Experimental and theoretical conformational analysis of 5-benzylimidazolidin-4-one derivatives - A 'playground' for studying dispersion interactions and a 'windshield-wiper' effect in organocatalysis

Helvetica Chimica Acta

Volumn 93, Issue 1, 2010, Pages 1-16

  Seebach, Dieter ^a   Grošelj, Uroš ^a,c   Schweizer, W Bernd ^a   Grimme, Stefan ^b   Mück Lichtenfeld, Christian ^b  

^a ETH ZURICH   (Switzerland)

^b UNIVERSITY OF MÜNSTER   (Germany)

^c UNIVERSITY OF LJUBLJANA   (Slovenia)

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE RING; BENZYL GROUP; BENZYLIC; C-C BONDS; CO-GROUP; CONFORMATIONAL ANALYSIS; CONJUGATE ADDITION; DIELS-ALDER REACTION; DISPERSION CONTRIBUTION; DISPERSION INTERACTION; ENANTIOSELECTIVE; ENANTIOSELECTIVE CATALYSTS; ENERGY DIFFERENCES; HETEROCYCLES; IDEAL SYSTEMS; IMINIUM; IMINIUM IONS; ISOPROPYLIDENE; MAXIMUM DISTANCE; ORGANOCATALYSIS; ORGANOCATALYTIC; QUANTUM CHEMICAL COMPUTATIONS; QUANTUM-CHEMICAL METHODS; REACTIVE INTERMEDIATE; SINGLE-POINT CALCULATIONS; STERIC INTERACTIONS; THEORETICAL RESULT; UNSATURATED CARBONYL COMPOUNDS; X-RAY STRUCTURE;

ADDITION REACTIONS; AIRCRAFT WINDSHIELDS; BENZENE; CARBONYLATION; CATALYSIS; CHEMICAL BONDS; CRYSTAL STRUCTURE; DISPERSIONS; IONS; QUALITY CONTROL; REACTION INTERMEDIATES; REACTION KINETICS; ROTATION; SINGLE CRYSTALS; UNSATURATED COMPOUNDS;

CONFORMATIONS;

5 BENZYL 1 CINNAMYLIDENE 3 METHYLIMIDAZOLIDIN 4 ONE DERIVATIVE; 5 BENZYLIMIDAZOLIDIN 3 ONE DERIVATIVE; IMIDAZOLINE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; CROSS LINKING; CRYSTAL STRUCTURE; DIELS ALDER REACTION; ENANTIOSELECTIVITY; PRIORITY JOURNAL; X RAY ANALYSIS;

EID: 76149119815     PISSN: 0018019X     EISSN: 15222675     Source Type: Journal    
DOI: 10.1002/hlca.200900376     Document Type: Article

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