Cascade [l,3]-sigmatropic rearrangements of ketene O,O-acetals: Kinetic and DFT level mechanistic studies

Journal of Organic Chemistry

Volumn 75, Issue 6, 2010, Pages 1898-1910

  López Camacho, Perla Y ^a   Joseph Nathan, Pedro ^a   Gordillo Román, Bárbara ^a   Suárez Castillo, Oscar R ^b   Morales Ríos, Martha S ^a  

^a DEPARTAMENTO DE FÍSICA   (Mexico)

^b UNIVERSIDAD AUTÓNOMA DEL ESTADO DE HIDALGO   (Mexico)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTIONS; HYDROCARBONS; PROBABILITY DENSITY FUNCTION; SULFUR COMPOUNDS;

ALKYL SUBSTITUENT; CHEMICAL EQUATIONS; DFT CALCULATION; DFT LEVELS; DIAZOMETHANES; KINETIC MODELS; MECHANISTIC STUDIES; O ,O-ACETALS; RATE DETERMINING STEP; REVERSIBLE PROCESS; REVERSIBLE REACTION; SIGMATROPIC REARRANGEMENTS; SOLVATION EFFECT; STEADY-STATE KINETICS; THERMODYNAMIC PARAMETER; TRANSITION STATE; UNIMOLECULAR; X-RAY STRUCTURE;

RATE CONSTANTS;

2 INDOYL CYANOMALONATE DETIVATIVE; ACETAL DERIVATIVE; ALKYL GROUP; DIAZOMETHANE; INDOLE ALPHA CYANO GAMMA LACTONE DERIVATIVE; INDOLE DERIVATIVE; LACTONE DERIVATIVE; LANTHANUM; MALONIC ACID; UNCLASSIFIED DRUG; ETHYLENE DERIVATIVE; KETENE; KETONE; OXYGEN;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; ISOLATION PROCEDURE; NUCLEAR MAGNETIC RESONANCE; SOLVATION; STEADY STATE; SYNTHESIS; THERMODYNAMICS; X RAY; CHEMISTRY; KINETICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; QUANTUM THEORY; X RAY CRYSTALLOGRAPHY;

ACETALS; CRYSTALLOGRAPHY, X-RAY; DIAZOMETHANE; ETHYLENES; KETONES; KINETICS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR STRUCTURE; OXYGEN; QUANTUM THEORY; THERMODYNAMICS;

EID: 77949802560     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo902520z     Document Type: Article

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