In situ studies of the mass transfer mechanism across a methane hydrate film using high-resolution confocal Raman spectroscopy

Journal of Physical Chemistry C

Volumn 114, Issue 2, 2010, Pages 1173-1180

  Davies, Simon R ^a   Sloan, E Dendy ^a   Sum, Amadeu K ^a   Koh, Carolyn A ^a  

^a Department of Geology and Geological Engineering   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CONCENTRATION PROFILES; CONFOCAL RAMAN SPECTROSCOPY; CRYSTAL FILMS; GAS MIGRATION; GAS-WATER INTERFACE; HIGH RESOLUTION; HOST MOLECULES; HYDRATE FILM; HYDRATE FORMATION; HYDRATE GROWTH; HYDRATE PHASE; IN-SITU STUDY; ISOTOPIC TRACER; MASS TRANSFER BARRIERS; MASS TRANSFER MECHANISM; MASS TRANSFER RESISTANCES; METHANE HYDRATES; MOBILE SPECIES; RELATIVE MOBILITY; WATER MOLECULE; WATER PHASIS;

FILM GROWTH; GAS HYDRATES; GAS PERMEABLE MEMBRANES; GASES; HYDRATION; MASS TRANSFER; METHANE; MOLECULES; RAMAN SCATTERING; RAMAN SPECTROSCOPY;

PHASE INTERFACES;

EID: 75249100371     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp909416y     Document Type: Article

References (66)

