Base-catalyzed insertion of dioxygen into rhodium-hydrogen bonds: Kinetics and mechanism

Inorganic Chemistry

Volumn 49, Issue 3, 2010, Pages 781-785

  Szajna Fuller, Ewa ^a   Bakac, Andreja ^a  

^a IOWA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA; HYDROGEN; ORGANOMETALLIC COMPOUND; OXYGEN; RHODIUM;

ARTICLE; CATALYSIS; CHEMISTRY; HYDROGEN BOND; KINETICS; OXIDATION REDUCTION REACTION; PH; THERMODYNAMICS;

AMMONIA; CATALYSIS; HYDROGEN; HYDROGEN BONDING; HYDROGEN-ION CONCENTRATION; KINETICS; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; OXYGEN; RHODIUM; THERMODYNAMICS;

EID: 75649124917     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic901808t     Document Type: Article

References (32)

1. Look, J. L.; Wick, D. D.; Mayer, J. M.; Goldberg, K. I. Inorg. Chem. 2009, 48, 1356-1369.
2. Wick, D. D.; Goldberg, K. I. J. Am. Chem. Soc. 1999, 121, 11900-11901.
3. Denney, M. C.; Smythe, N. A.; Cetto, K. L.; Kemp, R. A.; Goldberg, K. I. J. Am. Chem. Soc. 2006, 128, 2508-2509.
4. Tonnick, M. M.; Stahl, S. S. J. Am. Chem, Soc. 2008, 130, 5753-5762 and references therein.
5. Thyagarajan, S.; Incarvito, C. D.; Rheingold, A. L.; Theopold, K. H. Chem. Commun. 2001, 2198-2199.
6. Bakac, A. Dalton Trans. 2006, 1589-1596.
7. Roberts, H. L.; Symes, W. R. J. Chem. Soc., A 1968, 1450.
8. Gillard, R. D.; Heaton, B. T.; Vaughan, D. H. J. Chem. Soc., A 1970, 3126.
9. Endicott, J. F.; Wong, C.-L.; Inoue, T.; Natarajan, P. Inorg. Chem. 1979, 18, 450-1154
10. Cui, W.; Wayland, B. B. J. Am. Chem. Soc. 2006, 128, 10350-10351.
11. Keith, J. M.; Muller, R. P.; Kemp, R. A.; Goldberg, K. I.; Goddard, W. A.; Oxgaard, J. Inorg. Chem. 2006, 45, 9631-9633.
12. Bakac, A. J. Am. Chem. Soc. 1997, 119, 10726-10731.
13. Bakac, A. J. Photochem. Photobiol, A 2000, 132, 87-89.
14. Popp, B. V.; Stahl, S. S. Chem.-Eur. J. 2009, 15, 2915-2922.
15. Bakac, A. Coord. Coord. Chem. Rev. 2006, 250, 2046-2058.
16. Fulmer, G. R.; Muller, R. P.; Kemp, R. A.; Goldberg, K. I. J. Am. Chem. Soc. 2009, 131, 1346-1347.
17. Schlangen, M.; Schwarz, H. Helv. Chim. Acta 2008, 91, 379-386.
18. Takehira, K.; Hayakawa, T.; Orita, H. Chem. Lett. 1985, 1835-1838.
19. Hosokawa, T.; Murahashi, S. Acc. Chem. Res. 1990, 23, 49-54.
20. Jiang, B.; Feng, Y.; Ison, E. A. J. Am. Chem. Soc. 2008, 130, 14462-14464.
21. Nishimura, T.; Kakiuchi, N.; Onoue, T.; Ohe, K.; Uemura, S. J. Chem. Soc., Perkin Trans. 1 2000, 1915-1918.
22. Roussel, M.; Mimoun, H. J. Org. Chem. 1980, 45, 5387-5390.
23. Pestovsky, O.; Bakac, A. Inorg. Chem. 2002, 41, 3975-3982.
24. Vasbinder, M.; Bakac, A. Inorg. Chim. Acta 2008, 361, 3193-3198.
25. Vasbinder, M. J.; Bakac, A. Inorg. Chem. 2007, 46, 2921-2928.
26. Lemma, K.; Ellern, A.; Bakac, A. Inorg. Chem. Inorg. Chem. 2003, 42, 3662-3669.
27. Thomas, K.; Osborn, J. A.; Powell, A. R.; Wilkinson, G. J. Chem. Soc., A. 1968, 1801-1806.
28. Bakac, A.; Thomas, L. M. Inorg. Chem. 1996, 35, 5880-5884.
29. Szajna-Fuller, E.; Bakac, A. Inorg. Chem. 2007, 46, 10907-10912.
30. Springborg, J.; Zehnder, M. Acta Chem. Scand., Ser. A 1987, A41 484-495.
31. Pearson, R. G. In Bonding Energetics in Organometallic Compounds; Marks, T. J., Ed.; American Chemical Society: Washington, DC, 1990; pp 251-262.
32. Konnick, M. M.; Gandhi, B. A.; Guzei, I. A.; Stahl, S. S. Angew. Chem., Int. Ed. 2006, 45, 2904-2907.