Rhenium-rich molybdenite and rheniite in the Pagoni Rachi Mo-Cu-Te-Ag-Au prospect, northern Greece: Implications for the re geochemistry of porphyry-style Cu-Mo and Mo mineralization

Canadian Mineralogist

Volumn 47, Issue 5, 2009, Pages 1013-1036

  Voudouris, Panagiotis C ^a   Melfos, Vasilios ^b   Spry, Paul G ^c   Bindi, Luca ^d   Kartal, Tamara ^e   Arikas, Kyriakos ^e   Moritz, Robert ^f   Ortelli, Meussa ^f  

^a UNIVERSITY OF ATHENS   (Greece)

^b ARISTOTLE UNIVERSITY OF THESSALONIKI   (Greece)

^c IOWA STATE UNIVERSITY   (United States)

^d UNIVERSITY OF FLORENCE   (Italy)

^e UNIVERSITY OF HAMBURG   (Germany)

^f UNIVERSITY OF GENEVA   (Switzerland)

Author keywords

Greece; Pagoni Rachi; Phase separation; Polytype; Porphyry epithermal deposit; Re rich molybdenite; Rheniite; Sublimates; Tellurides

Indexed keywords

CHLORINE ACTIVITY; DURING PHASE; EPITHERMAL DEPOSITS; EPITHERMAL SYSTEMS; FLUID INCLUSION; HIGH-CONTENT; HYDROTHERMAL SOLUTION; KURILE ISLANDS; MO CONTENT; NORTHERN GREECE; OLIGOCENE; OXIDIZING CONDITIONS; POLYTYPES; QUARTZ VEIN; SCANNING ELECTRON MICROSCOPE; STRUCTURAL STUDIES; UNIT-CELL VALUES; VAPOR PHASIS;

ANALYTICAL GEOCHEMISTRY; CHLORINE; DEPOSITS; DISSOLUTION; GOLD DEPOSITS; IRON ORES; LEAD; METAL RECOVERY; MINERALOGY; ORE DEPOSIT GEOLOGY; OXIDE MINERALS; PHASE MODULATION; PHASE SEPARATION; QUARTZ; RHENIUM; SCANNING ELECTRON MICROSCOPY; SILICATE MINERALS; SILVER; SILVER ALLOYS; SODIUM CHLORIDE; STRUCTURAL ANALYSIS; TELLURIUM COMPOUNDS; TIN; VAPORS;

MOLYBDENUM;

DIKE; EPITHERMAL DEPOSIT; GEOCHEMISTRY; HOMOGENEITY; MINERAL DEPOSIT; MINERALIZATION; MOLYBDENITE; OLIGOCENE; POLYTYPISM; PORPHYRY; PRECIPITATION (CHEMISTRY); QUARTZ VEIN; RHENIUM; SUBLIMATE; TELLURIDE;

GREECE; KURIL ISLANDS; RUSSIAN FEDERATION; SAKHALIN;

EID: 74049104862     PISSN: 00084476     EISSN: None     Source Type: Journal    
DOI: 10.3749/canmin.47.5.1013     Document Type: Article

References (145)

