Kinetics and mechanisms of heterogeneous reaction of NO2 on CaCO3 surfaces under dry and wet conditions

Atmospheric Chemistry and Physics

Volumn 10, Issue 2, 2010, Pages 463-474

  Li, H J ^a   Zhu, T ^a   Zhao, D F ^a   Zhang, Z F ^a   Chen, Z M ^a  

^a PEKING UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CALCIUM CARBONATE; NITRATE; NITRITE; NITROGEN DIOXIDE; REACTION KINETICS; RELATIVE HUMIDITY; TROPOSPHERE;

EID: 74949087772     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-10-463-2010     Document Type: Article

References (46)

1. Al-Abadleh, H. A., Al-Hosney, H. A., and Grassian, V. H.: Oxide and carbonate surfaces as environmental interfaces: the importance of water in surface composition and surface reactivity, J. Mol. Catal. A-Chem., 228, 47-54, 2005.
2. Al-Hosney, H. A. and Grassian, V. H.: Carbonic acid: An important intermediate in the surface chemistry of calcium carbonate, J. Am. Chem. Soc., 126, 8068-8069, 2004.
3. 3 with alumina as a mineral dust model compound, J. Phys. Chem. A, 104, 5036-5045, 2000.
4. Carmichael, G. R., Zhang, Y., Chen, L. L., Hong, M. S., and Ueda, H.: Seasonal variation of aerosol composition at Cheju Island, Korea, Atmos. Environ., 30, 2407-2416, 1996.
5. Chen, L. Q.: Long range atmospheric transport of China desert aerosol to north Pacific Ocean, Acta Oceanol. Sin., 7, 554-560, 1985.
6. de Leeuw, N. H. and Parker, S. C.: Surface structure and morphology of calcium carbonate polymorphs calcite, aragonite, and va-terite: an atomistic approach, J. Phys. Chem. B, 102, 2914-2922, 1998.
7. Dentener, F. J., Carmichael, G. R., Zhang, Y., Lelieveld, J., and Crutzen, P. J.: Role of mineral aerosol as a reactive surface in the global troposphere, J. Geophys. Res.-Atmos., 101, 22869-22889, 1996.
8. 3(0001) surface, J. Phys. Chem. B, 102, 7008-7015, 1998.
9. 3 (0001) surface, Science, 288, 1029-1033, 2000.
10. Fenter, F. F., Caloz, F., and Rossi, M. J.: Experimental-Evidence for the Efficient Dry Deposition of Nitric-Acid on Calcite, Atmos. Environ., 29, 3365-3372, 1995.
11. 2 in laboratory systems and in outdoor and indoor atmospheres: An integrated mechanism, Phys. Chem. Chem. Phys., 5, 223-242, 2003.
12. Goodman, A. L.: A spectroscopic study of heterogeneous reactions of nitrogen oxides and sulfur oxides on solid particles of atmospheric relevance, Chemistry Department, The University of Iowa, Iowa, 276, 2000.
13. 3(a) on Hydrated Silica Particles, J. Phys. Chem. A, 103, 7217-7223, 1999.
14. Goodman, A. L., Underwood, G. M., and Grassian, V. H.: A laboratory study of the heterogeneous reaction of nitric acid on calcium carbonate particles, J. Geophys. Res.-Atmos., 105, 29053-29064, 2000.
15. 3, and atmospheric dust samples: A Knudsen cell study, J. Phys. Chem. A, 105, 3096-3106, 2001.
16. Hass, K. C., Schneider, W. F., Curioni, A., and Andreoni, W.: The chemistry of water on alumina surfaces: Reaction dynamics from first principles, Science, 282, 265-268, 1998.
17. 3(0001), J. Phys. Chem. B, 104, 5527-5540, 2000.
18. Jenkin, M. E., Cox, R. A., and Williams, D. J.: Laboratory Studies of the kinetics of formation of nitrous-acid from the thermal-reaction of nitrogen-dioxide and water-vapor, Atmos. Environ., 22, 487-498, 1988.
19. 3) Particles: A Knudsen Cell Study Using Multiple, Single, and Fractional Particle Layers, J. Phys. Chem. A, 109, 6901-6911, 2005.
20. Jonas, P. R., Charlson, R. J., Rodhe, H., Anderson, T. L., Andreae, M. O., Dutton, E., Graf, H., Fouquart, Y., Grassl, H., Heintzen-berg, J., Hobbs, P. V., Hofmann, D., Hubert, B., et al.: Aerosols, in Climate Change 1994: Radiative Forcing of Climate Change, edited by: Houghton, J. T., Meira Filho, L. G., Bruce, J., Lee, H., Callander, B. A., Haites, E., Harris, N., and Maskell, K., Cambridge University Press, Cambridge, UK, 127-162, 1995.
21. 3(1014), Langmuir, 21, 8793-8801, 2005.
22. Krueger, B. J., Grassian, V. H., Iedema, M. J., Cowin, J. P., and Laskin, A.: Probing heterogeneous chemistry of individual atmospheric particles using scanning electron microscopy and energy-dispersive X-ray analysis, Anal. Chem., 75, 5170-5179, 2003a.
