Li-ion anodes in air-stable and hydrophobic ionic liquid-based electrolyte for safer and greener batteries

International Journal of Energy Research

Volumn 34, Issue 2, 2010, Pages 97-106

  Lux, Simon F ^a   Schmuck, Martin ^b   Jeong, Sangsik ^a   Passerini, Stefano ^a   Winter, Martin ^a   Balducci, Andrea ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

^b GRAZ UNIVERSITY OF TECHNOLOGY   (Austria)

Author keywords

Anodic materials; Binders; Green chemistry; Ionic liquids; Lithium batteries

Indexed keywords

AIR-STABLE; ANODIC MATERIALS; CYCLING EFFICIENCY; CYCLING STABILITY; ELECTROLYTE ADDITIVES; ELECTROLYTIC SOLUTION; GREEN CHEMISTRY; HYDROPHOBIC IONIC LIQUID; ROOM TEMPERATURE; SILICON ELECTRODE; SOLID ELECTROLYTE INTERPHASE; SPECIFIC CAPACITIES;

BINDERS; GRAPHITE; IONIC LIQUIDS; IONIZATION OF LIQUIDS; IONS; LITHIUM; LITHIUM BATTERIES; SOLID ELECTROLYTES;

GRAPHITE ELECTRODES;

EID: 75749111749     PISSN: 0363907X     EISSN: 1099114X     Source Type: Journal    
DOI: 10.1002/er.1557     Document Type: Article

References (46)

