Temperature dependence, 0 to 40 °C, of the mineralogy of Portland cement paste in the presence of calcium carbonate

Cement and Concrete Research

Volumn 40, Issue 5, 2010, Pages 763-777

  Matschei, Thomas ^a,b   Glasser, Fredrik P ^b  

^a Holcim   (Switzerland)

^b UNIVERSITY OF ABERDEEN   (United Kingdom)

Author keywords

CaCO3 (D); Durability (C); Ettringite (D); Monosulfate (D); Thermodynamic Calculations (B)

Indexed keywords

AFM; ANION SITES; CARBONATE CONTENT; CEMENT PROPERTIES; CEMENT SYSTEM; CHANGING TEMPERATURE; EFFECTIVE TOOL; ETTRINGITE (D); ETTRINGITES; HYDROGARNET; ISOTHERMAL SECTIONS; LOW TEMPERATURES; PHASE RELATION; PORTLAND CEMENT PASTE; SOLID PHASIS; SPACE FILLING; TEMPERATURE DEPENDENCE; THERMAL IMPACTS; THERMODYNAMIC CALCULATIONS;

CALCITE; CALCIUM; CALCIUM CARBONATE; CARBONATE MINERALS; CRYSTALLIZATION; CRYSTALLOGRAPHY; DURABILITY; MINERALOGY; MINERALS; PORTLAND CEMENT; SOLID SOLUTIONS; SOLIDIFICATION; STOICHIOMETRY; TERMINOLOGY; THERMODYNAMICS;

TEMPERATURE;

EID: 77949489778     PISSN: 00088846     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cemconres.2009.11.010     Document Type: Article

References (37)

