Separation of lanthanides and actinides using magnetic silica particles bearing covalently attached tetra-CMPO-calix[4] arenes

Organic and Biomolecular Chemistry

Volumn 2, Issue 16, 2004, Pages 2327-2334

  Böhmer, Volker ^a   Dozol, Jean François ^c   Grüttner, Cordula ^b   Liger, Karine ^c   Matthews, Susan E ^a,d   Rudershausen, Sandra ^b   Saadioui, Mohamed ^a   Wang, Pingshan ^a,e  

^a JOHANNES GUTENBERG UNIVERSITY   (Germany)

^b MICROMOD PARTIKELTECHNOLOGIE GMBH   (Germany)

^c IRFM   (France)

^d UNIVERSITY OF EAST ANGLIA   (United Kingdom)

^e GOODYEAR TIRE AND RUBBER COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACYLATION; CONFORMATIONS; EXTRACTION; MAGNETIC DEVICES; ORGANIC SOLVENTS; RARE EARTH ELEMENTS; SEPARATION; SILICA;

AMINO GROUPS; CALIXARENES; CHEMICAL SEPARATION; MAGNETIC SILICA;

ACTINIDES;

ARENE;

EID: 4644338042     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/b405602g     Document Type: Article

References (20)

1. E. P. Horwitz, D. G. Kalina, H. Diamond, D. G. Vandegrift and W. W. Schultz, Solv. Extr. Ion Exch., 1985, 3, 75-109.
2. F. Arnaud-Neu, V. Böhmer, J.-F. Dozol, C. Grüttner, R. A. Jakobi, D. Kraft, O. Mauprivez, H. Rouquette, M.-J. Schwing-Weill, N. Simon and W. Vogt, J. Chem. Soc., Perkin Trans. 2, 1996, 1175-1182.
3. S. E. Matthews, M. Saadioui, V. Böhmer, S. Barboso, F. Amaud-Neu, M.-J. Schwing-Weill, A. Garcia Carrera and J.-F. Dozol, J. Prakt. Chem., 1999, 341, 264-273.
4. S. Barboso, A. Garcia Carrera, S. E. Matthews, F. Amaud-Neu, V. Böhmer, J.-F. Dozol, H. Rouquette and M.-J. Sohwing-Weill, J. Chem. Soc., Perkin Trans. 2, 1999, 719-724.
5. L. H. Delmau, N. Simon, M.-J. Schwing-Weill, F. Arnaud-Neu, J.-F. Dozol, S. Eymard, B. Tournois, V. Böhmer, C. Grüttner, C. Musigmann and A. Tunayar, Chem. Commun., 1998, 1627-1628.
6. For CMPO-fimctions attached to the wide rim of cavitands see: H. Boerrigter, W. Verboom and D. N. Reinhoudt, J. Org. Chem., 1997, 62, 7148-7155; for a rigidified calix[4]arene skeleton compare ref. 20.
7. For tripodal CMPO-derivatives see: M. W. Peters, E. J. Werner and M. J. Scott, Inorg. Chem., 2002, 41, 1707-1716.
8. L. Nuñez and M. D. Kaminski, Chemtech, 1998, 41-44.
9. L. Nuñez, B. A. Buchholz and G. F. Vandegrift, Sep. Sci. Technol., 1995, 30, 1455-1471.
10. L. Nuñez, B. A. Buchholz, M. Kaminski, S. B. Aase, N. R. Brown and G. F. Vandegrift, Sep. Sci. Technol., 1996, 31, 1393-1398.
11. M. D. Kaminski, L. Nuñez and A. E. Visser, Sep. Sci. Technol., 1999, 34, 1103-1109.
12. M. Kaminski, S. Landsberger, L. Nuñez and G. F. Vandegrift, Sep. Sci. Technol., 1997, 32, 115-126.
13. S. E. Matthews, P. Parzuchowski, A. Garcia Carrera, C. Grüttner, J.-F. Dozol and V. Böhmer, Chem. Commun., 2001, 417-418.
14. Product information: www.micromod.de; product-code: 58-39-105.
15. To prepare tetraether 6a tert-butylcalix[4]arene was first alkylated with bromopropylphthalimide (68%), followed by alkylation with propylbromide (82%), see ref. 13.
16. K. Winnacker and L. Küchler, Chemische Technologie, vol. 7(3), Carl Hanser Verlag, München, 1975, p. 93-94.
17. K. A. Martin, E. P. Horwitz and J. R. Ferraro, Solv. Extr. Ion Exch., 1986, 4, 1149-1169.
18. B. Lambert, V. Jacques, A. Shivanyuk, S. E. Matthews, A. Tunayar, M. Baaden, G. Wipff, V. Böhmer and J. Desreux, Inorg. Chem., 2000, 39, 2033-2041.
19. K. Iwamoto, K. Araki and S. Shinkai, J. Org. Chem., 1991, 56, 4955-4962.
20. A. Arduini, V. Böhmer, L. Delmau, J.-F. Desreux, J.-F. Dozol, M. A. Garcia Carrera, B. Lambert, C. Musigmann, A. Pochini, A. Shivanyuk and F. Ugozzoli, Chem. Eur. J., 2000, 6, 2135-2144.