Hydrolytic decarboxylation of carboxylic acids and the formation of protonated carbonic acid

Journal of the American Chemical Society

Volumn 132, Issue 7, 2010, Pages 2430-2436

  Mundle, Scott O C ^a   Lacrampe Couloume, Georges ^a   Lollar, Barbara Sherwood ^a   Kluger, Ronald ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION PARAMETER; ALTERNATIVE ROUTES; CARBONIC ACIDS; CARBOXYL GROUPS; CONJUGATE ACID; DECARBOXYLATION PROCESS; DECARBOXYLATION REACTIONS; ESTER HYDROLYSIS; KINETIC ISOTOPE EFFECTS; LEAVING GROUPS; PROTONATED; PYRROLE-2-CARBOXYLIC ACIDS; REACTION INTERMEDIATE; SOLVENT KINETIC ISOTOPE EFFECTS; VERY HIGH ENERGIES;

CARBON DIOXIDE; CARBOXYLATION; CARBOXYLIC ACIDS; CARRIER MOBILITY; COMPLEXATION; ESTERS; ISOTOPES; PROTONATION; REACTION INTERMEDIATES;

ORGANIC ACIDS;

2 PYRROLECARBOXYLIC ACID; CARBON; CARBON 13; CARBON DIOXIDE; CARBONIC ACID; CARBOXYLIC ACID; ESTER; SOLVENT; UNCLASSIFIED DRUG; WATER;

ACIDITY; ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONJUGATE; DECARBOXYLATION; HYDROLYSIS; ISOTOPE LABELING; KINETICS; PROTON TRANSPORT;

EID: 77749234183     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja910608m     Document Type: Article

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