Site-selective internal cross-linking between mercury(II)-centered vertices of an octahedral mercury (II) capsule by a rod-shaped ditopic ligand

Angewandte Chemie - International Edition

Volumn 49, Issue 1, 2010, Pages 138-143

  Hiraoka, Shuichi ^a,b   Kiyokawa, Madoka ^a   Hashida, Shizuka ^a   Shionoya, Mitsuhiko ^a  

^a UNIVERSITY OF TOKYO   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

Mercury; Molecular capsules; Self assembly; Sulfonate ligands; Supramolecular chemistry

Indexed keywords

BRIDGING LIGANDS; DITOPIC LIGANDS; LIGAND EXCHANGES; MOLECULAR CAPSULE; MOLECULAR CAPSULES; NANO-SPACE; ROD-SHAPED; SELF-ASSEMBLED; SITE SELECTIVE;

EXCITONS; MACROMOLECULES; MERCURY (METAL); MERCURY COMPOUNDS; SELF ASSEMBLY; SUPRAMOLECULAR CHEMISTRY;

LIGANDS;

EID: 73349100033     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200905449     Document Type: Article

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56. 19F diffusion-ordered NMR spectroscopy (DOSY; see the Supporting Information).
57. 3CN prior to ESI-TOF mass measurement.
58. - (see Figure S6 in the Supporting Information).
59. - ligands.
60. II centers (see Figure S8 and Table S2 in the Supporting Information).
61. 2- depends mainly on the electronic nature of monosulfonate ligands and not on their molecular size (see the Supporting Information for details).
62. - ligands. Thus, the same species with two different sulfonate ligands inside the capsule was obtained through two different pathways.
63. 6] was formed.