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As discussed in Ref., the energy gap, ΔE, is actually the difference between the vibrational frequency of the diatomic, ωBrBr, and the vdW bond energy, DRgBr2. It is only in the limit that 4π DRgBr2 ωBrBr / ω RgBr2 2 1 that ΔE can be safely approximated by the vibrational spacing of the diatomic. At the request of the reviewer we checked that this approximation was valid for our data by using ΔE= ωBrBr-DRgBr2 in the fit to see if it changed the VP lifetimes for NeBr2. The resulting values were safely within our error bars, with all the lifetimes but one differing by less than 2%. There was a change of 4.7% for ′ =20, which corresponds to a change in lifetime from 27.5 to 26.3 ps.
-
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35
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