Effect of nanoscale confinement on glass transition of polystyrene domains from self-assembly of block copolymers

Journal of Chemical Physics

Volumn 132, Issue 10, 2010, Pages

  Robertson, C G ^a   Hogan, T E ^a   Rackaitis, M ^a   Puskas, J E ^b   Wang, X ^a  

^a Bridgestone Americas   (United States)

^b The University of Akron   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS SUSPENSIONS; BULK BEHAVIOR; CHARACTERISTIC SIZE; DIBLOCK COPOLYMER; DIFFUSE INTERFACE; GLASS TRANSITION TEMPERATURE; HARD BLOCKS; INTRINSIC SIZE EFFECTS; LIMITING BEHAVIOR; NANO-SCALE GEOMETRIES; NANOSCALE CONFINEMENT; POLY(STYRENE-CO-BUTADIENE); POLYSTYRENE FILMS; POLYSTYRENE SPHERES; SHARP CONTRAST; SIZE DEPENDENCE; SOLUBILITY PARAMETERS; SPHERICAL DOMAIN; TRIBLOCK COPOLYMERS; ULTRA-THIN;

BLOCK COPOLYMERS; BUTADIENE; BUTENES; COPOLYMERIZATION; GLASS; NANOSTRUCTURED MATERIALS; ORGANIC POLYMERS; PHASE INTERFACES; PHASE SEPARATION; POLYSTYRENES; SIZE SEPARATION; STYRENE; SUSPENSIONS (FLUIDS); ULTRATHIN FILMS;

GLASS TRANSITION;

EID: 77949589125     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3337910     Document Type: Article

References (55)