1. AFIFI, A. M., KELLY, W. C. & ESSENE, E. J. (1988) : Phase relations among tellurides, sulfides and oxides. I. Thermochemical data and calculated equilibria. Econ. Geol. 83, 377-394.
2. AFRICANO, F, VAN ROMPAEY, G., BERNARD, A. & LEGUERN, F. (2002) : Deposition of trace elements from high temperature gases of Satsuma-Iwajima volcano. Earth Planet. Space 54, 275-286.
3. ARANCIBIA, O. N. & CLARK, A. H. (1996) : Early magnetite-amphibole-plagioclase alteration-mineralization in the Island Copper porphyry copper-gold-molybdenum deposit, British Columbia. Econ. Geol. 91, 402-438.
4. ARIKAS, K. (1979) : A porphyry Mo-Cu occurrence near Kirki (western Thrace, Greece). Neues Jahrb. Mineral., Abh. 137, 74-82.
5. ARIKAS, K. (1981) : Subvulkanisch-hydrothermale Mo-Cu-Pb-Zn-Vererzungen, S. E. Rhodope, Nord Griechenland: Petrographie und Geochemie. TSCHERMAKS MINERAL. PETROGR. MITT. 28, 189-205.
6. ARIKAS, K. (1991) : The porphyry Mo occurrence at Panoni Rachi (NE Kirki) and the mineralogy of hydrothermally altered subvolcanic rocks at Kirki-Esymi area. Bull. Geol. Soc. Greece 25, 259-274 (in Greek).
7. ARIKAS, K. & VOUDOURIS, P. (1998) : Hydrothermal alterations and mineralizations of magmatic rocks in the southern Rhodope Massif. Acta Volcanol. 10, 353-365.
8. ARUTYUNYAN, L. A. & KHURSHUDYAN, E. K. (1966) : Synthesis of molybdenum disulfide from sulfomolybdenate solutions at high temperatures. Geochem. Int. 3, 479-485.
9. BADALOV, S. T., KHURSHUDYAN, E. K. & TURESEKOV, A. (1971) : Polytypes of molybdenites from the Dal'nee molybdenum-copper-gold deposit. Dokl. Akad. Nauk SSSR 28, 41-42 (in Russ.).
10. BARKOV, A. Y. & LEDNEV, A. I. (1993) : A rhenium-molybenum-copper sulfide from the Lukkulaisvarra layered intrusion, northern Karelia, Russia. Eur. J. Mineral. 6, 1227-1233.
11. BARR, S. R., TEMPERLEY, S. & TARNEY, J. (1999) : Lateral crustal growth of the continental crust through deep level subduction-accretion: a re-evaluation of central Greek Rhodope. Lithos 46, 69-94.
12. BECKER, H. (2000) : Re-Os fractionation in eclogites and blueschists and the implications for recycling of oceanic crust into the mantle. Earth Planet. Sci. Lett. 177, 287-300.
13. 2) in volcanic fumaroles from the Usu volcano, Hokkaido, Japan. Proc. XIth Int. Cong, on Electron Microscopy, (Kyoto), 1691-1693.
14. BERNARD, A., SYMONDS, R. B. & ROSE, W. I. (1990) : Volatile transport and deposition of Mo, W and Re in high temperature magmatic fluids. Appl. Geo Chem. 5, 317-326.
15. BERZINA, A. N., SOTNIKOV, V. I., ECONOMOU- ELIOPOULOS, M. and ELIOPOULOS, D. G. (2005) : Distribution of rhenium in molybdenite from porphyry Cu-Mo and Mo-Cu deposits of Russia (Siberia) and Mongolia. Ore Geol. Rev. 26, 91-113.
16. 2O-NaCl solutions. Geochim. Cosmochim. Acta 57, 683-684.
17. BODNAR, R. J. (1995) : Fluid-inclusion evidence for a magmatic source of metals in porphyry copper deposits. In Magmas, Fluids and Ore Deposits (J. F. H. Thompson, ed.). Mineral. Assoc. Can., Short Course 23, 139-152.
18. BODNAR, R. J. (2003) : Introduction to fluid inclusions. In Fluid Inclusions: Analysis and Interpretation (I. M. Samson, A. J. Anderson & D. D. Marshall, eds.). Mineral. Assoc. Can., Short Course 32, 1-8.
19. BOGDANOV, K. & POPOV, K. (2003) : Cu-Au epithermal systems in the southern part of the Panaguiriste ore region, Bulgaria. Soc. Econ. Geol., Guidebook Ser. 36, 91-114.
20. BORODAEV, YU. S., GARAVELLI, A., GARBARINO, C, GRILLO, S. M., MOZGOVA, N. N., ORGANOVA, N. I., TRUBKIN, N. V. and VURRO, F. (2000) : Rare sulfosalts from Vulcano, Aeolian Islands, Italy. III. Wittite and cannizzarite. Can. Mineral. 38, 23-34.
21. BROWN, P. E. (1989) : FLINCOR: a microcomputer program for the reduction and investigation of fluid inclusion data. Am. Mineral. 74, 1390-1393.
22. 2 + NaCl: new graphical presentations and implications for fluid inclusion studies. Geochim. Cosmochim. Acta 53, 1209-1221.
23. BRUN, J. P. & SOKOTUIS, D. (2007) : Kinematics of the Southern Rhodope core complex (north Greece). Int. J. Earth Sci. 96, 1079-1099.
