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Volumn 209, Issue 14, 2008, Pages 1415-1423

Challenges in glassy dynamics of polymers

Author keywords

Glass transition; Interfacial dynamics; Polymer dynamics; Single chain; Thin films

Indexed keywords

ABS RESINS; DISTRIBUTION FUNCTIONS; DYNAMICS; GLASS; GLASS TRANSITION; MOLECULAR DYNAMICS; POLYMERS; QUANTUM CHEMISTRY; THICK FILMS; THIN FILMS;

EID: 55349144539     PISSN: 10221352     EISSN: 15213935     Source Type: Journal    
DOI: 10.1002/macp.200800197     Document Type: Article
Times cited : (26)

References (31)
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    • G. Reiter, P. G. de Gennes, Eur. Phys. J. E 2001, 6, 25. The transition from the dynamics of isolated molecules to that of a bulk liquid is observed for the first time by analyzing the dielectric relaxation (10-2-109 Hz) of ethylene glycol (EG) guest molecules confined to zeolitic host systems of different topology. Beyond a threshold channel size the liquid character is lost, indicated by a dramatically increased relaxation rate and an Arrhenius-like temperature dependence. Computer simulations of the molecular arrangement in a confining space prove that an ensemble as small as six molecules is sufficient to exhibit the dynamics of a bulk liquid.
    • G. Reiter, P. G. de Gennes, Eur. Phys. J. E 2001, 6, 25. The transition from the dynamics of isolated molecules to that of a bulk liquid is observed for the first time by analyzing the dielectric relaxation (10-2-109 Hz) of ethylene glycol (EG) guest molecules confined to zeolitic host systems of different topology. Beyond a threshold channel size the liquid character is lost, indicated by a dramatically increased relaxation rate and an Arrhenius-like temperature dependence. Computer simulations of the molecular arrangement in a confining space prove that an ensemble as small as six molecules is sufficient to exhibit the dynamics of a bulk liquid.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.