33, 1605.
22. (f) Burlakov, V. V.; Ohff, A.; Lefeber, C.; Tillack, A.; Baumann, W.; Kempe, R.; Rosenthal, U. Chem. Ber. 1995, 128, 967.
23. (g) Pulst, S.; Arndt, P.; Heller, B.; Baumann, W.; Kempe, R.; Rosenthal, U. Angew. Chem., Int. Ed. Engl. 1996, 35, 1112.
24. (h) Burlakov, V. V.; Peulecke, N.; Baumann, W. Spannenberg, A.; Kempe, R.; Rosenthal, U. J. Organomet. Chem. 1997, 536-537, 293.
25. (i) Hsu, D. P.; Davis, W. M.; Buchwald, S. L. J. Am. Chem. Soc. 1993, 115, 10394.
26. (a) Rosenthal, U.; Lefeber, C.; Arndt, P.; Tillack, A.; Baumann, W.; Kempe, R.; Burlakov, V. V. J. Organomet. Chem. 1995, 503, 221.
27. (b) Tillack, A.; Baumann, W.; Ohff, A.; Lefeber, C.; Spannenberg, A.; Rosenthal, U. J. Organomet. Chem. 1996, 520, 187.
28. (a) Pellny, P.-M.; Peulecke, N.; Burlakov, V. V.; Tillack, A.; Baumann, W.; Spannenberg, A.; Kempe, R.; Rosenthal, U. Angew. Chem., Int. Ed. Engl. 1997, 36, 2615.
29. (b) Pellny, P.-M.; Burlakov, V. V.; Baumann, W.; Spannenberg, A.; Kempe, R.; Rosenthal, U. Organometallics 1999, 18, 2906.
30. Burlakov, V. V.; Polyakov, A. V.; Yanovsky, A. I.; Struchkov, Y. T.; Shur, V. B.; Vol'pin, M. E.; Rosenthal, U.; Görls, H. J Organomet. Chem. 1994, 476, 197, and references therein.
31. Rosenthal, U.; Ohff, A.; Michalik, M.; Görls, H.; Burlakov, V. V.; Shur, V. B. Angew. Chem., Int. Ed. Engl. 1993, 32, 1193.
32. (a) Takahashi, T.; Xi, Z.; Obora, Y.; Suzuki, N. J. Am. Chem. Soc. 1995, 117, 2665.
33. (b) Xi, Z.; Fischer, R.; Hara, R.; Sun, W.-H.; Obora, Y.; Suzuki, N.; Nakajima, K.; Takahashi, T. J. Am. Chem. Soc. 1997, 119, 12842.
34. Dallaire, C.; Brook, M.; Bain, A.; Frampton, C.; Britten, J. Can. J Chem. 1993, 10, 1676.
35. 3.
36. (a) We thank Prof. D. Seyferth for his first hint concerning this analogy which has proved important and rather far-reaching.
37. (b) Hoffmann, R. Angew. Chem., Int. Ed. Engl. 1982, 21, 711.
38. (c) Seyferth, D.; Vick, S. C.; Shannon, M. L. Organometallics 1994, 3, 1897.
39. Peulecke, N.; Ohff, A.; Tillack, A.; Baumann, W.; Kempe, R.; Burlakov, V. V.; Rosenthal, U. Organometallics 1996, 15, 1340.
40. (a) Kunai, A.; Mihara, T.; Matsuo, Y.; Oshita, J.; Naka, A.; Ishikawa, M. J. Organomet. Chem. 1997, 545-546, 611.
41. (b) Kirmaier, L.; Weidenbruch, M.; Marsmann, H.; Peters, K.; von Schnering, H. G. Organometallics 1998, 17, 1237.
42. (c) Ostendorf, D.; Kirmaier, L.; Saak, W.; Marsmann, H.; Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 2301.
43. Pellny, P.-M.; Kirchbauer, F.; Burlakov, V. V.; Baumann, W.; Spannenberg, A.; Rosenthal, U. J. Am. Chem. Soc. 1999, 121, 1, 8313.
44. (a) Sekutowsky, D. G.; Stucky, G. D. J. Am. Chem. Soc. 1976, 98, 1376.
45. (b) Pavankumar, P. N. V.; Jemmis, E. D. J. Am. Chem. Soc. 1988, 110, 125.
46. (c) Jemmis, E. D.; Giju, K. T. Angew. Chem., Int. Ed. Engl. 1997, 36, 606.
47. (d) Jemmis, E. D.; Giju, K. T. J. Am. Chem. Soc. 1998, 120, 6952, and references therein.
48. 2 (SHELXL-93); structure representation with XP (Siemens). The crystals diffract weakly and contain a high amount of solvent, causing a rapid decay of the material when taken out of solution. This is observed even at low temperatures. The atoms of two phenyl groups and of one cyclopentadienyl ligand are refined isotropically. All other non-hydrogen atoms were refined anisotropically. Hydrogen atoms were included at calculated positions and refined riding with the corresponding atom.