Thermochromism of a poly(phenylene vinylene): Untangling the roles of polymer aggregate and chain conformation

Journal of Physical Chemistry B

Volumn 113, Issue 50, 2009, Pages 16110-16117

  Wang, Chun Chih ^a   Gao, Yuan ^a   Shreve, Andrew P ^a   Zhong, Chang ^a   Wang, Leeyih ^b   Mudalige, Kumara ^c   Wang, Hsing Lin ^a   Cotlet, Mircea ^c  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

^b Engineering National Taiwan University   (Taiwan)

^c BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; CHROMOPHORES; EMISSION SPECTROSCOPY; PHOTOLUMINESCENCE SPECTROSCOPY; TOLUENE;

ABSORPTION AND EMISSION SPECTRA; CHAIN CONFORMATIONS; DICHLOROBENZENES; DILUTED SOLUTIONS; DISORDERED REGIONS; EMISSION SPECTRUMS; HIGH TEMPERATURE; INTERCHAIN INTERACTIONS; LOW ENERGIES; LOW-TEMPERATURE STATE; PHENYLENEVINYLENE; PHYSICAL DIMENSIONS; PICOSECOND TIME; POLYMER AGGREGATES; POLYMER CHAINS; SINGLE POLYMER CHAINS; SPECTROSCOPIC BEHAVIOR; THERMOCHROMIC BEHAVIOR; THERMOCHROMISM; VISIBLE RANGE;

AGGREGATES;

EID: 73449125488     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp906645d     Document Type: Article

References (32)

