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Volumn 49, Issue 1, 2010, Pages 123-135

Cooperation between cis and trans influences in cis-Pt II(PPh3)2 complexes: Structural, spectroscopic, and computational studies

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EID: 73349089634     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic901510m     Document Type: Article
Times cited : (51)

References (76)
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    • (1991) Crystallographic Computing , vol.5 , pp. 126
  • 45
    • 0019989536 scopus 로고
    • For a discussion on the chirality of square planar complexes see, for instance: (a)
    • For a discussion on the chirality of square planar complexes see, for instance: (a) Gullotti, M.; Pacchioni, G.; Pasini, A.; Ugo, R. Inorg, Chem. 1982, 21, 2006-2014.
    • (1982) Inorg, Chem. , vol.21 , pp. 2006-2014
    • Gullotti, M.1    Pacchioni, G.2    Pasini, A.3    Ugo, R.4
  • 55
    • 73349128658 scopus 로고    scopus 로고
    • 3 > AcO; the position of Cl changes according to the class of complexes considered, suggesting that the actual influences of a ligand depend on its environment, and this will be discussed later
    • 3 > AcO; the position of Cl changes according to the class of complexes considered, suggesting that the actual influences of a ligand depend on its environment, and this will be discussed later.
  • 69
    • 33748837232 scopus 로고    scopus 로고
    • To our knowledge there is at least one example in which the order of the trans influence is opposite to that of the trans effect, see: Wendt, O. F.; Elding, L. I. J. Chem. Soc, Dalton Trans. 1997, 4725-4731.
    • (1997) J. Chem. Soc, Dalton Trans. , pp. 4725-4731
    • Wendt, O.F.1    Elding, L.I.2
  • 71
    • 0141454937 scopus 로고    scopus 로고
    • Strong donor ligands display also a strong (kinetic) cis effect because, lowering the positive charge on Pt, they reduce its electrophilicity. See: (a) Hofmann, A.; Dahlernburg, L.; van Eldik, R. Inorg. Chem. 2003, 42, 6528-6538.
    • (2003) Inorg. Chem. , vol.42 , pp. 6528-6538
    • Hofmann, A.1    Dahlernburg, L.2    Van Eldik, R.3
  • 73
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    • Mason, J., Ed.; Plenum Press: New York
    • Jameson, C. In Multinuclear NMR; Mason, J., Ed.; Plenum Press: New York, 1987; pp 89-131.
    • (1987) Multinuclear NMR , pp. 89-131
    • Jameson, C.1
  • 76
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    • PtP and the donor power of aryl phosphines, suggesting that π back-donation to P is negligible, see ref 40
    • PtP and the donor power of aryl phosphines, suggesting that π back-donation to P is negligible, see ref 40.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.