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Volumn 8, Issue 9, 2008, Pages 3130-3133

Tetra-transition-metal substituted weakley-type sandwich germanotungstates and their derivatives decorated by transition-metal complexes

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Indexed keywords


EID: 61549086539     PISSN: 15287483     EISSN: 15287505     Source Type: Journal    
DOI: 10.1021/cg701278b     Document Type: Article
Times cited : (60)

References (61)
  • 45
    • 61549092660 scopus 로고    scopus 로고
    • Single-crystal X-ray datajbr 1: H67Co 4Ge2Na11O101W18, Mr, 5626.63, triclinic, space group P1̄, a, 11.6603(10) Å, b, 12.8738(11) Å, c, 17.2486(15) Å, α, 97.7(10)°, β, 106.52(10)°, γ, 112.16(10)°, Z, 1, V, 2212.5(3) Å3, T, 293(2) K, Dc, 4.223 g cm-3, μ, 24.868 mm-1, Of 11029 total reflections collected, 7644 were unique (Rint, 0.0478, R1(WR2, 0.0506(0.1306) for 629 parameters and 6881 reflections [I < 2σ(I, For 2: C144H112Co 7Ge2N24O76W19, Mr =7445.38, monoclinic, space group C2/m, a, 23.621(5) Å, b, 32.045(6) Å, c
    • 2) = 0.0630(0.1587) for 1369 parameters and 9035 reflections [I < 2σ(I)]. Intensity data were collected with a Rigaku RAXIS-IV image plate area detector using graphite monochromatized Mo Kα radiation (λ = 0.71073 Å) at room temperature. The structures were solved by direct methods and refined using full-matrix least-squares on F. All calculations were performed using the SHELXL-97 program package. Intensity data were corrected for Lorentz and polarization effects as well as for empirical absorption. All of the non-hydrogen atoms were refined anisotropically. The organic hydrogen atoms were generated geometrically; the aqua hydrogen atoms were not located. Further details of the crystal structure investigation can be obtained from from the Fachinformationszentrum Karlsruhe [CSD no. 418579 (1)] and the Cambridge Crystallographic Data Centre [CCDC nos. 661205-661209 for 2-6].


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