New assembly of transition metal complexes based on [GeW9O34]10- building blocks: Syntheses, crystal structures and magnetic properties

Inorganic Chemistry Communications

Volumn 13, Issue 3, 2010, Pages 372-375

  Jiang, Ning ^a   Li, Fengyan ^a   Xu, Lin ^a   Li, Yungao ^a   Li, Jianmei ^a  

^a BEIJING UNIVERSITY OF POSTS AND TELECOMMUNICATIONS   (China)

Author keywords

Magnetic property; Polyoxometalate; Polyoxotungstogermanate; Sandwich

Indexed keywords

EID: 76749106491     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.12.025     Document Type: Article

References (24)

1. In: Hill C. (Ed). Chem. Rev., Polyoxometalates (1998)
2. In: Pope M.T., and Müller A. (Eds). Polyoxometalate Chemistry: from Topology via Self-assembly to Applications (2001), Kluwer Academic Publishers, Dordrecht, The Netherlands
3. Weakley T.J.R., Evans H.T., Showell J.S., Tourné G.F., and Tourné C.M. J. Chem. Soc. Chem. Commun. (1973) 139
4. Evans H.T., Tourné G.F., Tourné C.M., and Weakley T.J.R. J. Chem. Soc., Dalton Trans. (1986) 2699
5. Gómez-García C.J., Coronado E., and Borrás-Almenar J. Inorg. Chem. 31 (1992) 1667
6. Clemente-Juan J.M., Andres H., Borrás-Alamenar J.J., Coronado E., Güdel H.U., Aebersold M., Kearly G., Büttner H., and Zollinker M. J. Am. Chem. Soc. 121 (1999) 10021
7. Andres H., Clemente-Juan J.M., Aebersold M., Güdel H.U., Coronado E., Büttner H., Kearly G., Melero J., and Burriel R. J. Am. Chem. Soc. 121 (1999) 10028
8. Clemente-Juan J.M., Coronado E., Galán-Mascarós J.R., and Gómez-García C.J. Inorg. Chem. 38 (1999) 55
9. Kortz U., Isber S., Dickman M.H., and Ravot D. Inorg. Chem. 39 (2000) 2915
10. Bi L.H., Huang R.D., Peng J., Wang E.B., Wang Y.H., and Hu C.W. J. Chem. Soc., Dalton Trans. (2001) 121
11. Kortz U., Nellutla S., Stowe A.C., Dalal N.S., van Tol J., and Bassil B.S. Inorg. Chem. 43 (2004) 144
12. Kortz U., Nellutla S., Stowe A.C., Dalal N.S., Rauwald U., Danquah W., and Ravot D. Inorg. Chem. 43 (2004) 2308
13. Yamase T., Abe H., Ishikawa E., Nojiri H., and Ohshima Y. Inorg. Chem. 48 (2009) 138
14. Wang J.P., Ma P.T., Shen Y., and Niu J.Y. Crystal. Growth & Design 8 (2008) 3130
15. Wang G.W., Chen Y., Zou Y.C., Wang Y., Wang H.T., Li K.C., Cui X.B., Shi S.Y., and Xu J.Q. Inorg. Chem. Commun. 12 (2009) 646
16. Mbomekalle I.M., Keita B., Nierlich M., Kortz U., Berthet P., and Nadjo L. Inorg. Chem. 42 (2003) 5143
17. J.J. Borras-Almenar, J.M. Clemente-Juan, M. Clemente-Leon, E. Coronado, J.R. Galan- Mascaros, C.J. Gomez-Garcia, in: M.T. Pope, A. Müller (Eds.), Polyoxometalate Chemistry: From Topology Via Self-Assembly to Applications, Kluwer, Dordrecht, The Netherlands, 2001, p. 231.
18. Ritorto M.D., Anderson T.M., Neiwert W.A., and Hill C.L. Inorg. Chem. 43 (2004) 44
19. Compain J.D., Mialane P., Dolbecq A., Mbomekallé I.M., Marrot J., Sécheresse F., Rivière E., Rogez G., and Wernsdorfer W. Angew. Chem., Int. Ed. 48 (2009) 3077
20. Li B., Zhao J.W., Zheng S.T., and Yang G.Y. Inorg. Chem. Commun. 12 (2009) 69
21. 2O were added with stirring (pH 7.3-7.6). The solution was heated at 90 °C for 1 h and then filtered. Brown crystals (0.208 g) suitable for X-ray analysis were obtained after the filtrate was kept for two days at room temperature. The yield was ∼12% based on W. IR: 941 (s), 875 (s), 770 (s), 697 (s), 509 (w), 458 (m). Elemental analyses calcd. (%): W 59.59, Mn 4.45, Ge 2.94, Na 3.11, O 28.74, H 1.17. Found: W 59.33, Mn 4.57, Ge 2.85, Na 3.19, O 28.81, H 1.25.
22. Kα radiation (λ = 0.71073 Å) at 293(2) K.
23. Kα radiation (λ = 0.71073 Å) at 296(2) K. Further details of the structure determination are available on request from the ICSD Team, FIZ Karlsruhe, Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen.
24. Brown I.D., and Altermatt D. Acta Crystallogr. B41 (1985) 244