The solubility of molybdenum dioxide and trioxide in HCl-bearing water vapour at 350 °C and pressures up to 160 bars

Geochimica et Cosmochimica Acta

Volumn 72, Issue 13, 2008, Pages 3074-3083

  Rempel, K U ^a   Williams Jones, A E ^a   Migdisov, A A ^a  

^a MCGILL UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

HYDRATION; MOLYBDENUM; PORPHYRY; SOLUBILITY; SPECIATION (CHEMISTRY); WATER VAPOR;

EID: 44949174804     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2008.04.015     Document Type: Article

References (56)

1. Alvarez J., Corti H.R., Fernández-Prini R., and Japas M.L. Distribution of solutes between coexisting steam and water. Geochim. Cosmochim. Acta 58 (1994) 2789-2798
2. Anderson G.M., and Crerar D.A. Thermodynamics in Geochemistry: The Equilibrium Model (1993), Oxford University Press, New York
3. Archibald S.M., Migdisov A.A., and Williams-Jones A.E. The stability of Au-chloride complexes in water vapor at elevated temperatures and pressures. Geochim. Cosmochim. Acta 65 (2001) 4413-4423
4. Archibald S.M., Migdisov A.A., and Williams-Jones A.E. An experimental study of the stability of copper chloride complexes in water vapor at elevated temperatures and pressures. Geochim. Cosmochim. Acta 66 (2002) 1611-1619
5. nd edition. (1993), VCH, New York
6. Belton G.R., and Jordan A.S. The volatilization of molybdenum in the presence of water vapor. J. Phys. Chem. 69 (1965) 2065-2071
7. Booker J. L. and Fredrickson R. E. (1969). Vaporizing hydrogen chloride from hydrous molybdenum oxychloride without loss of molybdenum oxide. Patent, Dow Chemical Co.
8. 3. J. Catalysis 10 (1968) 188-199
9. - ions with large coordination number. Chem. Phys. Lett. 24 (1974) 520-523
10. Candela P.A., and Holland H.D. The partitioning of copper and molybdenum between melts and aqueous fluids. Geochim. Cosmochim. Acta 48 (1984) 373-380
11. Cannon P. The solubility of molybdenum trioxide in various mineral acids. J. Inorg. Nucl. Chem. 11 (1959) 124-127
12. Cao, X. (1989). Solubility of molybdenite and the transport of molybdenum in hydrothermal solutions. Ph.D. thesis, Iowa State University.
13. Carpenter R.H. Geology and ore deposits of the Questa molybdenum mine area, Taos county, New Mexico. In: Ridge J.D. (Ed). Ore Deposits of the United States, 1933-1967 (1968), The American Institute of Mining, Metallugical and Petroleum Engineers, Inc., New York
14. Chase M. W. (1998) NIST-JANAF thermochemical tables, 4th edition, J. Phys. Chem. Ref. Data, Monograph 9.
15. Chernikov C.C., and Tarakanov B.M. Chemical transport of molybdenum trioxide by hydrogen chloride studies by IR and UV spectroscopy. Z. Neorg. Khimii 18 (1973) 44-46
16. Cline J.S., and Bodnar R.J. Direct evolution of brine from a crystallizing silicic melt at the Questa, New Mexico, molybdenum deposit. Econ. Geol. 89 (1994) 1780-1802
17. Dennis Jr. J.E., and Woods D.J. In: Wouk A. (Ed). New Computing Environments: Microcomputers in Large-Scale Computing (1987), SIAM 116-122
18. Glemser O., and Haeseler R. Gaseous hydroxides, IV: gaseous hydroxides of molybdenum and tungsten. Z. Anorg. Allgem. Chem. 316 (1962) 168-181
19. Glemser O., Stöcker U., and Wendlandt H.G. Reaction of solid oxides with high density water at high temperatures. Ber. Bunsen Phys. Chem. 70 (1966) 1129-1134 in German
