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Volumn 83, Issue 1, 2010, Pages 52-57

Synthesis and properties of secondary thiocarbamoylsilanes

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL GROUPS; AROMATIC RINGS; BROOK REARRANGEMENT; CARBAMOYL; CARBON ATOMS; CHLOROSILANES; DFT CALCULATION; ELECTRON WITHDRAWING GROUP; NITROGEN ATOM; ORBITAL INTERACTION; SILYL GROUP; SILYLATION REACTION; THIOCARBONYL; UV-VISIBLE SPECTRA;

EID: 75449100516     PISSN: 00092673     EISSN: 13480634     Source Type: Journal    
DOI: 10.1246/bcsj.20090231     Document Type: Article
Times cited : (6)

References (79)
  • 25
    • 21644460853 scopus 로고    scopus 로고
    • ed. by A. R. Katritzky, R. J. K. Taylor, Elsevier Ltd., Oxford
    • (a) For recent reviews: A. J. Moore, in Comprehensive Organic Functional Group Transformations II, ed. by A. R. Katritzky, R. J. K. Taylor, Elsevier Ltd., Oxford, 2005, Vol.5, p. 519.
    • (2005) Comprehensive Organic Functional Group Transformations II , vol.5 , pp. 519
    • Moore, A.J.1
  • 72
    • 84913665068 scopus 로고
    • Silylation of 5 on the nitrogen atom may be possible since the silylation of lithium thioimidates derived from secondary thioamides has been reported to give a mixture of N-silylthioamides and S-silyl thioimidates, and they are in equilibrium
    • Silylation of 5 on the nitrogen atom may be possible since the silylation of lithium thioimidates derived from secondary thioamides has been reported to give a mixture of N-silylthioamides and S-silyl thioimidates, and they are in equilibrium: W. Walter, H.-W. Lüke, J. Vol., Justus Liebigs Ann. Chem. 1975, 1808.
    • (1975) Justus Liebigs Ann. Chem. , pp. 1808
    • Walter, W.1    Lüke, H.-W.2    Vol, J.3
  • 73
    • 75449113146 scopus 로고    scopus 로고
    • The formation of Z-7 from thioformamides bearing primary carbon atoms attached to the nitrogen atom has been postulated at this stage. However, thioformamides 1n1p may be converted to E isomers because of the steric influence of alkyl and aryl groups attached to the nitrogen atom. The reverse Brook rearrangement of E isomers may then be sterically disturbed
    • The formation of Z-7 from thioformamides bearing primary carbon atoms attached to the nitrogen atom has been postulated at this stage. However, thioformamides 1n1p may be converted to E isomers because of the steric influence of alkyl and aryl groups attached to the nitrogen atom. The reverse Brook rearrangement of E isomers may then be sterically disturbed.
  • 79
    • 75449111725 scopus 로고    scopus 로고
    • E can also elongate the C=O and C=S bonds
    • E can also elongate the C=O and C=S bonds.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.