Formation of side-chain hetero-polypseudorotaxane composed of α- and β-cyclodextrins with a water-soluble polymer bearing two recognition sites

Macromolecules

Volumn 43, Issue 4, 2010, Pages 1706-1713

  Taura, Daisuke ^a   Li, Shujing ^a   Hashidzume, Akihito ^a   Harada, Akira ^a,b  

^a OSAKA UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CDS; CIS ISOMERS; OLIGO(ETHYLENE GLYCOL); POLYPSEUDOROTAXANES; RECOGNITION SITE; SIDE CHAINS; SIDE-CHAIN; SIDE-CHAIN POLYROTAXANE; WATERSOLUBLE POLYMERS;

AROMATIC POLYMERS; BEARINGS (STRUCTURAL); CYCLODEXTRINS; ETHYLENE; ETHYLENE GLYCOL;

DATA STORAGE EQUIPMENT;

EID: 77249163649     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma902712u     Document Type: Article

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49. max = 326 nm) for the model compound (OEG-Azo), it was difficult to discuss the aggregation of the trans-Azo moieties in 1 in the absence of a-CD from, the UV - vis absorption spectra. However, we observed the NMR signals due to the Azo moieties in 1 became sharper upon addition of α-CD, indicative of association of the trans-Azo moieties in 1 in the absence of α-CD.
50. It may be possible to isolate polyrotaxane of 1 with a-CD after photoisomerization by size exclusion chromatography or dialysis. However, it is known that the as-Azo moiety is isomerized back to the trans isomer not only under visible light irradiation but also by a thermal, process. Thus, we would not try to isolate the polyrotaxane by removing excess a-CD because we would like to maintain the cw-Azo content as high as possible.
51. 7 and cis-Azo moieties were roughly estimated to be ca. 0.7 and 0.8, respectively, under the present conditions, indicating that the main species is the hetero-polypseudorotaxane.