Rapid and effective speciation analysis of arsenic compounds in human urine using anion-exchange columns in HPLC-ICP-MS

Journal of Occupational Health

Volumn 51, Issue 4, 2009, Pages 380-385

  Suzuki, Yoshihiro ^a   Shimoda, Yasuyo ^b   Endo, Yoko ^a   Hata, Akihisa ^c   Yamanaka, Kenzo ^b   Endo, Ginji ^c  

^a TOKYO ROSAI HOSPITAL   (Japan)

^b NIHON UNIVERSITY   (Japan)

^c OSAKA CITY UNIVERSITY GRADUATE SCHOOL OF MEDICINE   (Japan)

Author keywords

Arsenic; Biological monitoring; HPLC ICP MS; Speciation analysis

Indexed keywords

ANION EXCHANGE RESIN; ORGANOARSENIC DERIVATIVE;

ADOLESCENT; ADULT; AGED; ARTICLE; ENVIRONMENTAL MONITORING; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; HUMAN; JAPAN; MALE; MASS SPECTROMETRY; METHODOLOGY; MIDDLE AGED; OCCUPATIONAL EXPOSURE; URINE;

ADOLESCENT; ADULT; AGED; ANION EXCHANGE RESINS; ARSENICALS; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; ENVIRONMENTAL MONITORING; HUMANS; JAPAN; MALE; MASS SPECTROMETRY; MIDDLE AGED; OCCUPATIONAL EXPOSURE; YOUNG ADULT;

EID: 72549119391     PISSN: 13419145     EISSN: 13489585     Source Type: Journal    
DOI: 10.1539/joh.M9003     Document Type: Article

References (18)

1. American Conference of Governmental Industrial Hygienists. Arsenic and its inorganic compounds. In: 6th ed. Documentation of the TLVs and BEIs with other worlswide occupational exposure values. Cincinnati (OH): ACGIH; 2001.
2. Deutsche Forschungsgemeinschaft. Arsenic and inorganic arsenic compounds. In: Drexler H, Greim H, editors. Essential BAT value documentations. Weinheim (Germany): Wiley-VCH; 2006. p. 77-84.
3. Vahter M. Mechanisms of arsenic biotransformation. Toxicology 2002; 181-182: 211-7.
4. Hirata S, Toshimitsu H. Determination of arsenic species and arsenosugars in marine samples by HPLC-ICP-MS. Anal Bioanal Chem 2005; 383: 454-60.
5. Kirby J, Maher W, Spooner D. Arsenic occurrence and species in near-shore macroalgae-feeding marine animals. Environ Sci Technol 2005; 39: 5999-6005.
6. Vahter M, Marafante E, Dencker L. Metabolism of arsenobetaine in mice, rats and rabbits. Sci Total Environ 1983; 30: 197-211.
7. Marafante E, Vahter M, Dencker L. Metabolism of arsenocholine in mice, rats and rabbits. Sci Total Environ 1984; 34: 223-40.
8. Francesconi KA, Tanggaar R, McKenzie CJ, Goessler W. Arsenic metabolites in human urine after ingestion of an arsenosugar. Clin Chem 2002; 48: 92-101.
9. Hata A, Endo Y, Nakajima Y, et al. HPLC-ICP-MS speciation analysis of arsenic in urine of Japanese subjects without occupational exposure. J Occup Health 2007; 49: 217-23.
10. Habib A, Hayashi T, Sato KK, et al. Effectiveness of arsenic mitigation program in Bangladesh-Relationship between arsenic concentrations in well water and urine. Osaka City Med J 2007; 53: 97-103.
11. Gibbons RD. Detection and quantification of environmental pollutants. In: Meyers RA, editor. Encyclopedia of analytical chemistry. Chicheter (UK): Wiley & Sons Ltd; 2000. p. 2343-59.
12. Lin TH, Huang YL, Wang MY. Arsenic species in drinking water, hair, fingernails, and urine of patients with blackfoot disease. J Toxicol Environ Health A 1998; 53: 85-93.
13. Feldmann J, Lai VW, Cullen WR, Ma M, Lu X, Le XC. Sample preparation and storage can change arsenic speciation in human urine. Clin Chem 1999; 45: 1988- 97.
14. Nakajima Y, Endo G, Inoue Y, Yukita K, Endo Y. Biological monitoring of workers treating chemical warfare agents. Jap J Occup Med Traumatol 2006; 54: 29-33 (in Japanese).
15. Hirata S, Toshimitsu H, Aihara M. Determination of arsenic species in marine samples by HPLC-ICP-MS. Anal Sci 2006; 22: 39-43.
16. Shimoda Y, Suzuki Y, Endo Y, et al. Speciation analysis of arsenic in hijiki seaweed. In: 14th Arsenic Symposium. Tokyo: Japanese Arsenic Scientist's Society; 2008. p.11-2 (in Japanese).
17. Le XC, Cullen WR, Reimer KJ. Human urinary arsenic excretion after one-time ingestion of seaweed, crab, and shrimp. Clin Chem 1994; 40: 617-24.
18. Ministry of Health, Labour and Welfare, Japan. An ordinance to revise the portions of the Ordinance on Industrial Safety and Health (Ordinance of the Ministry of Health, Labour and Welfare No.158 of 2008). Tokyo: Ministry of Health, Labour and Welfare, 2008 (in Japanese).