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For instance, MOPV4 columnar structures in dodecane solution have a length of ≈150 nm, whereas for BOPV4 a length of ≈100 nm is found: P. Jonkheijm, J. K. J. van Duren, M. Kemerink, R. A. J. Janssen, A. P. H. J. Schenning, E. W. Meijer, unpublished results.
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See Supporting Information
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See Supporting Information.
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36
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27844557359
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note
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agg = 1 are consequently arbitrary and are taken as the spectra at the highest and lowest temperature measured, respectively.
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37
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24644440534
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Comparative time-resolved studies will be published elsewhere, which stress - from a physical point of view - the differences in organization and energy transfer in MOPV and BOPV assemblies: a) C. Daniel, F. Makereel, L. M. Herz, F. J. M. Hoeben, P. Jonkheijm, A. P. H. J. Schenning, E. W. Meijer, R. H. Friend, C. Silva, J. Chem. Phys. 2005, 123, 084902/1-084902/7.;
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41
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unpublished results
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b) C. Daniel, F. Makereel, L. M. Herz, D. Beljonne, F. J. M. Hoeben, P. Jonkheijm, A. P. H. J. Schenning, E. W. Meijer, C. Silva, unpublished results.
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Daniel, C.1
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42
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A. Gesquière, P. Jonkheijm, F. J. M. Hoeben, A. P. H. J. Schenning, S. De Feyter, F. C. De Schryver, E. W. Meijer, Nano Lett. 2004, 4, 1175-1179.
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De Feyter, S.5
De Schryver, F.C.6
Meijer, E.W.7
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43
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27844610254
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note
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Mixed assemblies are prepared by heating the mixed solutions at 80°C for 1 min and subsequent cooling to room temperature. This ensures breaking up of π-π stacking and hydrogen-bonding interactions and results in an intimate mixing between donor and acceptor.
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44
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27844508610
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note
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Upon going to high MOPV5 incorporations, direct MOPV5 excitation cannot be excluded.
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45
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27844483397
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note
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Comparing these curves with temperature-dependent PL spectra of pure BOPV3 (this Article) and MOPV3 (ref. [12]) relates the spectral changes observed at low temperatures to energy transfer to MOPV5.
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