Ruthenium seleno- and tellurocarbonyl complexes: Selenium and tellurium atom transfer to a terminal carbido ligand

Organometallics

Volumn 29, Issue 3, 2010, Pages 519-522

  Mutoh, Yuichiro ^a   Kozono, Naoki ^a   Araki, Miho ^a   Tsuchida, Noriko ^b   Takano, Keiko ^b   Ishii, Youichi ^a  

^a CHUO UNIVERSITY   (Japan)

^b OCHANOMIZU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ATOM TRANSFER;

ATOMS; RUTHENIUM; SELENIUM; TELLURIUM; TELLURIUM COMPOUNDS;

RUTHENIUM COMPOUNDS;

EID: 76149111609     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om901029w     Document Type: Article

References (47)

1. Baird, M. C; Wilkinson, G. J. Chem. Soc. Chem. Commun. 1966, 267-268.
2. For reviews, see: (a) Butler, I. S.; Fenster, A. E. J. Organomet. Chem. 1974, 66, 161-194.
3. (b) Yaneff, P. V. Coord. Chem. Rev. 1977, 23, 183-220.
4. (c) Butler, I. S. Ace. Chem. Res. 1977, 10, 359-365.
5. (d) Broadhurst, P. V. Polyhedron 1985, 4, 1801-1846.
6. (d) Butler, I. S. Pure Appl. Chem. 1988, 60, 1241-1244
7. (e) Moltzen, E. K.; Klabuunde, K. J.; Senning, A. Chem. Rev. 1988, 88, 391-406.
8. (f) Petz, W Coord. Chem. Rev. 2008, 252, 16891733.
9. Clark, G. R.; Grundy, K. R.; Harris, R. O.; James, S. M.; Roper, W. R. J. Organomet. Chem. 1975, 90, C37-C39.
10. For other examples of CSe complexes, see: (a) Butler, I. S.; Cozak, D.; Stobart, S. R. J. Chem. Soc., Chem. Commun. 1975, 103-104.
11. (b) Saillard, J.-Y. J. Grandjean, D. Acta Crystallogr., Sect. B: Struct. Sci. 1978, 34, 3772-3775.
12. (c) Brothers, P. J.; Headfbrd, C. E. L.; Roper, W R. J. Organomet. Chem. 1980, 195, C29-C33.
13. (d) Cozak, D.; Butler, I. S.; Baibich, I. M. J. Organomet. Chem. 1979, 169, 381-393.
14. (e) Battioni, J.-P.; Mansuy, D.; Chottard, J.-C. Inorg. Chem. 1980, 19, 791-792
15. (f) Gorce, J.-N.;Bottomley,L. A.Inorg. Chem. 1985, 24, 1431-1436.
16. (g)Ismail, A. A.; Butler, I. S.; Bonnet, J.-J.; Askenazy, S. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1985, 41, 1582-1585.
17. (a) Clark, G. R.; Marsden, K.; Roper, W. R.; Wright, L. J. J. Am. Chem. Soc. 1980, 102, 1206-1207.
18. (b) Clark, G. R.; Marsden, K.; Rikard, C. E. F.; Roper, W R.; Wright, L J. J. Organomet. Chem. 1988, 338, 393-410.
19. Desmond, T.; Lalor, F. J.; Ferguson, G.; Parvez, M. J. Chem. Soc., Chem. Commun. 1984, 75-77.
20. 3]:
21. 2] (Tp = hydrotris(lpyrazolyl)borate):
22. (b) Crevier, T. J.; Lovell, S.; Mayer, J. M.; Rheingold, A. L.; Guzei, I. A. J. Am. Chem. Soc. 1998, 120, 6607-6608.
23. "K[Mo=C-Te]" was described as a dimer:
24. (a) Greko, J. B.; Peters, J. C.; Baker, T. A.; Davis, W. M.; Cummins, C. C; Wu, G. J. Am. Chem. Soc. 2001, 123, 5003-5013.
25. - were reported:
26. (c) Cade, I. A.; Hill, A. F.; McQueen, C. M. A. Organometallics 2009, 28, 6639-6641.
27. 2] has also been reported:
28. (b) Stewart, M. H.; Johnson, M. J. A.; Kampf, J. W Organometallics 2007, 26, 5102-5110.
29. (a) Carlson, R. G.; GiIe, M. A.; Happert, J. A.; Mason, M. H.; Powell, D. R.; Vander Velde, D.; Vilain, J. M. J. Am. Chem. Soc. 2002, 124, 1580-1581.
30. (b) Romero, P. E.; Piers, W E.; McDonald, R. Angew. Chem., Int. Ed. 2004, 43, 6161-6165.
31. (c) Dubberley, S. R.; Romero, P.; Piers, W E.; Parvez, M. Inorg. Chim. Acta 2006, 359, 2658-2664.
32. 14: C, 57.84; H, 7.45; N, 3.14. Found: C, 57.83; H, 7.51; N, 3.33.
33. (a) Brooks, R. R.; Counter, J. A.; Bishop, R.; Tiekink, E. R. E. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1991,47,1939-1941 .
34. (b) Olcuma, K.; Kojima, K.; Kanelco, I; Tsujimoto, Y; Ohta, H.; Yokomori, Y. J. Chem. Soc, Perkin Trans. 1 1994, 2151-2159.
35. (a) Love, J. A.; Sanford, M. S.; Day, M. W.; Grubbs, R. H. J. Am. Chem. Soc. 2003, 125, 10103-10109.
36. (b) Mutoh, Y; Ikeda, Y; Kimura, Y; Ishii, Y. Chem. Lett. 2009, 35, 534-535.
37. Density functional theory (DFT) calculations were performed at the B3P86/SBKJC(d) level. See the Supporting Information for details.
38. Preliminary DFT studies suggest that a five-coordinate CTe complex with distorted-square-pyramidal geometry may be found as a local minimum structure.
39. 2O: C, 50.74; H, 5.72; N, 9.34. Found: C, 50.38; H, 5.58; N, 9.09.
40. Roper, W. R. J. Organomet. Chem. 1986, 300, 167-190.
41. Minoura, M.; Kawashima, T.; Tokitoh, N.; Okazaki, R. Chem. Commun. 1996, 123-124.
42. 3)] (2-CO) with DMAP. See the Supporting Information. (Figure Presented)
43. (a) Saillard, J.-Y.; Grandjean, D.; Caillet, P.; Le Beuze, A. J. Organomet. Chem. 1980, 190, 371-379.
44. (b) Ziegler, T. Inorg. Chem. 1986, 25, 2721-2727.
45. 9th
46. 12b.
47. 2, benzene, and acetone); the grayish black powder that precipitated in this process was unambiguously confirmed to be elemental tellurium by a powder X-ray diffraction study. Although we have to await further investigation, we believe that DMAP plays an important role in stabilizing the ruthenium species with a highly «-acidic CTe ligand, as described in the main text. Now we are examining degradation of 3-CTe in detail, experimentally and theoretically, and the results will be reported in due course.