1. van Schalkwijk WA, Scrosati B. Advanced in Lithium-Ion Batteries. Kluwer Academic/Plenum Publisher: New York, 2002.
2. Nazri GA, Pistoia G. Lithium Batteries. Kluwer Academic/Plenum Publisher: Norwell, 2004.
3. Wasserscheid P, Keim W. Ionic liquids-new 'solutions' for transition metal catalysis. Angewandte Chemie (International ed. in English) 2000; 39:3772.
4. Rogers R, Seddon KR. (eds). Ionic Liquids-Industrial Application to Green Chemistry: ACS Symposium Series 818: Oxford University Press: Oxford, 2002.
5. Earle MJ, Seddon KR. Ionic liquids. Green solvent for the future. Pure and Applied Chemistry 2000; 72:1391.
6. Anderson JL, Welton DT, Armstrong DW. Characterizing ionic liquids on the basis of multiple solvation interactions. Journal of the American Chemical Society 2002; 124:14247.
7. Dupont J, de Souza RF, Suarez PAZ. Ionic liquids (Molten salts) phase organometallic catalysis. Chemical Reviews 2002; 102:3667.
8. Bhatt AI, May I, Volkovich VA, Hetherington ME, Lewin B, Thied RC, Ertok N. Journal of the Chemical Society-Dalton Transactions 2002; 24:4532.
9. Fuller J, Breda AC, Carlin RT. Ionic liquid-polymer gel electrolytes from hydrophilic and hydrophobic ionic liquids. Journal of Electroanalytical Chemistry 1998; 29:459.
10. Nakagawa H, Izuchi S, Kunawa K, Nukuda T, Aihara Y. Liquid and polymer gel electrolytes for lithium batteries composed of room-temperature molten salt doped by lithium salt. Journal of the Electrochemical Society 2003; 150:A695.
11. Sakaebe H, Matsumoto H. N-methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13-TFSI)-novel electrolyte base for Li battery. Electrochemistry Communications 2003; 5:594.
12. Noda A, Susan MABH, Kudo K, Mitsushima S, Hayamizu K, Watanabe M. Acid-base ionic liquids as proton-conducting nonaqueous electrolytes. Journal of Physical Chemistry B 2003; 107:4024.
13. Balducci A, Henderson WA, Mastragostino M, Passerini S, Simon P, Soavi F. Cycling stability of a hybrid activated carbon//poly(3-methylthiophene) supercapacitor with N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide ionic liquid as electrolyte. Electrochimica Acta 2005; 50:2233.
14. Shin JH, Henderson WA, Passerini S. PEO-based polymer electrolytes with ionic liquids and their use in lithium metal-polymer electrolyte batteries. Journal of the Electro-chemical Society 2005; 152:A978.
15. Shin JH, Henderson WA, Passerini S. An elegant fix for polymer electrolytes. Electrochemical and Solid State Letters 2005; 8:A125.
16. Shin JH, Henderson WA, Appetecchi GB, Alessandrini F, Passerini S. Recent developments in the ENEA lithium metal battery project. Electrochimica Acta 2005; 50:3859.
17. Garcia B, Lavallée S, Perron G, Michot C, Armand M. Room temperature molten salts as lithium battery electrolyte. Electrochimica Acta 2004; 49:4583-4588.
18. Lee SY, Kim Seok K, Ahn S. Nano-encapsulation of LiCoO2 cathodes by a novel polymer electrolyte and its influence on thermal safeties of Li-ion batteries. Electro-chemistry Communications 2008; 10(1):113-117.
19. -for Li-ion batteries. Journal of Power Sources 2008; 175(2):866-873.
20. Shin JH, Henderson WA, Scaccia S, Prosini PP, Passerini S. Solid-state Li/LiFePO4 polymer electrolyte batteries incorporating an ionic liquid cycled at 40°C. Journal of Power Sources 2006; 156(2):560-566.
21. Ishikawa M, Sugimoto T, Kikuta M, Ishiko E, Kono M. Pure ionic liquid electrolytes compatible with a graphitized carbon negative electrode in rechargeable lithium-ion batteries. Journal of Power Sources 2006; 162(1):658-662.
22. Lewandowski A, Świderska-Mocek A. Properties of the graphite-lithium anode in N-methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide as an electrolyte. Journal of Power Sources 2007; 171(2):938-943.
23. Holzapfel M, Jost C, Novák P. Stable cycling of graphite in an ionic liquid based electrolyte. Chemical Communiations 2004; 2098-2099.
24. Balducci A, Dugas R, Taberna PL, Simon P, Plee D, Mastragostino M, Passerini S. High temperature carboncarbon supercapacitor using ionic liquid as electrolyte. Journal of Power Sources 2007; 165:922.
25. Randstrom S, Appetecchi GB, Lagergren C, Moreno A, Passerini S. The influence of air and its components on the cathodic stability of N-butyl-N-methylpyrrolidinium bis-(trifluoromethanesulfonyl)imide. Electrochemica Acta 2007; 53:1837.
26. Howlett PC, Izgorodina EI, Forsyth M, MacFarlane DR. Electrochemistry at negative potentials in bis(trifluoromethanesulfonyl)amide ionic liquids. Zeitschrift Fur Physikalische Chemie 2006; 220:1483-1498.