24. 4, a new mineral from Kudriavy volcano, Iturup Island, Kurile Islands. Zap. Vses. Mineral. Obshchest. 133 (4), 21-27 (in Russ.).
25. 4, a new mineral species from Kudriavy volcano, Iturup Island, Kurile arc. Can. Mineral. 43, 695-701.
26. CHAPLYGIN, I. V., MOZGOVA, N. N., MOKHOV, A. V., KOPORU-UNA, E. V., BERNHART, H.-J. & BRYZGALOV, I. A. (2007) : Minerals of the system ZnS-CdS from fumaroles of the Kudriavy volcano, Iturup Island, Kurily Islands, Russia. Can. Mineral. 45, 709-722.
27. 55, 397-409.
28. CHRISTOFIDES, G., SOLDATOS, T., ELEFTHERIADIS, G. & KORONEOS, A. (1998) : Chemical and isotopic evidence for source contamination and crustal assimilation in the Hellenic Rhodope plutonic rocks. Acta Volcanol. 10, 305-318.
29. CHUKHROV, F. V., ZVYAGIN, B. B., YERMILOVA, L. P., SOBOLEVA, S. V. & KHITROV, V. G. (1968) : Polytypes of molybdenite and their occurrences in ores. Int. Geol. Rev. 12, 74-86.
30. CIOBANU, C. L., COOK, N. J., DAMIAN, G. & DAMIAN, F. (2004) : Telluride and sulfosalt associations at Sǎcǎrîmb. In Au-Ag-Telluride Deposits of the Golden Quadrilateral, Apuseni Mts., Romania (N. J. Cook & C. L. Ciobanu, eds.). IAGOD Guidebook Ser. 12, 145-186.
31. CLARK, A. H. (1970) : Compositional differences between hexagonal and rhombohedral molybdenite. Neues Jahrb. Mineral., Monatsh., 33-38.
32. CLINE, J. S. & BODNAR, R. J. (1994) : Direct evolution of brine from a crystallizing silicic melt at the Questa, New Mexico, molybdenum deposit. Econ. Geol. 89, 1780-1802.
33. COOK, N. J. & CIOBANU, C. L. (2004) : Bismuth tellurides and sulfosalts from the Larga hydrothermal system, Metaliferi Mts, Romania: paragenesis and genetic significance. Mineral. Mag. 68, 301-321.
34. COOK, N. J., CIOBANU, C. L., DAMIAN, G. & DAMIAN, F. (2004) : Tellurides and sulfosalts from deposits in the Golden Quadrilateral. In Au-Ag-Telluride Deposits of the Golden Quadrilateral, Apuseni Mts., Romania (N. J. Cook & C. L. Ciobanu, eds.). IAGOD Guidebook Ser. 12, 111-144.
35. COOKE, D. R. & MCPHAIL, D. C. (2001) : Epithermal Au-Ag-Te mineralization, Acupan, Baguio District, Philippines: numerical simulations of mineral deposition. Econ. Geol. 96, 109-131.
36. CORBETT, G. J. & LEACH, T. M. (1998) : Southwest Pacific Rim gold-copper systems: structure, alteration and mineralization. Soc. Econ. Geol., Spec. Publ. 6.
37. DE BOORDER, H., SPAKMAN, W., WHITE, S. H. & WORTEL, M. J. R. (1998) : Late Cenozoic mineralization, orogenic collapse and slab detachment in the European Alpine Belt. Earth Planet. Sci. Lett. 164, 569-575.
38. DEL MORO, A., INNOCENTI, F., KYRIAKOPOULOS, C, MANETTI, P. & PAPADOPOULOS, P. (1988) : Tertiary granitoids from Thrace (northern Greece) : Sr isotopic and petrochemical data. Neues Jahrb. Mineral., Abh. 159, 113-135.
39. DILLES, J. H. & EINAUDI, M. T. (1992) : Wall-rock alteration and hydrothermal flow paths about the Ann-Mason porphyry copper deposit, Nevada: a 6-km vertical reconstruction. ECON. GEOL. 87, 1963-2001.
40. DINTER, D. A. & ROYDEN, L. (1993) : Late Cenozoic extension in northeastern Greece: Strymon Valley detachment system and Rhodope metamorphic core complex. GEOLOGY 21, 45-48.
41. EKSTRǑM, M. & HȦlenius, U. (1982) : A new rhenium-rich sulfide from two Swedish localities. Neues Jahrb. Mineral., Monatsh., 6-10.
42. FILIMONOVA, L. E., ZHUKOV, N. M. & MALYAVKA, A. G. (1984) : Genetic aspects of polytype and rhenium content of molybdenites of the copper porphyry deposits. Geokhimiya 7, 1040-1046 (in Russian with English abstract).
43. FILIPPPIDIS, A., VAVELIDIS, M., MLCHAILIDIS, K. & EVANGELOU, E. (1986) : Re-rich and Re-poor molybdenite in the Melitena porphyritic intrusion, Rhodope massif. Fortschr. Mineral. 64, 47 (abstr.).
44. FLEISCHER, M. (1959) : The geochemistry of rhenium, with special reference to its occurrence in molybdenite. Econ. Geol. 54, 1406-1413.
45. FYTIKAS, M., INNOCENTI, F., MANNETI, P., PECCERILLO, A., MAZZUOLI, R. & VILLARI, L. (1984) : Tertiary to Quaternary evolution of volcanism in the Aegean region. In The Geological Evolution of the Eastern Mediterranean (J. E. Dixon & A. H. F. Robertson, eds.). Geol. Soc, Spec. Pap. 17, 687-699.