1. Song, J.; Cisar, J. S.; Bertozzi, C. R. Functional self-assembling bolaamphiphilic polydiacetylenes as colorimetric sensor scaffolds. J. Am. Chem. Soc 2004, 126, 8459-8465.
2. Leclerc, M. Optical and electrochemical transducers based on functionalized conjugated polymers. Adv. Mater. 1999, 11, 1491-1498 (Pubitemid 30519080)
3. Yoshino, K.; Park, D. H.; Park, B. K.; Fujii, M.; Sugimoto, R. Anomalous temperature dependence of electrical conductivity in polythiophene derivatives substituted with long alkyl chain. Jpn. J. Appl. Phys., Part 2 1988, 27, L1410-13.
4. Chen, S. A.; Ni, J. M. Structure/properties of conjugated conductive polymers. 1. Neutral poly(3-alkylthiphene)s. Macromolecules 1992, 25, 6081-6089.
5. DiCesare, N.; Belletete, M.; Durocher, G.; Leclerc, M. Towards a theoretical design of thermochromic polythiophenes. Chem. Phys. Lett. 1997, 275, 533-539 (Pubitemid 127162870)
6. Yang, C.; Orfino, F. P.; Holdcroft, S. Phenomenological model for predicting thermochromism of regioregular and nonregioregular poly(3-alkylthiophenes). Macromolecules 1996, 29, 6510-6517. (Pubitemid 126536621)
7. Tashiro, K.; Ono, K.; Minagawa, Y.; Kobayashi, M.; Kawai, T.; Yoshino, K. Structure and thermochromic solid-state phase transition of poly(3-alkylthiophene). J. Polym. Sci., Part B: Polym. Phys. 1991, 29, 1223-1233 (Pubitemid 21736492)
8. Dufour, B.; Rannou, P.; Djurado, D.; Zagorska, A.; Kulszewicz, B.; Pron, A. The role of chain and dopant engineering in the preparation of processible conducting polymers with desired properties. Synth. Met. 2003, 135/136, 63-68 (Pubitemid 41055512)
9. Rannou, P.; Dufour, B.; Travers, J. P.; Pron, A.; Djurado, D.; Janeczek, H.; Sek, D. Temperature-induced transitions in doped polyaniline: Correlation between glass transition, thermochromism and electrical transport. J. Phys. Chem. B 2002, 106, 10553-10559. (Pubitemid 35410252)
10. Rannou, P.; Dufour, B.; Travers, J. P.; Pron, A.; Djurado, D.; Janeczek, H.; Sek, D. Temperature-induced transitions in doped polyaniline: correlation between glass transition, thermochromism and electrical transport. J. Phys. Chem. B 2002, 106, 10553-10559 (Pubitemid 35410252)
11. Masters, J. G.; Ginder, J. M.; Macdiarmid, A. G.; Epstein, A. J. Thermochromism in the insulating forms of polyaniline: role of ringtorsional conformation. J. Chem. Phys. 1992, 96, 4768-4778
12. Hoofman, R. J. O. M.; Gelinck, G. H.; Siebbeles, L. D. A.; de Haas, M. P.; Warman, J. M.; Bloor, D. Influence of backbone conformation on the photoconductivity of polydiacetylene chains. Macromolecules 2000, 33, 9289-9297. (Pubitemid 32089775)
13. Rumbles, G.; Samuel, I. D. W.; Collison, C. J.; Miller, P. F.; Moratti, S. C; Holmes, A. B. Temperature dependent photoluminescence from a cyano-substituted phenylene vinylene polymer. Synth Met. 1999, 101, 158-161
14. Chen, S. A.; Chang, E. C. Structure and properties of cyanosubstituted poly(2,5-dialkoxy-p-phenylene vinylene)s. Macromolecules 1998, 31, 4899-4907.
15. Gelinck, G. H.; Warman, J. M.; Staring, E. G. J. Polaron pair formation, migration, and decay on photoexcited poly(phenylenevinylene) chains. J. Phys. Chem. 1996, 100, 5485-5491.
16. Leger, J. M.; Holt, A. L.; Carter, S. A. Reversible thermochromic effects in poly(phenylene vinylene)-based polymers. Appl. Phys. Lett. 2006, 88, 111901.
17. Lebouch, N.; Garreau, S.; Louarn, G.; Belletete, M.; Durocher, G.; Leclerc, M. Structural study of the thermochromic transition in poly(2,5-dialkyl-p-phenyleneethynylene)s. Macromolecules 2005, 38, 9631-9637.
18. Dei, S.; Matsumoto, A.; Matsumoto, A. Thermochromism of polydiacetylenes in the solid state and in solution by the self-organization of polymer chains containing no polar group. Macromolecules 2008, 41, 2467-2473. (Pubitemid 351569206)
19. Yan, M.; Rothberg, L. J.; Papadimitrakopoulos, F.; Galvin, M. E.; Miller, T. M. Defect quenching of conjugated polymer luminescence. Phys. Rev. Lett. 1994, 73, 744-747
20. Yan, M.; Rothberg, L. J.; Kwock, E. W.; Miller, T. M. Interchain excitations in conjugated polymers. Phys. Rev. Lett. 1995, 75, 1992-1995
21. Jenekhe, S. A.; Osaheni, J. A. Excimers and exciplexes of conjugated polymers. Science 1994, 265, 765-768
22. Nguyen, T. Q.; Martini, I. B.; Liu, J.; Schwartz, B. J. Controlling interchain interactions in conjugated polymers: The effects of chain morphology on exciton-exciton annihilation and aggregation in MEH-PPV films. J. Phys. Chem. B 2000, 104 (2), 237-255.
23. Chang, R.; Hsu, J. H.; Fann, W. S.; Yu, J.; Lin, S. H.; Lee, Y. Z.; Chen, S. A. Aggregated states of luminescent conjugated polymers in solutions. Chem. Phys. Lett. 2000, 317, 153-158
24. Blatchford, J. W.; Jessen, S. W.; Lin, L. B.; Gustafson, T. L.; Fu, D. K.; Wang, H. L.; Swager, T. M.; MacDiarmid, A. G.; Epstein, A. J. Photoluminescence in pyridine-based polymers: role of aggregates. Phys. Rev. B: Condens. Matter 1996, 54, 9180-9189 (Pubitemid 126798016)
25. Gao, Y.; Wang, C. C.; Wang, L.; Wang, H. L. Conjugated polyelectrolytes with pH-dependent conformations and optical properties. Langmuir 2007, 23, 7760.
26. Bulmer, J. T.; Shurvell, H. F. Factor-analysis as a complement to band resolution techniques. 1. Method and its application to self-association of acetic-acid. J. Phys. Chem. 1973, 77, 256-262.
27. Panda, D.; Datta, A. Implications of area normalization of multicomponent spectra. Appl. Spectrosc. 2008, 62, 341-344.
28. Leclerc, M.; Faid, K. Electrical and optical properties of processable polythiophene derivatives: Structure-property relationships. Adv. Mater. 1997, 9, 1087-1094. (Pubitemid 127538791)
29. Chayer, M.; Faid, K.; Leclerc, M. Highly conducting water-soluble polythiophene derivatives. Chem. Mater. 1997, 9, 2902-2905. (Pubitemid 127471282)
30. Hoeben, F. J. M.; Schenning, A.; Meijer, E. W. Energy-transfer efficiency in stacked oligo(p-phenylene vinylene)s: Pronounced effects of order. ChemPhysChem 2005, 6, 2337-2342.
31. Yu, J.; Hu, D. H.; Barbara, P. F. Unmasking electronic energy transfer of conjugated polymers by suppression of 0-2 quenching. Science 2000, 289, 1327-1330.
32. Sartori, S. S.; De Feyter, S.; Hofkens, J.; Van der Auweraer, M.; De Schryver, F.; Brunner, K.; Hofstraat, J. W. Host matrix dependence on the photophysical properties of individual conjugated polymer chains. Macromolecules 2003, 36, 500-507.