Stereoselective synthesis of highly substituted annulated dihydropyrans based onγ-lithiation and homoaldol reaction of an enantiopure α-silylated vinyl carbamate

Synthesis

Volumn , Issue 2, 2010, Pages 329-342

  Hémery, Thérése ^a   Wibbeling, Birgit ^a   Fröhlich, Roland ^a   Hoppe, Dieter ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Aldehyde addition; Annulated dihydropyrans; Chiral allyl carbamates; Diastereo selective lithiation; Vinyl carbamates

Indexed keywords

BORON TRIFLUORIDE; CHIRAL ALLYL CARBAMATES; DESILYLATION; DIETHYL ETHERS; ENANTIOPURE; FIVE-MEMBERED RINGS; HOMOALDOL REACTIONS; LITHIATION; PRINS REACTION; STEREOSELECTIVE SYNTHESIS; TITLE COMPOUNDS; TRIMETHYLSILYL; VINYL CARBAMATES;

ALDEHYDES; BORON; BORON COMPOUNDS; ETHERS; SYNTHESIS (CHEMICAL);

STEREOSELECTIVITY;

[1 (TRIMETHYLSILYL)VINYL]CARBAMATE; ALDEHYDE DERIVATIVE; BORON TRIFLUORIDE; BUTYLLITHIUM; CARBAMIC ACID DERIVATIVE; DIHYDROPYRAN; DIISOPROPYLCARBAMATE; ETHER; LITHIUM DERIVATIVE; MYRTENOL; PYRAN DERIVATIVE; TERPENE DERIVATIVE; UNCLASSIFIED DRUG;

ADDITION REACTION; ALDOL REACTION; ANNULATION REACTION; ARTICLE; CHEMICAL MODIFICATION; CONTROLLED STUDY; DESILYLATION; ENANTIOSELECTIVITY; LITHIATION; SILYLATION; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS; TITANATION;

EID: 73949109924     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0029-1218596     Document Type: Article

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