46. th Int. Geol. Congress, Sect. 10, 145-152.
47. GOLDSTEIN, R. (2003) : Petrographic analysis of fluid inclusions. In Fluid Inclusions: Analysis and Interpretation (I. M. Samson, A. J. Anderson & D. D. Marshall, eds.). Mineral. Assoc. Can., Short Course 32, 9-53.
48. GOLDSTEIN, R. H. & REYNOLDS, T. J. (1994) : Systematics of fluid inclusions in diagenetic minerals. Soc. Econ. Paleontol. Mineral., Short Course 31.
49. GUSTAFSON, L. B. & HUNT, J. P. (1975) : The porphyry copper deposit at El Salvador, Chile. Econ. Geol. 70, 857-912.
50. HAAS, J. L. (1971) : The effect of salinity on the maximum thermal gradient of a hydrothermal system at hydrostatic pressure. Econ. Geol. 66, 940-946.
51. HANNAH, J. L., STEIN, H. J., WIESER, M. E., DE LAETER, J. R. and VARNER, M. D. (2007) : Molybdenum isotope variations in molybdenite: vapor transport and Rayleigh fractionation of Mo. Geology 35, 703-706.
52. HEDENQUIST, J. W., ARRIBAS, A. R. & GONZALEZ-URIEN, E. (2000) : Exploration for epithermal gold deposits. In Gold 2000 (S. G. Hagemann & P. E. Brown, eds.). Rev. Econ. Geol. 13, 245-277.
53. HEINRICH, C. A. & NEUBAUER, F. (2002) : Cu-Au-Pb-Zn-Ag metallogeny of the Alpine - Balkan - Carpathian - Dinaride geodynamic province. Mineral. Deposita 37, 533-540.
54. IBERS, J. A. & HAMILTON, W. C., eds. (1974) : International Tables for X-ray Crystallography IV. The Kynoch Press, Dordrecht, The Netherlands.
55. INNOCENTI, F., KOLIOS, N., MANETTI, O., MAZZUOU, R., PECCERILLO, G., RITA, F. & VILLARI, L. (1984) : Evolution and geodynamic significance of the Tertiary orogenic volcanism in northeastern Greece. Bull. Vulcanol. 47, 25-37.
56. JENSEN, E. P. & BARTON, M. D. (2000) : Gold deposits related to alkaline magmatism. In Gold 2000 (S. G. Hagemann & P. E. Brown, eds.). Rev. Econ. Geol. 13, 279-314.
57. JONES, C. E., TARNEY, J., BAKER, J. H. & GEROUKI, F. (1992) : Tertiary granitoids of Rhodope, northern Greece: magmatism related to extensional collapse of the Helenic Orogen? Tectonophysics 210, 295-314.
58. 8, a new mineral species from the Hitura mine, Nivala, Finland. Can. Mineral. 42, 539-544.
59. KORZHINSKY, M. A., TKACHENKO, S. I., BULGAKOV, R. F. and SHMULOVICH, K. I. (1996) : Condensate compositions and native metals in sublimates of high-temperature gas streams of Kudryavy volcano, Iturup Island, Kuril Islands. Geochem. Int. 34, 1057-1064.
60. KORZHINSKY, M. A., TKACHENKO, S. I., SHMULOVICH, K. I., TARAN, Y. A. & STEINBERG, G. S. (1994) : Discovery of a pure rhenium mineral at Kudriavy volcano. Nature 369, 51-52.
61. KOUZMANOV, K., BOGDANOV, K. & RAMBOZ, C. (2005) : Teand Bi-bearing assemblages in the Elshitsa and Radka epithermal deposits, central Srednogorie, Bulgaria: mineralogy and genetical features. In Au-Ag-Te-Se Deposits (N. J. Cook & I. K. Bonev, eds.). Geochem. Mineral. Petrol. (Sofia) 43, 108-112.
62. KOVALENKER, V. A., LAPUTINA, I. P. & VYAL'SOV, L. N. (1974) : Rhenium-rich molybdenite from the Talnakh coppernickel deposit, Norilsk region. Dokl. Acad. Sci. USSR, Earth Sci. Sect. 217, 104-106.
63. KROHE, A. & MPOSKOS, E. (2002) : Multiple generations of extensional detachments in the Rhodope Mountains (northern Greece) : evidence of episodic exhumation of high-pressure rocks. In The Timing and Location of Major Ore Deposits in an Evolving Orogen (D. J. Blundell, F. Neubauer & A. Von Quadt, eds.). Geol. Soc, Spec. Publ. 204, 151-178.
64. LAROCQUE, A. C. L., STIMAC, J. A., SIEBE, C, GREENGRASS, K., CHAPMAN, R. & MEJIA, S. R. (2008) : Deposition of a highsulfidation Au assemblage from a magmatic volatile phase, Volcan Popocatépetl, Mexico. J. Volcanol. Geotherm. Res. 170, 51-60.
65. MAGGANAS, A. C. (2002) : Constraints on the petrogenesis of Evros ophiolite extrusives, NE Greece. Lithos 65, 165-182.
66. MAO JINGWEN, ZHANG ZHAOCHONG, ZHANG ZUOHENG & DU ANDAO (1999) : Re-Os isotopic dating of molybdenites in the Xiaoliugou W (Mo) deposit in the northern Qilian Mountains and its geological significance. Geochim. Cosmochim. Acta 63, 1815-1818.
