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Single-crystal X-ray datajbr 1: H67Co 4Ge2Na11O101W18, Mr, 5626.63, triclinic, space group P1̄, a, 11.6603(10) Å, b, 12.8738(11) Å, c, 17.2486(15) Å, α, 97.7(10)°, β, 106.52(10)°, γ, 112.16(10)°, Z, 1, V, 2212.5(3) Å3, T, 293(2) K, Dc, 4.223 g cm-3, μ, 24.868 mm-1, Of 11029 total reflections collected, 7644 were unique (Rint, 0.0478, R1(WR2, 0.0506(0.1306) for 629 parameters and 6881 reflections [I < 2σ(I, For 2: C144H112Co 7Ge2N24O76W19, Mr =7445.38, monoclinic, space group C2/m, a, 23.621(5) Å, b, 32.045(6) Å, c
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