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The high surface sensitivity, which can be obtained at the third generation synchrotron radiation beamlines, originates from a number of experimental unique capabilities, such as the ability of selecting the photon energy in such a way that photoemitted electrons have the minimum escape depth kinetic energy, and using grazing angle emission. The possibility of distinguishing shifts as small as 20 meV rests, however, on the possibility of choosing core levels of relatively small intrinsic line width, such as the Ru and Pd 3d5/2 levels in the present work.
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