67. MARCHEV, P. (2007) : Magmatic influence on the zonation of the Paleogene epithermal mineralization in the centraleastern Rhodopes, Bulgaria and Greece. In Digging Deeper (C. J. Andrew et al., eds.). Balkema, Rotterdam, The Netherlands (857-860).
68. MARCHEV, P., ARAI, S. & VASELU, O. (2006) : Cumulate xenoliths in Oligocene alkaline basaltic and lamprophyric dikes from the eastern Rhodopes, Bulgaria: evidence for the existence of layered plutons under the metamorphic core complexes. In Post-collisional Tectonics and Magmatism in the Mediterranean Region and Asia (Y. Dilek & S. Pavlides, eds.). Geol. Soc. Am., Spec. Pap. 409, 237-258.
69. MARCHEV, P., KAISER-ROHRMEIER, M., HEINRICH, C, OVTCHA-ROVA, M., VON QUADT, A. & RAICHEVA, R. (2005) : Hydrothermal ore deposits related to post-orogenic extensional magmatism and core complex formation: the Rhodope Massif of Bulgaria and Greece. Ore Geol. Rev. 27, 53-89.
70. MARCHEV, P., RAICHEVA, R., DOWNES, H., VASELU, O., CHI-ARADIA, M. & MORITZ, R. (2004) : Compositional diversity of Eocene-Oligocene basaltic magmatism in the Eastern Rhodopes, SE Bulgaria: implications for genesis and tectonic setting. Tectonophysics 393, 301-328.
71. MARCHEV, P., ROGERS, G., CONREY, R., QUICK, J., VASELLI, O. and RAICHEVA, R. (1998) : Paleogene orogenic and alkaline basic magmas in the Rhodope zone: relationships, nature of magma sources, and role of crustal contamination. Acta Vulcanol. 10, 217-232.
72. MCCANDLESS, T. E., RUIZ, J. & CAMPBELL, A. R. (1993) : Rhenium behavior in molybdenite in hypogene and nearsurface environments: implications for Re-Os geochronometry. Geochim. Cosmochim. Acta 57, 889-905.
73. MELFOS, V., VAVELIDIS, M. & BOGDANOV, K. (2003) : Occurrence, mineralogy and chemical composition of primary gold from Tertiary ore mineralisations in the Rhodope massif (Greece-Bulgaria). In Mineral Exploration and Sustainable Development (D. G. Eliopoulos et al., eds.). Millpress, Rotterdam, The Netherlands (1201-1204).
74. MELFOS, V., VAVELIDIS, M., CHRISTOFIDES, G. & SEIDEL, E. (2002) : Origin and evolution of the Tertiary Maronia porphyry copper-molybdenum deposit, Thrace, Greece. Mineral. Deposita 37, 648-668.
75. MELFOS, V., VAVELIDIS, M., FILIPPIDIS, A., Christofides, G. and EVANGELOU, E. (1991) : Re-rich and Re-poor molybdenite in the Maronia rhyolitic intrusion, northeastern Greece. In Source, Transport and Deposition of Metals (M. Pagel & J. L. Leroy, eds.), Balkema, Rotterdam, The Netherlands (775-777).
76. MELFOS, V, VOUDOURIS, P., ARIKAS, K. & VAVELIDIS, M. (2001) : High Re concentrations in molybdenites from porphyry-Mo±Cu in Thrace (NE Greece). Bull. Geol. Soc. Greece 34, 1015-1022 (in Greek).
77. MICHAEL, C. (2004) : Epithermal systems and gold mineralization in western Thrace (north Greece). Bull. Geol. Soc. Greece 36, 416-423.
78. MICHAEL, C, CONSTANTINIDES, D., ASHWORTH, K., PERDI-KATSIS, V. & DEMETRIADES, A. (1989) : The Kirki vein polymetallic mineralization, NE Greece. Geol. Rhodop. 1, 366-373.
79. MITCHELL, R. H., LAFLAMME, J. H. & CVABRI, L. J. (1989) : Rhenium sulfide from the Coldwell Complex, northwestern Ontario. Mineral. Mag. 53, 635-637.
80. MUNTEAN, J. L. & EINAUDI, M. T. (2001) : Porphyry-epithermal transition: Maricunga belt, northern Chile. Econ. Geol. 96, 743-772.
81. NESBITT, R. W., BILLET, M. F., ASHWORTH, K. L., DENIEL, C, CONSTANTINIDES, D., DEMETRIADES, A., KATIRTZOGLOU, G, MICHAEL, C, MPOSKOS, E., ZACHOS, S. & SANDERSON, D. (1988) : The geological setting of base metal mineralization in the Rhodope region, northern Greece. In Mineral Deposits within the European Community (J. Boissonnas and P. Omenetto, eds.). Springer, Berlin, Germany (499-514).
82. NEUBAUER, F. (2002) : Contrasting Late Cretaceous with Neogene ore provinces in the Alpine-Balkan-Carpathian-Dinaride collision belt. In The Timing and Location of Major Ore Deposits in an Evolving Orogen (D. J. Blundell, F. Neubauer & A. von Quadt, eds.). Geol. Soc, Spec. Publ. 204, 81-102.