1. Internal Sulfate Attack and Delayed Ettringite Formation. In: Scrivener K., and Skalny J. (Eds). Proceedings of the International RILEM TC 186-ISA Workshop (2004), RILEM publications, Paris
2. 2O. Cement and Concrete Research 37 (2007) 1379-1410
3. Lothenbach B., Matschei T., Möschner G., and Glasser F.P. Thermodynamic modelling of the effect of temperature on the hydration and porosity of Portland cement. Cement and Concrete Research 38 (2008) 1-18
4. Matschei T., Lothenbach B., and Glasser F.P. The AFm phase in Portland cement. Cement and Concrete Research 37 (2007) 118-130
5. Matschei T., Lothenbach B., and Glasser F.P. The role of calcium carbonate in cement hydration. Cement and Concrete Research 37 (2007) 551-558
6. Matschei T., and Glasser F.P. Zum Einfluss von Kalkstein auf die Zementhydratation. Zement Kalk Gips 59 (12/2006) 78-86
7. Matschei T., Skapa R., Lothenbach B., and Glasser F.P. The distribution of sulfate in hydrated Portland cement paste. Proceedings of the 12th Intern. Congress on the Chemistry of Cements, Montreal (2007)
8. Matschei T., Herfort D., Lothenbach B., and Glasser F.P. Relationships of Cement Paste Mineralogy to Porosity and Mechanical Properties. Modelling of Heterogenous Materials with Applications in Construction and Biomedical Engineering, Prague (2007) extended abstract
9. Kulik, D.; Berner, U.; Curti, E.: Modelling chemical equilibrium partitioning with the GEMS-PSI code. PSI Scientific Report 2003, Vol. IV, 109-122, http://gems.web.psi.ch.
10. Thönen, T.; Kulik, D. Nagra/PSI Chemical Thermodynamic Data Base 01/01 for the GEM-Selektor (V.2-PSI) Geochemical Modeling Code: Release 28-02-03. PSI Technical Report TM-44-03-04 (unpublished) about the GEMS version of Nagra/PSI chemical thermodynamic database 01/01. 2003.
11. Hummel W., Berner U., Curti E., Pearson F.J., and Thönen T. Nagra/PSI Chemical Thermodynamic Data Base 01/01 (2002), Universal Publishers, Parkland, Florida, USA
12. Johnson J.W., Ölkers E.H., and Helgeson H.C. SUPCRT92: a software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000 °C. Computers & Geosciences 18 (1992) 899-947. http://geopig.asu.edu/supcrt92_data/slop98.dat slop98.dat database available from http://geopig.asu.edu/supcrt92_data/slop98.dat
13. Shock E.L., Sassani D.C., Willis M., and Sverjensky D. Inorganic species in geologic fluids: correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes. Geochimica et Cosmochimica Acta 61 (1997) 907-950
14. Sverjensky D., Shock E.L., and Helgeson H.C. Prediction of the thermodynamic properties of aqueous metal complexes to 1000 °C and 5 kbar. Geochimica et Cosmochimica Acta 61 (1997) 1359-1412
15. Babushkin V.I., Matveev G.M., and Mčedlov-Petrosjan O.P. Thermodinamika Silikatov (1985), Springer, Moskau
16. Glynn P.: Solid-solution Solubilities and Thermodynamics: Sulfates, Carbonates and Halides. In: Sulfate Minerals: Crystallography, Geochemistry and Environmental Significance, Alpers C.N., Jambor J.L. and Nordstrom D.K. (eds.), Mineralogical Society of America and Geochemical Society, Reviews in Mineralogy and Geochemistry, 2000, v. 40, 481-511.
17. Glynn P.D. MBSSAS: a code for the computing of margules parameters and equilibrium relations in binary solid-solutions aqueous-solution systems. Computers & Geoscience 17 (1991) 907-966
18. Matschei T., and Glasser F.P. Interactions between Portland cement and carbon dioxide. Proceedings of the 12th ICCC, Montreal (2007)
19. Midgley, H.G.; Rosaman, D.: The composition of ettringite in set Portland cement. Proceedings of the IV. Intern. Symposium on the chemistry of Cements, Washington, D.C, 1964, Vol. III-S2 p. 259-262.
20. J. Neubauer, F. Götz-Neunhöffer, D. Schmitt, M. Degenkolb, U. Holland, In-situ Untersuchung der frühen PZ-Hydratation. Proceedings of the 16th Ibausil, Weimar, 2006, Vol. I, 1-0375 - 1-0382.
21. Warren C.J., and Reardon E.J. The solubility of ettringite at 25 °C. Cement and Concrete Research 24 (1994) 1515-1524
22. 2O. Cement and Concrete Research 20 (1990) 941-947
23. 2O. Cement and Concrete Research 31 (2001) 13-17
24. Carlson E.T., and Berman H.A. Some observations on the calcium aluminate carbonate hydrates. Journal of Research of the National Bureau of Standards 64 (1960) 333-341
25. Flint E.P., and Wells L.S. Analogy of hydrated calcium silicoaluminates and hexacalcium aluminate to hydrated calcium sulfoaluminates. Journal of Research of the National Bureau of Standards 33 (1944) 471-478
26. Murdoch J. Crestmore past and present. American Mineralogist 46 (1961) 245-257
27. Murdoch J., and Chalmers R.A. Ettringite ("woodfordite") from Crestmore. American Mineralogist 45 (1960) 1275-1278
28. Kollmann H., and Struebel G. Ettringite-Thaumasit-Mischkristalle von Brenk (Eifel). Chemie der Erde 40 (1981) 110-120
29. Matschei T., and Glasser F.P. New Approaches to Quantification of Cement Hydration. Proceedings of the 16th Ibausil, Weimar vol. I (2006) 1-0389-1-0400
30. Matschei T., and Glasser F.P. Phase Assemblages Relevant to Portland Cement Hydration at Low Temperatures, 0-25 °C. Proceedings of the 17th Ibausil, Weimar vol. I (2009) 01-219-01-233
31. T. Matschei, D. Macphee, F.P. Glasser, in preparation 2009.
32. 2 aq. Neues Jahrbuch fuer Mineralogie Abhandlungen 161 (1989) 27-41
33. Roberts M.H. Calcium aluminate hydrates and related basic salt solid solutions. Proceedings of the V. Intern. Symposium on the Chemistry of Cements, Tokyo vol. II (1969) 104-117
34. R. Skapa, F.P. Glasser, in preparation 2009.
35. Barry T.I., and Glasser F.P. Calculation of Portland cement clinkering reactions. Advances in Cement Research 12 (2000) 19-28
36. Dosch W., and zur Strassen H. Ein alkalihaltiges Calciumaluminatsulfathydrat (Natrium-Monosulfat). Zement-Kalk-Gips 20 9 (1967) 392-401
37. Strunz H., and Nickel H.E. Mineralogical Tables. 9th Edition (2001), E. Schweizerbart'sche Verlagsbuchhandlung, Stuttgart