1. Sloan, E. D.; Koh, C. A. Clathrate Hydrates of Natural Gases, 3rd Ed.; CRC Press, Taylor and Francis Group: Boca Raton FL, 2008.
2. Makogan, Y. F. Hydrates of Natural Gas; PennWell Publishing: Tulsa, OK, 1981.
3. Kvenvolden, K. A.; Rogers, B. W. Mar. Pet. Geol. 2005, 22, 579-590.
4. Allison, E.; Boswell, R. Methane Hydrate, Future Energy Within Our Grasp, An Overview. DOE Report, 2007.
5. Koh, C. A.; Sloan, E. D. AIChE J. 2007, 53, 1636-1643.
6. Stevens, J. C; Husebø, J.; Ersland, G. R; Baldwin, B. A.; Graue, A.; Howard, J. J. Experimental Hydrate Formation and Gas Production Scenarios Based on CO2 Sequestration. 6th International Conference on Gas Hydrates, Vancouver, BC,July 5-10, 2008.
7. Maini, B. B.; Bishnoi, P. R. Chem. Eng. Sci. 1981, 36, 183-189.
8. Servio, P.; Englezos, P. AIChE J. 2003, 49, 269-276.
9. Taylor, C. J.; Miller, K. T.; Koh, C. A.; Sloan, E. D. Macroscopic Investigation of Hydrate Film Growth at the Hydrocarbon/Water Interface. 6th International Conference on Gas Hydrates, Vancouver, BC,July 6-10, 2008; p 5407.
10. Davies, S. R.; Lachance, J. W.; Sloan, E. D.; Koh, C. A. A Novel Approach To Measuring Methane Diffusivity Through A Hydrate Film Using Differential Scanning Calorimetry. 6th International Conference on Gas Hydrates, Vancouver, BC,July 6-10, 2008; p 5413.
11. Taylor, C. J.; Dieker, L. E.; Miller, K. T.; Koh, C. A.; Sloan, E. D. J. Colloid Interface Sci. 2007, 306, 255-261.
12. Teng, H.; Yamasaki, A.; Shindo, Y. Chem. Eng. Sci. 1996, 51, 4979-4986.
13. Hirai, S.; Okazaki, K.; Araki, N.; Yazawa, H.; Ito, H.; Hijikata, K. Energy Convers. Manage. 1996, 37, 1073-1078.
14. Uchida, T.; Ebinuma, T.; Kawabata, J.; Narita, H. J. Cryst. Growth 1999, 204, 348-356.
15. Uchida, T.; Ikeda, I. Y.; Takeya, S.; Ebinuma, T.; Nagao, J.; Narita, H. J. Cryst. Growth 2002, 237-239, 383-387.
16. Mori, Y. H. J. Cryst. Growth 2001, 223, 206-212.
17. Katsuki, D.; Ohmura, R.; Ebinuma, T.; Narita, H. Philos. Mag. 2006, 86, 1753-1761.
18. Mochizuki, T.; Mori, Y. H. Clathrate Hydrate Film Growth along Water/Hydrate Former Phase Boundaries: Numerical Analyses of Mass and Heat Transfer to/from a Hydrate Film in Relation to Its Growth. 6th International Conference on Gas Hydrates, Vancouver, BC,July 6-10, 2008; p 5466.
19. Ohmura, R.; Kashiwazaki, S.; Mori, Y. H. J. Cryst. Growth 2000, 218, 372-380.
20. Kobayashi, I.; Ito, Y.; Mori, Y. H. Chem. Eng. Sci. 2001, 56, 4331-4338.
21. Sakaguchi, H.; Ohmura, R.; Mori, Y. H. J. Cryst. Growth 2003, 247, 631-641.
22. Staykova, D. K.; Kuhs, W. F.; Salamantin, A. N.; Hansen, T. J. Phys. Chem. B. 2003, 107, 10299-10311.
23. Moudrakovski, I. L.; McLaurin, G. E.; Ratcliffe, C. I.; Ripmeester, J. A. J. Phys. Chem. B. 2004, 108, 17591-17595.
24. Kuhs, W. F.; Staykova, D. K.; Salamatin, A. N. J. Phys. Chem. B. 2006, 110, 13283-13295.
25. Freer, E. M.; Selim, M. S.; Sloan, E. D. Fluid Phase Equilib. 2001, 185, 65-75.
26. Mochizuki, T.; Mori, Y. H. J. Cryst. Growth 2006, 290, 642-652.
27. Henning, R. W.; Schultz, A. J.; Thieu, V.; Halpern, Y. J. Phys. Chem. A. 2000, 104, 5066-5077.
28. Wang, X.; Schultz, A. J.; Halpern, Y. Kinetics of Ice Particle Conversion to Methane Hydrate 4th International Conference on Gas Hydrates, Yokahama, Japan,May 19-23, 2002; pp 455-460.
29. Topham, D. R. Chem. Eng. Sci. 1984, 39, 821-828.
30. Shindo, Y.; Fujioka, Y.; Takeuchi, K. Int. J. Chem. Kinet. 1995, 27, 569-575.
31. Mochizuki, T.; Mori, Y. H. Ann. N.Y. Acad. Sci. 2000, 912, 642-650.
32. Mori, Y. H.; Mochizuki, T. Modeling of Mass Transport across a Hydrate Layer Intervening between Liquid Water and "Guest" Fluid Phases. Proceedings of the 2nd International Conference on Gas Hydrates, Toulouse, France,June 2-6, 1996; pp 267-274.