1. C. L. Jackson and G. B. McKenna, J. Non-Cryst. Solids JNCSBJ 0022-3093 131-133, 221 (1991). 10.1016/0022-3093(91)90305-P
2. O. K. C. Tsui, T. P. Russell, and C. J. Hawker, Macromolecules MAMOBX 0024-9297 34, 5535 (2001). 10.1021/ma000028v (Pubitemid 34220577)
3. M. Alcoutlabi and G. B. McKenna, J. Phys.: Condens. Matter JCOMEL 0953-8984 17, R461 (2005). 10.1088/0953-8984/17/15/R01
4. E. Donth, J. Non-Cryst. Solids JNCSBJ 0022-3093 53, 325 (1982). 10.1016/0022-3093(82)90089-8
5. E. Hempel, G. Hempel, A. Hensel, C. Schick, and E. Donth, J. Phys. Chem. B JPCBFK 1089-5647 104, 2460 (2000). 10.1021/jp991153f
6. C. G. Robertson and X. Wang, Macromolecules MAMOBX 0024-9297 37, 4266 (2004). 10.1021/ma0495792
7. X. H. Qiu and M. D. Ediger, J. Phys. Chem. B JPCBFK 1089-5647 107, 459 (2003). 10.1021/jp021888b
8. L. Hong, P. D. Gujrati, V. N. Novikov, and A. P. Sokolov, J. Chem. Phys. JCPSA6 0021-9606 131, 194511 (2009). 10.1063/1.3266508
9. K. Dalnoki-Veress, J. A. Forrest, P. G. de Gennes, and J. R. Dutcher, J. Phys. IV JPICEI 1155-4339 10 (Pr7), 221 (2000). 10.1051/jp4:2000744
10. C. G. Robertson and C. M. Roland, Rubber Chem. Technol. RCTEA4 0035-9475 81, 506 (2008).
11. M. Lazzari and M. A. López-Quintela, Adv. Mater. ADVMEW 0935-9648 15, 1583 (2003). 10.1002/adma.200300382
12. I. W. Hamley, Nanotechnology NNOTER 0957-4484 14, R39 (2003). 10.1088/0957-4484/14/10/201
13. C. Allen, D. Maysinger, and A. Eisenberg, Colloids Surf., B CSBBEQ 0927-7765 16, 3 (1999). 10.1016/S0927-7765(99)00058-2 (Pubitemid 29486794)
14. D. A. Olson, L. Chen, and H. A. Hillmyer, Chem. Mater. CMATEX 0897-4756 20, 869 (2008). 10.1021/cm702239k
15. C. Park, J. Yoon, and E. L. Thomas, Polymer POLMAG 0032-3861 44, 6725 (2003). 10.1016/j.polymer.2003.08.011 (Pubitemid 37210458)
16. A. S. Mikhail and C. Allen, J. Control. Release 138, 214 (2009). 10.1016/j.jconrel.2009.04.010 0168-3659
17. F. S. Bates and G. H. Fredrickson, Annu. Rev. Phys. Chem. ARPLAP 0066-426X 41, 525 (1990). 10.1146/annurev.pc.41.100190.002521
18. A. Todo, H. Uno, K. Miyoshi, T. Hashimoto, and H. Kawai, Polym. Eng. Sci. PYESAZ 0032-3888 17, 587 (1977). 10.1002/pen.760170816
19. J. Bares, Macromolecules MAMOBX 0024-9297 8, 244 (1975). 10.1021/ma60044a030
20. S. Krause, M. Iskandar, and M. Iqbal, Macromolecules MAMOBX 0024-9297 15, 105 (1982). 10.1021/ma00229a021
21. D. Rosati, M. Perrin, P. Navard, V. Harabagiu, M. Pinteala, and B. C. Simionescu, Macromolecules MAMOBX 0024-9297 31, 4301 (1998). 10.1021/ma971577c
22. J. H. Chu, P. Rangarajan, J. L. Adams, and R. A. Register, Polymer POLMAG 0032-3861 36, 1569 (1995). 10.1016/0032-3861(95)99001-B
23. J. A. Forrest, K. Dalnoki-Veress, J. R. Stevens, and J. R. Dutcher, Phys. Rev. Lett. PRLTAO 0031-9007 77, 2002 (1996). 10.1103/PhysRevLett.77.2002
24. J. A. Forrest and J. Mattsson, Phys. Rev. E PLEEE8 1063-651X 61, R53 (2000). 10.1103/PhysRevE.61.R53
25. U. Gaur and B. Wunderlich, Macromolecules MAMOBX 0024-9297 13, 1618 (1980). 10.1021/ma60078a048
26. T. Sasaki, A. Shimizu, T. H. Mourey, C. T. Thurau, and M. D. Ediger, J. Chem. Phys. JCPSA6 0021-9606 119, 8730 (2003). 10.1063/1.1613257
27. C. B. Roth and J. M. Torkelson, Macromolecules MAMOBX 0024-9297 40, 3328 (2007). 10.1021/ma070162g (Pubitemid 46750635)