27. Appetecchi GB, Scaccia S, Tizzani C, Alessandrini F, Passerini S. Synthesis of hydrophobic ionic liquids for electrochemical applications. Journal of Electrochemical Society 2006; 153:A1655.
28. Shin JH, Henderson WA, Tizzani C, Passerini S, Jeong SS, Kim KW. Characterization of solvent-free polymer electrolytes consisting of ternary PEO-LiTFSI-PYR14 TFSI. Journal of Electrochemical Society 2006; 153:A1649.
29. Brazier A, Appetecchi GB, Passerini S, Surca Vuk A, Orel B, Donsanti F, Dnecker F. Ionic liquids in electrochromic devices. Electrochimica Acta 2007; 52:4792.
30. Rymarczyk J, Carewska M, Appetecchi GB, Zane D, Alessandrini F, Passerini S. A novel ternary polymer electrolyte for LMP batteries based on thermal cross-linked poly(urethane acrylate) in presence of a lithium salt and an ionic liquid. European Polymer Journal 2008; 44:2153.
31. Shin JH, Henderson WA, Passerini S. Ionic liquids to the rescue? Overcoming the ionic conductivity limitations of polymer electrolytes. Electrochemistry Communications 2003; 5:1016.
32. Balducci A, Schmuck M, Kern W, Rupp B, Passerini S, Winter M. Ionic liquids as electrolyte in lithium batteries: in situ FTIRS studies on the use of electrolyte additives. ECS Transactions 2008; 11(29):109.
33. Appetecchi GB, Montanino M, Balducci A, Lux SF, Winter M, Passerini S. Lithium insertion in graphite from ternary ionic liquid-lithium salt electrolytes. I. Electrochemical characterization of the electrolytes. Journal of Power Sources, accepted, available on-line, DOI: 10.1016/j.powsour.2008.12.095.
34. Schmuck M, Balducci A, Rupp B, Kern W, Passerini S, Winter M. Alloying of electrodeposited silicon with lithium-a principal study of applicability as anode materials for lithium-ion batteries. Journal of Solid State Electrochemistry, available on-line, DOI: 10.1007/s10008-0088-0763-4.
35. Lux SF, Schmuck M, Rupp B, Kern W, Appetecchi GB, Passerini S, Winter M, Balducci A. Mixtures of ionic liquids in combination with graphite electrodes: the role of li-Salt. ECS Transactions, accepted.
36. Lux SF, Schmuck M, Appetecchi GB, Winter M, Passerini S, Balducci A. Lithium insertion in graphite from ternary ionic liquid-lithium salt electrolytes. II. Evaluation of specific capacity and cycling efficiency and stability at room temperature. Journal of Power Sources, DOI: 10.1016/j.powsour.2009.02.066.
37. Ishikawa M, Sugimoto T, Kikuta M, Ishiko E, Kono M, Pure ionic liquid electrolytes compatible with a graphitized carbon negative electrode in rechargeable lithium-ion batteries. Journal of Power Sources 2006; 162:658.
38. Xu J, Yang J, NuLi Y, Wang J, Zhang Z. Additive-containing ionic liquid electrolytes for secondary lithium battery. Journal of Power Sources 2006; 160:621.
39. Zheng H, Bao L, Fu Y, Takeshi A, Zempachi O. Compatibility of quaternary ammonium-based ionic liquid electrolytes with electrodes in lithium ion batteries. Electrochimica Acta 2006; 52:1556.
40. Zheng H, Jiang K, Abe T, Ogumi Z. Electrochemical intercalation of lithium into a natural graphite anode in quaternary ammonium-based ionic liquid electrolytes. Carbon 2006; 44:203.
41. Holzapfel M, Jost C, Prodi-Schwab A, Krumeich F, Würsig A, Buqa H, Novák P, Stabilisation of lithiated graphite in an electrolyte based on ionic liquids: an electrochemical and scanning electron microscopy study. Carbon 2005; 43:1488.
42. Howlett PC, MacFarlane, Hollenkamp AF. High lithium metal cycling efficiency in a room temperature ionic liquid. Electrochemical Solid-state Letters 2004; 7:A97.
43. Howlett PC, Brack N, Hollenkamp AF, Forsyth M, MacFarlane DR. Characterization of the lithium surface in N-methyl-N-alkylpyrrolidinium Bis(trifluoromethanesul-fonyl)amide room-temperature ionic liquid electrolytes. Journal of Electrochemical Society 2006; 153:A595.
44. Winter M, Besenhard JO. Electrochemical lithiation of tin and tin-based intermetallics and composites. Electrochimica Acta 1999; 45:31.
45. Boukamp BA, Lesh GC, Huggins RA. All-solid lithium electrodes with mixed-conductor matrix. Journal of Electrochemical Society 1981; 128:725.
46. Hochgatterer NS, Schweiger MR, Koller S, Raimann P, Wöhrle T, Wurm C, Winter M. Silicon/graphite composite electrodes for high-capacity anodes: influence of binder chemistry on cycling stability. Electrochemical and Solid-state Letters 2008; 11(5):A80.