33. Mori, Y. H.; Mochizuki, T. Chem. Eng. Sci. 1997, 52, 3613-3616.
34. Sugaya, M.; Mori, Y. H. Chem. Eng. Sci. 1996, 51, 3505-3517.
35. Satoh, K.; Uchida, T.; Mae, S. Diffusion Coefficient and Gas Solubility Measurements of Noble Gases in Ice Crystals. Proceedings of the NIPR Symposium on Polar Meteorology and Glaciology, Tokyo, Japan,September 9-10, 1996; Vol.10, pp 73-81.
36. Ikeda, T.; Fukazawa, H.; Mae, S.; Pepin, L.; Duval, P.; Champagnon, B.; Lipenkov, V. Y.; Hondoh, T. Geophys. Res. Lett. 1999, 26, 91-94.
37. Komai, T.; Kang, S. P.; Yoon, J. H.; Yamamoto, Y.; Kawamura, T. J. Phys. Chem. B. 2004, 108, 8062-8068.
38. Uchida, T.; Takeya, S.; Wilson, L. D.; Tulk, C. A.; Ripmeester, J. A.; Nagao, J.; Ebinuma, T.; Narita, H. Can. J. Phys. 2003, 81, 351-357.
39. Hori, A.; Hondoh, T. Can. J. Phys. 2003, 81, 251-259.
40. Goto, K.; Hondoh, T.; Higashi, A. Jpn. J. Appl. Phys. 1986, 25, 351-357.
41. Livingston, F. E.; Whipple, G. C.; George, S. M. J. Chem. Phys. 1998, 108, 2197-2207.
42. Livingston, F. E.; Smith, J. A.; George, S. M. J. Phys. Chem. A 2002, 106, 6309-6318.
43. Oxley, S. P.; Zahn, C. M.; Pursell, C. J. J. Phys. Chem. A 2006, 110, 11064-11073.
44. Ikeda-Fukazawa, T.; Horikawa, S.; Hondoh, T. J. Chem. Phys. 2002, 117, 3886-3896.
45. Borg, R. J.; Dienes, G. J. An Introduction To Solid State Diffusion; Academic Press: Boston, 1988.
46. Salamantin, A. N.; Hondoh, T.; Uchida, T.; Lipenkov, V. Y. J. Cryst. Growth 1998, 193, 197-218.
47. Demurov, A.; Radhakrishnan, R.; Trout, B. L. J. Chem. Phys. 2002, 116, 702-707.
48. Peters, B.; Zimmermann, N. E. R.; Beckham, G. T.; Tester, J. W.; Trout, B. L. J. Am. Chem. Soc. 2008, 130, 17342-17350.
49. Stern, L. A.; Kirby, S. H.; Circone, S.; Durham, W. B. Am. Mineral. 2004, 89, 1162-1175.
50. Stern, L.; Circone, S.; Kirby, S.; Durham, W. SEM Imaging of Gas Hydrate Formation Processes and Growth Textures, and Comparison to Natural Hydrates of Marine and Permafrost Origin. 5th International Conference on Gas Hydrates, Trondheim, Norway,June 13-16, 2005; p 1046.
51. Hirata, A.; Mori, Y. H. Chem. Eng. Sci. 1998, 53, 2641-2643.
52. Kuhs, W. F.; Genov, G.; Goreshnik, E.; Zeller, A.; Techmer, S.; Bohrmann, G. Int. J. Offshore Polar Eng. 2004, 14, 305-309.
53. Menzel, M. I.; Han, S. I.; Stapf, S.; Blümich, B. J. Magn. Reson. 2000, 143, 376-381.
54. Lu, W.; Chou, I. M.; Burruss, R. C. Geochim. Cosmochim. Acta 2008, 72, 412-422.
55. Lu, W. J.; Chou, I. M.; Burruss, R. C.; Yang, M. Z. Appl. Spectrosc. 2006, 60, 122-129.
56. Bermejo, D.; Escribano, R.; Orza, J. M. J. Mol. Spectrosc. 1977, 65, 345-353.
57. Hachikubo, A.; Ozeki, T.; Kosaka, T.; Sakagami, H.; Minami, H.; Nunokawa, Y.; Takahashi, N.; Shoji, H.; Kida, M.; Krylov, A. Isotopic Fractionation of Guest Gas at the Formation of Methane and Ethane Hydrates. 6th International Conference on Gas Hydrates, Vancouver, BC,July 6-10, 2008; p 5351.
58. Livingston, F. E.; Whipple, G. C.; George, S. M. J. Phys. Chem. B 1997, 101, 6127-6131.
59. Daschbach, J. L.; Schenter, G. K.; Ayotte, P.; Smith, R. S.; Kay, B. D. Phys. Rev. Lett. 2004, 92, 198306.
60. Davidson, D. W.; Leaist, D. G.; Hesse, R. Geochim. Cosmochim. Acta 1983, 47, 2293-2295.
61. Maekawa, T.; Imai, N. Ann. N.Y. Acad. Sci. 2000, 912, 452-459.
62. Maekawa, T. Geochem. J. 2004, 38, 129-138.
63. Kuhn, W.; Thürkauf, M. Helv. Chim. Acta 1958, 41, 938-971.
64. Bartels, D. M.; Han, P.; Percival, P. W. Chem. Phys. 1992, 164, 421-437.
65. Buchanan, P.; Soper, A. K.; Thompson, H.; Westacott, R. E.; Creek, J. L.; Hobson, G.; Koh, C. A. J. Chem. Phys. 2005, 123, 164507.
66. Gompertz, G.; Orville-Thomas, W. J. J. Phys. Chem. 1959, 63, 1331-1332.