28. C. G. Robertson and C. M. Roland, J. Polym. Sci., Part B: Polym. Phys. JPBPEM 0887-6266 42, 2604 (2004). 10.1002/polb.20127
29. T. G. Fox and P. J. Flory, J. Appl. Phys. JAPIAU 0021-8979 21, 581 (1950). 10.1063/1.1699711
30. Polymer Handbook, 4th ed., edited by, J. Brandrup, E. H. Immergut, and, E. A. Grulke, (Wiley, New York, 1999), p. V-3.
31. E. Helfand and Y. Tagami, J. Chem. Phys. JCPSA6 0021-9606 56, 3592 (1972). 10.1063/1.1677735
32. E. Helfand and Z. R. Wasserman, Macromolecules MAMOBX 0024-9297 9, 879 (1976). 10.1021/ma60054a001
33. K. L. Ngai and C. M. Roland, Macromolecules MAMOBX 0024-9297 26, 6824 (1993). 10.1021/ma00077a019
34. K. Kunal, C. G. Robertson, S. Pawlus, S. F. Hahn, and A. P. Sokolov, Macromolecules MAMOBX 0024-9297 41, 7232 (2008). 10.1021/ma801155c
35. D. J. Plazek and K. L. Ngai, Physical Properties of Polymers Handbook, The Glass Temperature, edited by, J. E. Mark, (AIP, Woodbury, 1996), Chap., pp. 139-159.
36. R. F. Boyer, Rubber Chem Technol. 36, 1303 (1963).
37. A. G. Shvarts, Kolloidn. Zh. KOZHAG 0023-2912 18, 755 (1956).
38. R. Böhmer, K. L. Ngai, C. A. Angell, and D. J. Plazek, J. Chem. Phys. JCPSA6 0021-9606 99, 4201 (1993). 10.1063/1.466117
39. Q. Qin and G. B. McKenna, J. Non-Cryst. Solids JNCSBJ 0022-3093 352, 2977 (2006). 10.1016/j.jnoncrysol.2006.04.014 (Pubitemid 44041019)
40. G. B. McKenna, J. Phys. IV JPICEI 1155-4339 10 (Pr7), 53 (2000). 10.1051/jp4:2000710
41. Y. P. Koh, G. B. McKenna, and S. L. Simon, J. Polym. Sci., Part B: Polym. Phys. JPBPEM 0887-6266 44, 3518 (2006). 10.1002/polb.21021 (Pubitemid 46052420)
42. A. Serghei, Macromol. Chem. Phys. MCHPES 1022-1352 209, 1415 (2008). 10.1002/macp.200800197
43. A. Serghei, M. Tress, and F. Kremer, J. Chem. Phys. JCPSA6 0021-9606 131, 154904 (2009). 10.1063/1.3248368
44. H. Bodiguel and C. Fretigny, Eur. Phys. J. E EPJSFH 1292-8941 19, 185 (2006). 10.1140/epje/e2006-00021-8 (Pubitemid 43383158)
45. H. Bodiguel and C. Fretigny, Macromolecules MAMOBX 0024-9297 40, 7291 (2007). 10.1021/ma070460d (Pubitemid 47583078)
46. H. Lu, W. Chen, and T. P. Russell, Macromolecules MAMOBX 0024-9297 42, 9111 (2009). 10.1021/ma901789k
47. P. A. O'Connell and G. B. McKenna, Science SCIEAS 0036-8075 307, 1760 (2005). 10.1126/science.1105658 (Pubitemid 40392509)
48. P. A. O'Connell, S. A. Hutcheson, and G. B. McKenna, J. Polym. Sci., Part B: Polym. Phys. JPBPEM 0887-6266 46, 1952 (2008). 10.1002/polb.21531
49. C. Svanberg, Macromolecules MAMOBX 0024-9297 40, 312 (2007). 10.1021/ma061967b (Pubitemid 46255898)
50. R. D. Priestley, L. J. Broadbelt, J. M. Torkelson, and F. Fukao, Phys. Rev. E PLEEE8 1063-651X 75, 061806 (2007). 10.1103/PhysRevE.75.061806 (Pubitemid 47143688)
51. C. Rotella, S. Napolitano, and M. Wübbenhorst, Macromolecules MAMOBX 0024-9297 42, 1415 (2009). 10.1021/ma8027968
52. S. Kim, C. B. Roth, and J. M. Torkelson, J. Polym. Sci., Part B: Polym. Phys. JPBPEM 0887-6266 46, 2754 (2008). 10.1002/polb.21591
53. C. B. Roth and J. R. Dutcher, Eur. Phys. J. E EPJSFH 1292-8941 12, S103 (2003). 10.1140/epjed/e2003-01-024-2
54. D. Zhou, H. Huth, Y. Gao, G. Xue, and C. Schick, Macromolecules MAMOBX 0024-9297 41, 7662 (2008). 10.1021/ma8012543
55. X. Wang and W. Zhou, Macromolecules MAMOBX 0024-9297 35, 6747 (2002). 10.1021/ma020291r