20. Gu, Y. (1993) Theoretical and experimental studies of the hydrothermal geochemistry of molybdenum. Ph.D. thesis, Monash University.
21. Henley R.W., and McNabb A. Magmatic vapor plumes and ground-water interaction in porphyry copper emplacement. Econ. Geol. 73 (1978) 1-19
22. Hofer T.S., Randolf B.R., and Rode B.M. Sr(III) in water: a labile hydrate with a highly mobile structure. J. Phys. Chem. 110 (2006) 20409-20417
23. Hultgren N. and Brewer L. (1956) Gaseous molybdenum oxychloride. Radiation Laboratory Report, U.C. Berkeley, 60, 947-949.
24. Kestin J., Sengers J.V., Kamgar-Parsi B., and Levelt Sengers J.M.H. Thermophysical properties of fluid water. J. Phys. Chem. Ref. Data 13 (1984) 175-183
25. 2O-HF. Contrib. Mineral. Petrol. 109 (1991) 139-150
26. Linnen R.L., and Williams-Jones A.E. Evolution of aqueous-carbonic fluids during contact metamorphism, wall-rock alteration, and molybdenite deposition at Trout Lake, British Columbia. Econ. Geol. 85 (1990) 1840-1856
27. Migdisov A.A., Williams-Jones A.E., and Suleimenov O.M. Solubility of chlorargyrite (AgCl) in water vapor at elevated temperatures and pressures. Geochim. Cosmochim. Acta 63 (1999) 3817-3827
28. Migdisov A.A., and Williams-Jones A.E. An experimental study of cassiterite solubility in HCl-bearing water vapor. Chem. Geol. 217 (2005) 29-40
29. Nelder J.A., and Mead R. A simplex method for function minimization. Comput. J. 7 (1965) 308-313
30. Pankratz L. B. (1982) Thermodynamic Properties of Elements and Oxides. United States Bureau of Mines, Bulletin 672, Washington, DC.
31. Pankratz L. B. (1984) Thermodynamic Properties of Halides. United States Bureau of Mines, Bulletin 674, Washington, DC.
32. Pearson R.G. Hard and soft acids and bases. Phys. Inorg. Chem. 85 (1963) 3533-3539
33. Priest R.C. Gaseous precision etching of molybdenum. U.S. Govt. Res. Dev. Rep. 67 (1966) 98
34. Priest R. C. (1970) Gaseous etching of molybdenum with oxygen-hydrogen chloride mixtures. Patent, Stanford Research Institute.
35. Rempel K.U., Migdisov A.A., and Williams-Jones A.E. The solubility of molybdenum in water vapour at elevated temperatures and pressures: implications for ore genesis. Geochim. Cosmochim. Acta 70 (2006) 687-696
36. Robie R. A., Bethke P. M., Toulmin M. S. and Edwards J. L. (1966) X-ray crystallography data, densities, and molar volumes of minerals. In Handbook of Physical Constants revised edition (ed. S. P. Clark). Geological Society of America, Memoir 97, New York, pp. 437-458.
37. Sandler S.I. Chemical and Engineering Thermodynamics (1989), John Wiley and Sons, New York
38. Selby D., Nesbitt B.E., Muehlenbachs K., and Prochaska W. Hydrothermal alteration and fluid chemistry of the Endako porphyry molybdenum deposit, British Columbia. Econ. Geol. 95 (2000) 183-202
39. Simon A.C., Pettke T., Candela P.A., Piccoli P.M., and Heinrich C.A. Gold partitioning in melt-vapor-brine systems. Geochim. Cosmochim. Acta 69 (2005) 3321-3335
40. Simon A.C., Pettke T., Candela P.A., Piccoli P.M., and Heinrich C. Copper partitioning in sulfur bearing magmatic systems. Geochim. Cosmochim. Acta 70 (2006) 5583-5600
