A 3D copper(II) coordination framework showing different kinetic and thermodynamic crystal transformations through removal of guest water cubes

Chemistry - A European Journal

Volumn 15, Issue 47, 2009, Pages 12974-12977

  Chen, Xu Dong ^a   Zhao, Xiao Hu ^a   Chen, Min ^a   Du, Miao ^a  

^a TIANJIN NORMAL UNIVERSITY   (China)

Author keywords

Crystal engineering; Kinetic control; Metalorganic frameworks; Supramolecular chemistry thermodynamic control

Indexed keywords

COORDINATION FRAMEWORKS; CRYSTAL TRANSFORMATION; KINETIC CONTROL; METAL ORGANIC FRAMEWORK; METALORGANIC FRAMEWORKS; THERMODYNAMIC CONTROL; WATER CLUSTER;

CHEMICALS REMOVAL (WATER TREATMENT); CRYSTAL ENGINEERING; CRYSTALLINE MATERIALS; ISOMERS; MACROMOLECULES; THERMODYNAMICS; THREE DIMENSIONAL;

SUPRAMOLECULAR CHEMISTRY;

EID: 73349139836     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902306     Document Type: Article

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47. 4O4) : C 54.86, H 3.22, N 12.79; found: C 54.41, H 3.66, N 12.47.
48. 3, corresponding to 39.1 % per unit cell volume.
49. Notably, the dehydrated species 1 is insoluble in water, revealing a solid-state process.
50. 6) : C 50.69, H 3.83, N 11.82; found: C 50.02, H 4.15, N 11.48; this sample was obtained by rehydration of 1.
51. 4O4) : C 54.86, H 3.22, N 12.79; found: C 54.55, H 3.41, N 12.62.
52. 2O is placed inside a vacuum desiccator.
53. 2O and 45.0 (1)/11.3 (1) ° for 2, whereas those between imidazolyl and carboxylate are 50.2 (4) and 33.8 (1) °, respectively.
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