83. NEWBERRY, R. J. J. (1979a) : Polytypism in molybdenite. I. A non-equilibrium, impurity-induced phenomenon. Am. Mineral. 64, 758-767.
84. NEWBERRY, R. J. J. (1979b) : Polytypism in molybdenite. II. Relationships between polytypism, ore deposition/alteration stages and rhenium contents. Am. Mineral. 64, 768-775.
85. OXFORD DIFFRACTION (2006) : CRYSALIS RED (Version 1.171.31.2) and ABSPACK in CRYSALIS RED. Oxford Diffraction Ltd, Abingdon, Oxfordshire, U. K.
86. PAPADOPOULOS, P. (1982) : Geological map of Greece, Maronia sheet, scale 1:50, 000. Inst. Geol. Mineral Exploration, Athens, Greece.
87. PECSKAY, Z., ELEFTHERIADIS, G., KORONEOS, A., SOLDATOS, T. & CHRISTOFIDES, G. (2003) : K/Ar dating, geochemistry and evolution of the Tertiary volcanic rocks (Thrace, northeastern Greece). In Mineral Exploration and Sustainable Development (D. G. Eliopoulos et al., eds.). Millpress, Rotterdam, The Netherlands (1229-1232).
88. PELTONEN, P., PAKKANEN, L. & JOHANSON, B. (1995) : Re-Mo-Cu-Os sulphide from the Ekojoki Ni-Cu deposit, SW Finland. Mineral. Petrol. 52, 257-264.
89. th Int. Symp. Eastern Mediterranean Geology (Thessaloniki) 3, 1208-1211.
90. PE-PIPER, G., CHRISTOFIDES, G. & ELEFTHERIADIS, G. (1998) : Lead and neodymium isotopic composition of Tertiary igneous rocks of northeastern Greece and their regional significance. Acta Vulcanol. 10, 255-263.
91. PE-PIPER, G. & PIPER, D. J. W. (2002) : The Igneous Rocks of Greece. The anatomy of an orogen. Gebr. Borntraeger, Berlin, Germany.
92. PE-PIPER, G. & PIPER, D. J. W. (2006) : Unique features of the Cenozoic igneous rocks of Greece. IN Postcollisional Tectonics and Magmatism in the Mediterranean Region and Asia (Y. Dilek & S. Pavlides, eds.). Geol. Soc. Am., Spec. Pap. 409, 259-282.
93. PE-PIPER, G., PIPER, D. J. W., KOUKOUVELAS, I., DOLANSKY, L. M. & KOKKALAS, S. (2009) : Postorogenic shoshonitic rocks and their origin by melting underplated basalts: the Miocene of Limnos, Greece. Geol. Soc. Am., Bull. 121, 39-54.
94. PERUGINI, D., POLI, G., CHRISTOFIDES, G., ELEFTHERIADIS, G., KORONEOS, A. & SOLDATOS, T. (2004) : Mantle-derived and crustal melts dichotomy in northern Greece: spatiotemporal and geodynamic implications. GEOL. J. 39, 63-80.
95. PLOTINSKAYA, O. Yu., KOVALENKER, V. A., SELTMANN, R. and STANLEY, C. J. (2006) : Te and Se mineralogy of the highsulfidation Kochbulak and Kairagach epithermal gold telluride deposits (Kurama Ridge, Middle Tien Shan, Uzbekistan). Mineral. Petrol. 87, 187-207.
96. REMPEL, K. U., MIGDISOV, A. A. & WILLIAMS-JONES, A. E. (2006) : The solubility and speciation of molybdenum in water vapour at elevated temperatures and pressures: implications for ore genesis. Geochim. Cosmochim. Acta 70, 687-696.
97. REMPEL, K. U., WILLIAMS-JONES, A. E. & MIGDISOV, A. A. (2008) : The solubility of molybdenum dioxide and trioxide in HCl-bearing water vapour at 350°C and pressures up to 160 bars. Geochim. Cosmochim. Acta 72, 3074-3083.
98. RICE, C. M., HARMON, R. S. & SHEPHERD, T. J. (1985) : Central City, Colorado: the upper part of an alkaline porphyry molybdenum system. Econ. Geol. 80, 1769-1796.
99. RICHARDS, J. P. (2009) : Postsubduction porphyry Cu-Au and epithermal Au deposits: products of remelting of subduction-modified lithosphere. Geology 37, 247-250.
100. RICOU, J.-L., BURG, J.-P., GOLFIAUX, I. & IVANOV, Z. (1998) : Rhodope and Vardar: the metamorphic and the olistostromic paired belts related to the Creataceous subduction under Europe. Geodin. Acta 11, 285-309.
101. ROEDDER, E. (1984) : Fluid Inclusions. Rev. Mineral. 12.
102. 2. Acta Crystallogr. B39, 404-407.
103. SEEDORFF, E., DILLES, J. H., PROFFETT, J. M., JR., EINAUDI, M. T., ZÜRCHER, L., STAVAST, W. J. A., JOHNSON, D. A. and BARTON, M. D. (2005) : Porphyry deposits: characteristics and origin of hypogene features. Econ. Geol., 100th Anniv. Vol., 251-298.
104. SHANNON, R. D. (1981) : Bond distances in sulfides and a preliminary table of sulfide crystal radii. In Structure and Bonding in Crystals 2 (M. O'Keeffe & A. Navrotsky, eds.). Academic Press, New York, N. Y. (53-70)
