Rationalisation and optimisation of solid state electro-reduction of SiO2 to Si in molten CaCl2 in accordance with dynamic three-phase interlines based voltammetry

Journal of Electroanalytical Chemistry

Volumn 639, Issue 1-2, 2010, Pages 130-140

  Xiao, Wei ^a   Jin, Xianbo ^a   Deng, Yuan ^a   Wang, Dihua ^a   Chen, George Z ^a,b  

^a WUHAN UNIVERSITY   (China)

^b UNIVERSITY OF NOTTINGHAM   (United Kingdom)

Author keywords

Cyclic voltammetry; Electro reduction; Molten salts; Silica; Silicon; Three phase interlines

Indexed keywords

ALGEBRA; CALCIUM; CALCIUM CHLORIDE; ELECTRIC INSULATORS; ELECTROCHEMICAL ELECTRODES; FUSED SALTS; OXIDE MINERALS; OXYGEN; PELLETIZING; POROUS SILICON; QUARTZ; SILICA; SILICIDES; SILICON OXIDES; TUNGSTEN;

AG/AGCL; COMPOSITION ANALYSIS; CYCLIC VOLTAMMOGRAMS; ELECTRO REDUCTION; ELECTROLYTIC PROCESS; HIGH-PURITY SILICON; LOGARITHM LAW; MOLTEN SALT; MOLTEN SALTS; OPTIMISATIONS; OXYGEN CONTENT; POROUS SILICA; POROUS SILICON LAYERS; POTENTIAL RANGE; POTENTIAL WINDOWS; POTENTIOSTATIC ELECTROLYSIS; PURE SILICON; RATIONALISATION; REDUCTION CURRENT; REFERENCE ELECTRODES; SCAN RATES; THREE-PHASE INTERLINES; UNIQUE FEATURES; VOLTAMMETRIC;

CYCLIC VOLTAMMETRY;

EID: 75249097814     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jelechem.2009.12.001     Document Type: Article

References (37)

1. Zulehner W., Elvers B., Hawkin S., Russey W., and Schulz G. Ullmann's Encyclopedia of Industrial Chemistry. Fifth ed. vol. A23 (1995), VCH, Weinheim pp. 721-748
2. Nagamuri N., Malinsky I., and Claveau A. Metall. Trans. B 17 (1986) 503
3. Chen G.Z., Fray D.J., and Farthing T.W. Nature 407 (2000) 361
4. Nohira T., Yasuda K., and Ito Y. Nat. Mater. 2 (2003) 397
5. Jin X.B., Gao P., Wang D.H., Hu X.H., and Chen G.Z. Angew. Chem. Int. Ed. 43 (2004) 733
6. Yasuda K., Nohira T., and Ito Y. J. Phys. Chem. Solids. 66 (2005) 443
7. Yasuda K., Nohira T., Amezawa K., Ogata Y.H., and Ito Y. J. Electrochem. Soc. 152 (2005) D69
8. Yasuda K., Nohira T., Takahashi K., Hagiwara R., and Ogata Y.H. J. Electrochem. Soc. 152 (2005) D232
9. Deng Y., Wang D.H., Xiao W., Jin X.B., Hu X.H., and Chen G.Z. J. Phys. Chem. B 109 (2005) 14043
10. Gao P., Jin X.B., Wang D.H., Hu X.H., and Chen G.Z. J. Electroanal. Chem. 579 (2005) 321
11. Yasuda K., Nohira T., Ogata Y.H., and Ito Y. J. Electrochem. Soc. 152 (2005) D208
12. Wang S.L., Zhang H., and Zhang L.J. J. Northeaestern Univ. Nat. Sci. 28 (2007) 53 (in Chinese)
13. Assadi H. Model. Simulat. Mater. Sci. Eng. 14 (2006) 963
14. Pistorius P.C., and Fray D.J. JS Afr. Inst. Min. Metall. 106 (2006) 31
15. Xiao W., Jin X.B., Deng Y., Wang D.H., Hu X.H., and Chen G.Z. Chem. Phys. Chem. 7 (2006) 1750
16. Xiao W., Jin X.B., Deng Y., Wang D.H., and Chen G.Z. Chem. Eur. J. 13 (2007) 604
17. Yasuda K., Nohira T., Hagiwara R., and Ogata Y.H. J. Electrochem. Soc. 154 (2007) E95
18. Yasuda K., Nohira T., Hagiwara R., and Ogata Y.H. Electrochim. Acta 53 (2007) 106
19. Greener route to pure silicon, Chem. Eng. News 82 (2004) 24.
20. Chen G.Z., Gordo E., and Fray D.J. Metall. Mater. Trans. B 35 (2004) 223
21. Qiu G.H., Ma M., Wang D.H., Jin X.B., Hu X.H., and Chen G.Z. J. Electrochem. Soc. 152 (2005) E328
22. Qiu G.H., Jiang K., Ma M., Wang D.H., Jin X.B., and Chen G.Z. Z. Naturforsch. A 62 (2007) 292
23. Wu T., Jin X.B., Xiao W., Hu X.H., Wang D.H., and Chen G.Z. Chem. Mater. 19 (2007) 153
24. Dring K., Dashwood R., and Inman D. J. Electrochem. Soc. 152 (2005) E104
25. Bard A.J., Inzelt G., and Scholz F. Electrochemical Dictionary (2008), Springer-Verlag, Heidelberg pp. 532
26. Bourges G., Lambertin D., Rochefort S., Delpech S., and Picard G. J. Alloys Compd. 444-445 (2007) 404
27. Stohr U., and Freyland W. Phys. Chem. Chem. Phys. 1 (1999) 4383
28. Haarberg G.M., Thonstad J., Egan J.J., Oblakowski R., and Pietrzyk S. Ber. Bunsenges. Phys. Chem. 102 (1998) 1314
29. Haarberg G.M., Osen K.S., Heus R.J., and Egan J.J. J. Electrochem. Soc. 137 (1990) 2777
30. Conway B.E. Electrochemical Supercapacitors (1999), Kluwer Academic Plenum Publishers, New York
31. Jin X.B., Zhou W., Zhang S.W., and Chen G.Z. Small 3 (2007) 1513
32. Peng C., Snook G.A., Fray D.J., Shaffer M.S.P., and Chen G.Z. Chem. Commun. (2006) 4629
33. Scriba M.R., Arendse C., Harting M., and Britton D.T. Thin Solid Films 516 (2008) 844
34. http://www.tradeeasy.com/supplier/579283/products/p1024968/silicon-nanoparticles.html.
35. Yang J.Y., Lu S.G., Kan S.R., Zhang X.J., and Du J. Chem. Commun. (2009) 3273
36. Manfrinetti P., Fornasini M.L., and Palenzona A. Intermetallics 8 (2000) 223
37. Hao R.R., Fang X.Y., and Niu S.C. Inorganic Chemistry Series: The Group of Carbon (1998), Silicon and Germanium, Science Press, Beijing (in Chinese)