41. Simonson J.M., and Palmer D.A. Liquid-vapor partitioning of HCl(aq) to 350 °C. Geochim. Cosmochim. Acta 57 (1993) 1-8
42. Smith R. W. (1983) Aqueous chemistry of molybdenum at elevated temperatures and pressures with application to porphyry molybdenum deposits. Ph.D. thesis, New Mexico Institute of Mining and Technology.
43. Stryjek R., and Vera J.H. PRSV: an improved Peng-Robinson equation of state for pure compounds and mixtures. Can. J. Chem. Eng. 64 (1986) 323-333
44. Symonds R.B., Rose W.I., Reed M.H., Lichte F.E., and Finnegan D.L. Volatilization, transport, and sublimation of metallic and non-metallic elements in high temperature gases at Merapi Volcano, Indonesia. Geochim. Cosmochim. Acta 51 (1987) 2083-2101
45. Symonds R.B., Reed M.H., and Rose W.I. Origin, speciation, and fluxes of trace-element gases at Augustine volcano, Alaska: insights into magma degassing and fumarolic processes. Geochim. Cosmochim. Acta 56 (1992) 633-657
46. Symonds R. B., Rose W. I., Bluth G. J. S. and Gerlach T. M. (1994) Volcanic-gas studies: methods, results and applications. In Volatiles in Magmas (eds. M. R. Carroll and J. R. Holloway), Reviews in Mineralogy 30, Mineralogical Society of America, Washington, DC. pp. 1-60.
47. Taylor J.R. An Introduction to Error Analysis: The Study of Uncertainties in Physical Measurements (1982), University Science Books, Sausalito
48. Wallace S.R., Muncaster N.K., Jonson D.C., MacKenzie W.B., Bookstrom A.A., and Surface V.E. Multiple intrusions and mineralization at Climax, Colorado. In: Ridge J.D. (Ed). Ore Deposits of the United States, 1933-1967 (1968), The American Institute of Mining, Metallurgical, and Petroleum Engineers, New York 605-640
49. Wallace S.R., MacKenzie W.B., Blair R.G., and Muncaster N.K. Geology of the Urad and Henderson molybdenite deposits, Clear Creek County, Colorado, with a section on comparison of these deposits with those at Climax, Colorado. Econ. Geol. 73 (1978) 325-368
50. Wiebke J., Moritz A., Cao X., and Dolg M. Approaching actinide(+III) hydration from first principles. Phys. Chem. Chem. Phys. 9 (2007) 459-465
51. Williams-Jones A.E., and Heinrich C.A. Vapor transport of metals and the formation of magmatic-hydrothermal ore deposits. Econ. Geol. 100 (2005) 1287-1312
52. Williams-Jones A. E., Migdisov A. A., Archibald S. M. and Xiao Z. (2002) Vapor-transport of Ore Metals. Water-rock Interactions, Ore Deposits, and Environmental Geochemistry: A Tribute to David A. Crerar (eds. R. Hellmann and S. A. Wood). The Geochemical Society, Special Publication No. 7, Washington, DC, pp. 279-305.
53. 2 solutions from 200° to 350 °C. Econ. Geol. 82 (1987) 1864-1887
54. Yokoi K., Maysubayashi N., Miyanaga T., Watanabe I., Ikeda S., and Murata K. Studies on the structure of the paramagnetic u-oxo dimer of molybdenum(V) in hydrochloric acid solutions by EXAFS. Polyhedron 8 (1988) 45-49
55. Yokoi K., Matsubayashi N., Miyanaga T., Watanabe I., and Ikeda S. Studies on the structure of molybdenum(VI) in acidic solution by XANES and EXAFS. Polyhedron 12 (1993) 911-914
56. Zezin D.Y., Migdisov A.A., and Williams-Jones A.E. The solubility of gold in hydrogen sulfide gas: an experimental study. Geochim. Cosmochim. Acta 71 (2007) 3070-3081