105. SHELDRICK, CM. (1997) : SHELXL-97. A Program for Crystal Structure Refinement. University of Göttingen, Göttingen, Germany.
106. SHEPHERD, T., RANKIN, A. & ALDERTON, D. H. M. (1985,) : A Practical Guide to Fluid lnclusion Studies. Blackie, Glasgow, U. K.
107. SIDERIS, C (1973) : Petrochemistry of some volcanic rocks from West Thrace. Tectonic and petrochemical relationships with volcanics of Greece. Chem. Erde 32, 174-195.
108. SILLITOE, R. H. (2000) : Gold-rich porphyry deposits: descriptive and genetic models and their role in exploration and discovery. Rev. Econ. Geol. 13, 315-345.
109. SKARPELIS, N. (1999) : The Agios Filippos ore deposit, Kirki (western Thrace). A base-metal part of a high-sulfidation epithermal system. Bull. Geol. Soc. Greece 33, 51-60.
110. SKARPEUS, N., VOUDOURIS, P. & ARIKAS, K. (1999) : Exploration for epithermal gold in SW Thrace, Greece: new target areas. In Mineral Deposits: Processes to Processing (C. J. Stanley et al., eds.). Balkema, Rotterdam, the Netherlands (589-592).
111. SOKOUTIS, D., BRUN, J. P., VAN DEN DRIESSCHE, J. & PAVUDES, S. (1993) : A major Oligo-Miocene detachment in southern Rhodope controlling north Aegean extension. J. Geol. Soc. London 150, 243-246.
112. SOMINA, M. Y. (1966) : Trigonal molybdenite from East Siberian carbonatites. Dokl. Akad. Nauk SSSR 167, 96-99 (in Russ.).
113. 22O-NaCl at elevated temperatures and pressures. Am. J. Sci. 260, 115-141.
114. SPRY, P. C, FOSTER, F, TRUCKLE, J. S. & CHADWICK, T. H. (1997) : The mineralogy of the Golden Sunlight gold-silver telluride deposit, Whitehall, Montana, U. S. A. Mineral. Petrol. 59, 143-164.
115. STEIN, H. J. (1985) : A Lead, Strontium, and Sulfur Isotope Study of Laramide-Tertiary Intrusions and Mineralization in the Colorado Mineral Belt with Emphasis on Climax-Type Porphyry Molybdenum Systems plus a Summary of Other Newly Acquired Isotopic and Rare Earth Element Data. Ph. D. thesis, Univ. of North Carolina, Chapel Hill, N. C.
116. STEIN, H. J. (2006) : Low-rhenium molybdenite by metamorphism in northern Sweden: recognition, genesis, and global implications. Lithos 87, 300-327.
117. STEIN, H. J., MARKEY, R. J., MORGAN, J. W., HANNAH, J. L. and SCHERSTEN, A. (2001) : The remarkable Re-Os chronometer in molybdenite: how and why it works. Terra Nova 13, 479-486.
118. 187Os and assessment of laser ablation ICP-MS spot dating in molybdenite. Geochim. Cosmochim. Acta 67, 3673-3686.
119. SUN, W., ARCULUS, R. J., BENNETT, V. C, EGGINS, S. M. and BINNS, R. A. (2003) : Evidence for rhenium enrichment in the mantle wedge from submarine arc-like volcanic glasses (Papua New Guinea). GEOLOGY 31, 845-848.
120. SYMONDS, R. B., ROSE, W. I., REED, M. H., LICHTE, F. E. and FINNEGAN, D. L. (1987) : Volatilization, transport and sublimation of metallic and non-metallic elements in high temperature gases at Merapi volcano, Indonesia. Geochim. Cosmochim. Acta 51 2083-2101.
121. TARAN, Y. A., HEDENQUIST, J. W., KORZHINSKY, M. A., TKACHENKO, S. I. & SHMULOVICH, K. I. (1995) : Geochemistry of magmatic gases from Kudryavy volcano, Iturup, Kuril Islands. Geochim. Cosmochim. Acta 59, 1749-1761.
122. 8. Eur. J. Mineral. 3, 977-982.
123. TERADA, K., OSAKI, S., ISHIHARA, S. & KIBA. T. (1971) : Distribution of rhenium in molybdenites from Japan. Geochem. J. 4, 123-141.
124. TESSAUNA, S. G., CAPMAS, F, BIRCK, J.-L., ALLÈGRE, C.-J., YUDOVSKAYA, M. A., DISTLER, V. V. & CHAPLYGIN, I. V. (2005) : Sources of rhenium and osmium enrichment in fumaroles, sulphide sublimates and volcanic rocks from the Kudriavy volcano. In Mineral Deposit Research: Meeting the Global Challenge (Mao Jingwen & F. P. Bierlein, eds.). Proc. Eighth Biennial SGA Conf. (Beijing), 841-843.
125. TESSALLNA, S. G., YUDOVSKAYA, M. A., CHAPLYGIN, I. V., BIRCK, J.-L. & CAPMAS, F. (2008) : Sources of unique rhenium enrichment in fumaroles and sulphides at Kudryavy volcano. Geochim. Cosmochim. Acta 72, 889-909.
126. TODOROV, T. & STAIKOV, M. (1985) : Rhenium content in molybdenite from ore mineralizations in Bulgaria. Geol. Balcanica 15, 45-58.