23. Krueger, B. J., Grassian, V. H., Laskin, A., and Cowin, J. P.: The transformation of solid atmospheric particles into liquid droplets through heterogeneous chemistry: Laboratory insights into the processing of calcium containing mineral dust aerosol in the troposphere, Geophys. Res. Lett., 30, 1148, doi:10.1029/2002GL016563, 2003b.
24. Kuriyavar, S. I., Vetrivel, R., Hegde, S. G., Ramaswamy, A. V., Chakrabarty, D., and Mahapatra, S.: Insights into the formation of hydroxyl ions in calcium carbonate: temperature dependent FTIR and molecular modelling studies, J. Mater. Chem., 10, 1835-1840, 2000.
25. Lee, Y. N. and Schwartz, S. E.: Reaction kinetics of nitrogen dioxide with liquid water at low partial pressure, J. Phys. Chem., 85, 840-848, 1981.
26. 2 on the surface of NaCl particles, Sci. China Ser. B, 49, 371-378, 2006.
27. 3 over a Wide Range of Humidity, J. Phys. Chem. A, 112, 1561-1571, 2008a.
28. 3 particles by micro-Raman spectrometry, At-mos. Chem. Phys., 8, 7205-7215, 2008, http://www.atmos-chem- phys.net/8/7205/2008/.
29. 3(10(1)over-bar4) surface-water interface, Surf. Sci., 373, 288-299, 1997.
30. Nakamoto, K.: Infrared and Raman Spectra of Inorganic and Coordination Compounds Part A, New York, John Wiley & Sons, 1997.
31. Okada, K., Qin, Y., and Kai, K.: Elemental composition and mixing properties of atmospheric mineral particles collected in Hohhot, China, Atmos. Res., 73, 45-67, 2005.
32. Quan, H.: Discussion of the transport route of dust storm and loess aerosol from Northwest China at the high altitude, Environ. Sci., 14, 60-65, 1993.
33. Song, C. H. and Carmichael, G. R.: Gas-particle partitioning of nitric acid modulated by alkaline aerosol, J. Atmos. Chem., 40, 1-22, 2001.
34. Song, C. H., Maxwell-Meier, K., Weber, R. J., Kapustin, V., and Clarke, A.: Dust composition and mixing state inferred from airborne composition measurements during ACE-Asia C130 Flight #6, Atmos. Environ., 39, 359-369, 2005.
35. Stipp, S. L. S., Gutmannsbauer, W., and Lehmann, T.: The dynamic nature of calcite surfaces in air, Am. Mineral., 81, 1-8, 1996.
36. Stipp, S. L. S.: Toward a conceptual model of the calcite surface: Hydration, hydrolysis, and surface potential, Geochim. Cosmochim. Ac., 63, 3121-3131, 1999.
37. Stumm, W.: Chemistry of the solid-water interface: processes at the mineral-water and particle-water interface in natural systems, New York, John Wiley & Sons, 1992.
38. Sullivan, R. C., Guazzotti, S. A., Sodeman, D. A., and Prather, K. A.: Direct observations of the atmospheric processing of Asian mineral dust, Atmos. Chem. Phys., 7, 1213-1236, 2007, http://www.atmos-chem-phys.net/7/1213/2007/.
39. Svensson, R., Ljungstrom, E., and Lindqvist, O.: Kinetics of the Reaction between Nitrogen Dioxide and Water Vapor, Atmos. Environ., 21, 1529-1539, 1987. (Pubitemid 18308225)
40. Thompson, D. W. and Pownall, P. G.: Surface Electrical-Properties of Calcite, J. Colloid Interf. Sci., 131, 74-82, 1989.
41. 2 on mineral dust, Atmos. Chem. Phys., 3, 2043-2051, 2003, http://www.atmos-chem-phys.net/3/2043/2003/.
42. Underwood, G. M., Li, P., Usher, C. R., and Grassian, V. H.: Determining accurate kinetic parameters of potentially important heterogeneous atmospheric reactions on solid particle surfaces with a Knudsen cell reactor, J. Phys. Chem. A, 104, 819-829, 2000.
43. Underwood, G. M., Miller, T. M., and Grassian, V. H.: Transmission FT-IR and Knudsen Cell Study of the Heterogeneous Reactivity of Gaseous Nitrogen Dioxide on Mineral Oxide Particles, J. Phys. Chem. A, 103, 6184-6190, 1999.
44. Vlasenko, A., Sjogren, S., Weingartner, E., Stemmler, K., Gäggeler, H. W., and Ammann, M.: Effect of humidity on nitric acid uptake to mineral dust aerosol particles, Atmos. Chem. Phys., 6, 2147-2160, 2006, http://www.atmos- chem-phys.net/6/2147/2006/.
45. Zhang, D. Z., Shi, G. Y., Iwasaka, Y., and Hu, M.: Mixture of sul-fate and nitrate in coastal atmosphere aerosol:individual particle studies in Qingdao, China, Atmos. Environ., 374, 2669-2679, 2000.
46. Zhuang, H., Chan, C. K., Fang, M., and Wexler, A. S.: Formation of nitrate and non-sea-salt sulfate on coarse particles, Atmos. Environ., 33, 4223-4233, 1999.