127. VAN HINSGERGEN, D. J. J., HAFKENSCHEID, E., SPAKMAN, W., MEULENKAMP, J. E. & WORTEL, R. (2005) : Nappe stacking resulting from subduction of oceanic and continental lithosphere below Greece. Geology 33, 325-328.
128. VAVELIDIS, M., FILIPPIDIS, A., MICHAILIDIS, K. & EVANGELOU, E. (1989) : The polymetallic ore mineralization of the Kirki area, Alexandroupolis district, northeastern Greece. GEOL. RHODOP. 1, 350-365.
129. VOLBORTH, A. & HOUSLEY, R. M. (1984) : A preliminary description of complex graphite, sulfide, arsenide, and platinum group element mineralization in a pegmatoid pyroxenite of the Stillwater Complex, Montana, U. S. A. Tschermaks Mineral. Petrogr. Mitt. 33, 213-230.
130. VOLBORTH, A., TARKIAN, M., STUMPFL, E. F. & HOUSLEY, R. M. (1986) : A survey of the Pd-Pt mineralization along the 35-km strike of the J-M Reef, Stillwater Complex, Montana. Can. Mineral. 24, 329-346.
131. VON BRAUN, E. (1993) : The Rhodope question, viewed from eastern Greece. Z. Deutsch. Geol. Gesellsch. 144, 406-418.
132. VON QUADT, A., MORITZ, R., PEYTCHEVA, I. & HEINRICH, C. A. (2005) : Geochronology and geodynamics of Late Creataceous magmatism and Cu-Au mineralization in the Panagyurishte region of the Apuseni-Banat-Timok-Srednogorie belt, Bulgaria. Ore Geol. Rev. 27, 95-126.
133. VOUDOURIS, P. (2006) : A comparative mineralogical study of Te-rich magmatic-hydrothermal systems in northeastern Greece. Mineral. Petrol. 87, 241-275.
134. VOUDOURIS, P. & ARIKAS, K. (2003) : The Pagoni Rachi and Kassiteres porphyry Cu-(±Mo) occurences in Thrace: ore mineralogy of late-stage veins. In Mineral Exploration and Sustainable Development (D. G. Eliopoulos et al., eds.). Millpress, Rotterdam, The Netherlands (411-414).
135. VOUDOURIS, P. & MELFOS, V. (2006) : Bismuth sulfosalts and silver tellurides in the Pagoni Rachi porphyry Cu-Mo prospect, western Thrace (N. E. Greece). In Au-Ag-Telluride-Selenide Deposits (N. G. Cook, I. Özgenc & T. Oyman, eds.). Int. Geol. Correlation Program 486, Field Workshop, Proc, 159-166.
136. VOUDOURIS, P., TARKIAN, M. & ARIKAS, K. (2006) : Mineralogy of telluride-bearing epithermal ores in Kassiteres-Sappes area, western Thrace, Greece. Mineral. Petrol. 87, 31-52.
137. WATANABE, M. & SOEDA, A. (1981) : Distribution of polytype contents of molybdenites from Japan and possible controlling factor in polytypism. Neues Jahrb. Mineral., Abh. 141, 258-279.
138. 2 and the dominant oxidation state of rhenium in hydrothermal solutions. Chem. Geol. 158, 245-256.
139. 2 buffer assemblage and transport of rhenium under supercritical conditions. Geochem. Trans. 3, 1-10.
140. YANEV, Y. (2003) : Mantle sources of the Paleogene collisionrelated magmas of the eastern Rhodopes (Bulgaria) and western Thrace (Greece) : characteristics of the mafic magmatic rocks. Neues Jahrb. Mineral., Abh. 178, 131-151.
141. YANEV, Y, INNOCENTI, F., MANETTI, P. & SERRI, G. (1998) : Upper Eocene-Oligocene collision-related volcanism in Eastern Rhodopes (Bulgaria) - western Thrace (Greece) : petrogenetic affinity and geodynamic significance. Acta Vulcanol. 10, 279-291.
142. YUDOVSKAYA, M. A., DISTLER, V. V., CHAPLYGIN, I. V., MOK-HOV, A. V., TRUBKIN, N. V. & GORBACHEVA, S. A. (2006) : Gaseous transport and deposition of gold in magmatic fluid: evidence from the active Kudryavy volcano, Kurile Islands. Mineral. Deposita 40, 828-848.
143. ZAGORCHEV, I. S. (1998) : Pre-Priabonian Palaeogene formations in southwestern Bulgaria and northern Greece: stratigraphy and tectonic implications. Geol. Mag. 135, 101-119.
144. ZIMMERMAN, A., STEIN, H. J., HANNAH, J. L., KOŽEU, D., BOG-DANOV, K. & BERZA, T. (2008) : Tectonic configuration of the Apuseni-Banat-Timrok-Srednogorie belt, Balkans - South Carpathians, constrained by high precision Re-Os molybdenite ages. Mineral. Deposita 43, 1-21.
145. 2, the natural rhenium disulfide from fumaroles of Kudryavy volcano, Iturup Island, Kurile Islands. Zap. Vses. Mineral. Obshchest. 134 (5), 32-40 (in Russ.).